Implications for peat formation in Maritsa-West Basin, SE Bulgaria: Insights from organic petrology, palynology and biomarker assemblage

2020 ◽  
Vol 222 ◽  
pp. 103447 ◽  
Author(s):  
Alexander Zdravkov ◽  
Maya Stefanova ◽  
Elżbieta Worobiec ◽  
Achim Bechtel ◽  
Stefan Marinov ◽  
...  
2021 ◽  
Vol 82 (2) ◽  
pp. 33-45
Author(s):  
Jordan Kortenski ◽  
Alexander Zdravkov

The presence and distribution of Si and Al in 19 Bulgarian coal basins and deposits, belonging to 8 coal provinces, were studied. Coals are of different rank (lignite to anthracite) and age (Late Carboniferous to Pliocene). The presence of both studied major elements depends strongly on: i) their concentration within the basin’s provenance; ii) the extent of terrigenous supply; iii) environmental acidity during peat formation; and iv) the presence and composition of epigenetic mineralization within the coal seams. Because of the presumed abundant terrigenous supply, the concentrations of both Si and Al are higher than the world average for most of the studied coals. Exceptions are the Maritsa-West, Burgas, Staniantsi, Oranovo, Chukurovo and Pernik Basins, for which reduced terrigenous supply can be suggested. For most of the basins, both Si and Al demonstrate good positive correlation with the ash yields, thus arguing for predominant inorganic affinity. Relatively low Si/Al ratios (typically <2) and good positive correlation between Si and Al (ro>0.6) imply the predominant role of the clay mineral assemblages as the main source of the elements in coal. Quartz is presumed to have dominant role only in Maritsa-West Basin. Poorer or negative correlations with the ash yields in part of the studied basins (i.e. Svoge, Maritsa-West, Sofia, Burgas and Dobrudzha Basins) suggest either mixed or predominantly organic affinity of the elements. Release of Si and Al from the clay minerals during the peat formation/diagenesis and subsequent formation of organo-metallic complexes is considered to responsible for such affinity.


1966 ◽  
Vol 44 (4) ◽  
pp. 421-427 ◽  
Author(s):  
John M. Stewart ◽  
Edward A. C. Follett

Phragmites communis, Eriophorum vaginatum, Calluna vulgaris, and Sphagnum palustre are representative of plants whose remains are frequently encountered in Scottish peat deposits. The effects of preservation in peat on the surface features of their leaves were followed by electron microscopy. Wax projections were observed on the surfaces of mature living leaves of Phragmites and Eriophorum but not on Calluna or Sphagnum. Details of cell wall outlines and stomata (or pores) were clearly defined in Phragmites, Eriophorum, and Sphagnum, but obscured in Calluna. The previous year's leaves differed by displaying a general absence of wax projections, an erosion of the cuticular surface, which took the form of either a loss in definition of the cell wall outlines or a definite etching of the surface, and the presence of numerous microorganisms. The surface features of preserved leaves exhibited to a greater degree this erosion of cell wall outline and cuticular surface. This preliminary study has indicated that major alterations in the submicroscopic features of cuticularized leaf surfaces occur at the leaf litter stage. The primary agents responsible for this degradation would appear to be microorganisms in conjunction with the physical and chemical processes of peat formation.


1994 ◽  
Vol 126 (S169) ◽  
pp. 7-20 ◽  
Author(s):  
Dale H. Vitt

AbstractCanadian peatlands can be classified into ombrotrophic bogs and minerotrophic fens, the latter subdivided into poor, moderate-rich, and extreme-rich fens, each with distinctive indicator species, acidity, alkalinity, and base cation content. If hydrology is considered the most important factor in peatland classification then the primary division must be between ombrotrophic bogs and minerotrophic fens; however both chemical and vegetational differences strongly indicate that the primary division of peatlands should be between acidic, Sphagnum-dominated bogs and poor fens on the one hand, and alkaline, brown-moss-dominated rich fens on the other. Although some metals such as sulphur and aluminum also vary along this gradient, nutrient contents of the surface waters do not. Bogs and fens are oligotrophic to mesotrophic wetlands that should be distinguished from eutrophic, non-peat-forming wetlands such as marshes and swamps by the presence in the former of a well-developed ground layer of bryophytes associated with relatively little seasonal water level fluctuation. Oligotrophy is probably maintained in bogs and poor fens by reduced water flow, whereas rich fens maintain mesotrophy by having larger water through-puts; however this is not well documented. Sphagnum appears to have real ecological significance, both in the initial stages of acidification and in controlling surface water temperature. Seasonal variation in surface water chemistry in all peatland types is relatively small, however precipitation events leading to changes in water levels do affect some chemical components. Although both autogenic and allogenic factors affect peatland development, initiation of peat formation and early development of peatlands during the Early and Mid Holocene were considerably influenced by regional climatic change. Later developmental patterns during the late Holocene and those seen at the present time appear to be more influenced by autogenic factors.


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