The influence of mixed cationic–anionic surfactants on the three-phase contact parameters in silica–solution systems

Author(s):  
L. Alexandrova ◽  
K. Hanumantha Rao ◽  
K.S.E. Forsberg ◽  
L. Grigorov ◽  
R.J. Pugh
2021 ◽  
Vol 22 (15) ◽  
pp. 7953
Author(s):  
Lionel Perrin ◽  
Andrew Akanno ◽  
Eduardo Guzman ◽  
Francisco Ortega ◽  
Ramon G. Rubio

The formation of coffee-ring deposits upon evaporation of sessile droplets containing mixtures of poly(diallyldimethylammonium chloride) (PDADMAC) and two different anionic surfactants were studied. This process is driven by the Marangoni stresses resulting from the formation of surface-active polyelectrolyte–surfactant complexes in solution and the salt arising from the release of counterions. The morphologies of the deposits appear to be dependent on the surfactant concentration, independent of their chemical nature, and consist of a peripheral coffee ring composed of PDADMAC and PDADMAC–surfactant complexes, and a secondary region of dendrite-like structures of pure NaCl at the interior of the residue formed at the end of the evaporation. This is compatible with a hydrodynamic flow associated with the Marangoni stress from the apex of the drop to the three-phase contact line for those cases in which the concentration of the complexes dominates the surface tension, whereas it is reversed when most of the PDADMAC and the complexes have been deposited at the rim and the bulk contains mainly salt.


Author(s):  
L. Alexandrova ◽  
K. Hanumantha Rao ◽  
K.S.E. Forsberg ◽  
L. Grigorov ◽  
R.J. Pugh

1999 ◽  
Vol 96 (9) ◽  
pp. 1335-1339 ◽  
Author(s):  
ALAN E. VAN GIESSEN, DIRK JAN BUKMAN, B.

2020 ◽  
Vol 55 (1) ◽  
pp. 32-37
Author(s):  
A. Yu. Vorob’ev ◽  
V. A. Nebol’sin ◽  
N. Swaikat ◽  
V. A. Yuriev

2009 ◽  
Vol 131 (12) ◽  
Author(s):  
Enno Wagner ◽  
Peter Stephan

In a special boiling cell, vapor bubbles are generated at single nucleation sites on top of a 20μm thick stainless steel heating foil. An infrared camera captures the rear side of the heating foil for analyzing the temperature distribution. The bubble shape is recorded through side windows with a high-speed camera. Global measurements were conducted, with the pure fluids FC-84 and FC-3284 and with its binary mixtures of 0.25, 0.5, and 0.75mole fraction. The heat transfer coefficient (HTC) in a binary mixture is less than the HTC in either of the single component fluid alone. Applying the correlation of Schlünder showed good agreement with the measurements (1982, “Über den Wärmeübergang bei der Blasenverdampfung von Gemischen,” Verfahrenstechnik, 16(9), pp. 692–698). Furthermore, local measurements were arranged with high lateral and temporal resolution for single bubble events. The wall heat flux was computed and analyzed, especially at the three-phase-contact line between liquid, vapor, and heated wall. The bubble volume and the vapor production rate were also investigated. For pure fluids, up to 50–60% of the latent heat flows through the three-phase-contact region. For mixtures, this ratio is clearly reduced and is about 35%.


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