Electrocatalytic selective oxidation of ethylene glycol: a concise review of catalyst development and reaction mechanism with comparison to thermocatalytic oxidation process

2021 ◽  
pp. 100929
Author(s):  
Ji Qi ◽  
Ziying An ◽  
Chuang Li ◽  
Xiao Chen ◽  
Wenzhen Li ◽  
...  
Keyword(s):  
Reaction Mechanism ◽  
Ethylene Glycol ◽  
Selective Oxidation ◽  
Oxidation Process ◽  
Catalyst Development ◽  
Concise Review

Hierarchically porous γ-Al2O3 nanosheets: Facile template-free preparation and reaction mechanism for H2S selective oxidation

2018 ◽  
Vol 346 ◽  
pp. 238-248 ◽  
Author(s):  
Lijuan Shen ◽  
Xiaohai Zheng ◽  
Ganchang Lei ◽  
Xiang Li ◽  
Yanning Cao ◽  
...  
Keyword(s):  
Reaction Mechanism ◽  
Selective Oxidation ◽  
Hierarchically Porous ◽  
Template Free

Selective oxidation of methane in the presence of nitric oxide: comments on the reaction mechanism

1990 ◽  
Vol 6 (4) ◽  
pp. 399-407 ◽  
Author(s):  
Graham J. Hutchings ◽  
Michael S. Scurrell ◽  
Jeremy R. Woodhouse
Keyword(s):  
Nitric Oxide ◽  
Reaction Mechanism ◽  
Selective Oxidation ◽  
Oxidation Of Methane

Insight into the active site and reaction mechanism for selective oxidation of methane to methanol using H2O2 on a Rh1/ZrO2 catalyst

2020 ◽  
Vol 44 (4) ◽  
pp. 1632-1639 ◽  
Author(s):  
Qi Zhao ◽  
Bing Liu ◽  
Yuebing Xu ◽  
Feng Jiang ◽  
Xiaohao Liu
Keyword(s):  
Reaction Mechanism ◽  
Selective Oxidation ◽  
Active Site ◽  
Oxidation Of Methane ◽  
Methanol Formation ◽  
Zro2 Catalyst ◽  
Insight Into

Five-coordinated Rh leads to the over-oxidation of CH4, while four-coordinated Rh stabilizes CH3 and facilitates methanol formation via the CH3OOH intermediate.

The reaction mechanism of the selective oxidation of butane on (VO)2P2O7 catalysts: The influence of the valence state of vanadium

1997 ◽  
Vol 153 (1-2) ◽  
pp. 217-231 ◽  
Author(s):  
U. Rodemerck ◽  
B. Kubias ◽  
H.-W. Zanthoff ◽  
G.-U. Wolf ◽  
M. Baerns
Keyword(s):  
Reaction Mechanism ◽  
Selective Oxidation ◽  
Valence State

Kinetics and Mechanism of Oxidation of Selenium(IV) by Permanganate Ion in Aqueous Perchlorate Solutions

1993 ◽  
Vol 58 (3) ◽  
pp. 538-546 ◽  
Author(s):  
Refat M. Hassan ◽  
Sahr A. El-Gaiar ◽  
Abd El-Hady M. El-Summan
Keyword(s):  
Reaction Mechanism ◽  
Reaction Rate ◽  
Oxidation Process ◽  
Selenium Dioxide ◽  
Order Reaction ◽  
Acid Solutions ◽  
First Order ◽  
Acid Catalyzed ◽  
Mechanism Of Oxidation ◽  
Kinetics Of

The kinetics of permanganate oxidation of selenium dioxide in perchloric acid solutions at a constant ionic strength of 2.0 mol dm-3 has been investigated spectrophotometrically. A first-order reaction in [MnO4-] and fractional order with respect to selenium(IV) were observed. The reaction rate was found to be pH-independent at lower acid concentrations ([H+] < 0.5 mol dm-3) and was acid-catalyzed beyond this range. Addition of Mn2+ and F- ions leads to the prediction that MnO4- is the sole reactive species in the oxidation process. A tentative reaction mechanism consistent with the reaction kinetics has been proposed.

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