Activating effect of potassium silicate solution in low portland cement binder

2022 ◽  
Vol 319 ◽  
pp. 126091
Author(s):  
Linlin Zhao ◽  
Xianwei Ma ◽  
Shuaiqi Song ◽  
Peibo You ◽  
Hairong Wu
2019 ◽  
Vol 966 ◽  
pp. 77-82
Author(s):  
Ketut Sumada ◽  
Srie Muljani ◽  
Caecilia Pujiastuti

Potassium silicate is well known as a fertilizer and source of silica for plants growth. This study aims to infiltrate nitrogen from carbamide (urea) into potassium silicate solution to produced silica potassium nitrogen (Si-K-N) matrix by precipitation method using CO2 as precipitator. Potassium silicate in the range of 3-8% SiO2 was obtained by extracting silica from geothermal sludge using potassium hydroxide solution. Carbamide is added to the potassium silicate solution allowed by mixing and flowing of CO2 gas in reactor glass. The result of IR spectra indicated the presence of N-H groups, potassium and silica in the gel matrix produced from precipitation process while no N-H group appears in the gel matrix produced from precipitation in the absence of carbamide. X-ray fluorescence showed the composition of the product Si-K-N in the range of 40 to 50 %SiO2 and in the range of 50 to 60 %K2O.


2019 ◽  
Vol 265 ◽  
pp. 01011
Author(s):  
Anisa Kuzina ◽  
Ekaterina Shokodko ◽  
Andrey Pustovgar ◽  
Aleksey Adamtsevich

This work represents the stage of the author's research aimed at identifying the solutions for increasing the energy efficiency of the production of precast concrete and reinforced concrete products and structures in plant conditions due to reducing the temperature of heat treatment, or due to the reduction of duration of this technological process. The work provides results of the research of the influence of the admixture of lithium carbonate (Li2CO3) on the dynamics of hydration process of the binding systems on a cement basis in the conditions of the increased temperature (40°C). The research was performed using the method of isothermal calorimetry on the two various samples of the cement binder, conducted in various countries. The Li2CO3 admixture is accepted in dosages from 0.5% to 2.5%. The graphical dependence of the heat flow of the exothermic reaction of hydration on the used lithium carbonate dosage in the first days of curing of the samples is established and presented.


2001 ◽  
Vol 28 (3) ◽  
pp. 375-382 ◽  
Author(s):  
Adnan Çolak

This paper deals with the effect of gypsum–Portland cement and gypsum–Portland cement–natural pozzolan ratios on the physical, mechanical, and durability properties of gypsum–Portland cement–natural pozzolan blends. The results indicate that the setting time of these paste decreases with the increase of gypsum content in the mixture, ranging from 8 to 11 min. The addition of superplasticizer increases the setting time from approximately 11 to 35 min. This increase is greatly dependent on the plasticizer admixture dosage. These blends show a kinetic of capillary water absorption very similar to that of the Portland cement binder. Sorptivity is strongly influenced by the type of binder, binder composition and water–binder ratio. Porosity of blended gypsum binders ranges from 12% to 37%. Their water absorption is high, reaching 27% in the blends with a greater proportion of gypsum. The gypsum–Portland cement blends themselves possess good water resistance, which is further enhanced by the addition of natural pozzolan and superplasticizer. The water-cured blends with the composition of 41:41:18 (gypsum : Portland cement : natural pozzolan) and 41:41:18S1 (gypsum : Portland cement : natural pozzolan : 1% superplasticizer) offer a compressive strength of approximately 20 MPa at room temperature. These blends give excellent properties retention after aging in water at 20°C for 95 days. Their good resistance to water decreases as the gypsum content in the mixture is raised. However, the strength loss for the gypsum–Portland cement–natural pozzolan blends is generally less than that observed for the gypsum binder.Key words: gypsum, Portland cement, natural pozzolan, physical, mechanical, durability.


1996 ◽  
Vol 2 (7) ◽  
pp. 41-45 ◽  
Author(s):  
Antanas Laukaitis ◽  
Laima J. Kunskaitė

Low-density (250–350 kg/m3) porous concrete has good thermal insulation and acoustical properties. However, the determination of these properties requires a lot of time and is rather costly. Changes in these properties can be determined, if the porous concrete air penetrability, which can be simply found, is known. This paper deals with porous concrete made using Portland cement binder and a binder mixture (lime + Portland cement), as well as with foam concrete air penetrability coefficient value dependency on its density and water/dry solids ratio V/K. The raw materials composition is given in Table 1. Fig. 1 represents the air penetrability determination apparatus scheme. Air penetrability increases with a decrease of density in porous concrete sample. For example, when V/K=0.6 and product density decreases from 490 to 310 kg/m3, the air penetrability coefficient increases from 2.5·10−7to 13.1·10−7 m3/m·S·Pa. Porous concrete air penetrability increases with an increase in V/K (Fig. 2.). The air penetrability coefficient increases from 6·6·10−7 to 12.8·10−7 m3/m·S·Pa when the product density is 350 kg/m3 and V/K changes from 0.5 to 0.7. Changes in V/K have a greater influence on low density porous concrete air penetrability. That is why, when slowly hydrating Portland cement is used for porous concrete production, foaming formation mixture temperature is not high, it binds and is cured very slowly. For higher density product pore structures such a slow curing process does not have any effects, because small, spherical pores prevail. When the water content is increased in the formation mixture, a change in product porous structure is observed, because larger deformed coupled pores are formed and therefore the air penetrability increases. An air penetrability dependency on product density and V/K regression equation (3) is given. Air penetrability coefficients of porous concrete made using a mixed binder (lime + Portland cement) are given in Table 2. It has been established, that a 20% Portland cement equivalent amount of lime in the binder mixture according to equation 1 and when the V/K ratio increased from 0.52 to 0.65, the some density product air penetrability coefficient of equal density products increased by 3 times, while the lime content in the binder increased from 20 to 80% from formation mixture samples with V/K ratio =0.52. Air penetrability of porous concrete made using a mixed binding material also depends on concrete density and formation mixture V/K ratio (Fig. 3.). Cellular concrete air penetrability coefficient values are given in Fig. 4. Cellular concrete differs from porous concrete, because its air penetrability coefficient values decrease with an increase in V/K ratio. This is the reason why cellular concrete air penetrability coefficients are lower than those of porous concrete. Cellular concrete air penetrability coefficient dependency on product density and V/K ratio is expressed by equation 4.


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