Hydration of Cement in the Presence of Biocidal Modifiers Based on Metal Hydrosilicates

This article presents the results of a study of the characteristics of hydration and properties of a composite biocidal cement binder containing hydrosilicates of barium, copper or zinc. It was found that copper hydrosilicates block hydration processes, and when zinc hydrosilicates are used, the rate of hydration is determined by the content of silicic acid. The limiting concentrations of biocidal modifiers have been established: zinc hydrosilicates—no more than 4% and copper hydrosilicates—no more than 0.5%, which are advisable to use for the manufacture of a biocidal composite binder. It is shown that modifying additives slow down the setting time, the amount of tricalcium silicate in cement stones increases, and their strength for some compositions decreases. Active binding of portlandite with the formation of calcium hydrosilicates occurs when the content of zinc hydrosilicates is 2%, which leads to an increase in the strength of the materials.

Paste Pipeline Transportation of Pumping Backfill Technology with Long Distance and High Stowing Gradient in Cold and High-Altitude Areas

A paste pipeline transportation of pumping backfill technology with long distance and high stowing gradient is proposed to solve the problem of filling slurry transportation with low concentration, the filling body poor quality, and the transportation difficulties with long distance and high stowing gradient in Heiniudong copper mine (HCM). The physical and chemical properties of the backfill material, backfill proportion test, circular pipe experiment, and backfill system analysis evaluation were studied in the laboratory and outdoor, and the application in HCM was carried out to evaluate the technology. The research results show the feasibility of considering classified tailings and binder as backfill aggregates, and the optimum proportion of cement-binder-classified tailings applied in the stope and goaf is 1 : 4 : 8 and 1 : 4 : 15, respectively, with paste rheological properties of mass fractions of both being 74%∼76% and the backfill strength of about 1.5 MPa at 28 d. Furthermore, when backfill proportions and rate of flow are 1 : 4 : 8 and 50 m3/h, the pressure loss of the pipeline is around 0.4 MPa/100 m, and the backfill pump meets the backfill requirements. On this condition, the technology is capable of obvious economic benefits with the backfill cost of only 25.56 yuan/t, remnant ore recovery rate of 80%, and new output value of 1.28 billion. It creates a precedent for the paste pumping backfill technology with long distance and high stowing gradient in cold and high-altitude areas. The technology also provides reference mining experience for similar mines.

Industrial experience in the implementation of clinker-free binders of alkaline activation

Objective. Issues related to the search for new, less energy- and material- intensive binders have long been on the agenda of many world environmental forums, since the carbonate technology of Portland cement entails pollution of the surrounding atmosphere and habitat, and the price of this product is unjustifiably growing. In our opinion, alkaline cements could contribute to the construction industry. Within the framework of this work, research results have been obtained that confirm the effectiveness of the development of a clinker-free technology for producing alkaline-mixed binders and composites based on them using aluminosilicate additives, both natural and technogenic origin.Method. The methods of electron microscopy and differential thermal analysis make it possible to study the nature of the components and the processes of formation of the structure of the cement stone. Waste from the cement industry has the appropriate granulometric and chemical composition, the aluminosilicate mineralogy of the studied powders confirms their compliance with the ready-made raw mix of Portland cement clinker, which is the key to the possibility of their effective use.Result. The carried out differential thermal analyzes confirmed the presence of the following phases in the composition of cement stone on binding bonds "cement dust - alkaline activator" of zeolite, calcite, mica type muscovite, montrillonite, magnesium oxide, calcium sulfoaluminates, ettringite structure, calcium hydrochloraluminate, calcium hydrosilicate, calcium hydrosilicate calcium.Conclusion. The obtained regularities of the processes of formation of the structure of the cement binder "waste of the cement industry - Na2SiO3", will transform these developments to create strong and durable artificial building composites competing with concretes on Portland cement.

Replacement of traditional components of the backfill mixture with man-made waste

The formation and storage of man-made waste of water-soluble ores creates a global environmental problem that entails changing landscapes in mining areas and environmental degradation. The involvement of man-made waste in a closed cycle of the production and technological chain makes it possible to reduce the impact of mining and processing on the environment. The use of non-waste (low-waste) technologies, in addition to reducing the environmental burden, allows you to expand the raw material base of the enterprise by replacing the traditional components of the backfill mixture with man-made waste from mining and processing enterprises. The possibility of replacing the traditional, specially extracted aggregate in the backfill mixture with industrial waste of water-soluble ores is experimentally proved. The possibility of creating a cementless backfill mixture is proved. The possibility of replacing the cement binder with magnesium-containing slags of the Chusovsky Metallurgical Plant was confirmed. It was found that the separate activation treatment of the components of the backfill mixture has a positive effect on its rheological properties and increases the strength of the joint mass. The use of lignosulfonate improves the quality of the mixture and the resulting mass. The development of a backfill composite from man-made waste makes it possible to implement the principle of organizing mining production, which provides for the use of intermediate products in cyclic production and excludes the formation of man-made waste of water-soluble ores.

The Influence of Chrysotile Nanofibers Dispersion on the Physical and Mechanical Properties of the Cement Matrix

The article describes the influence of chrysotile nanofibers dispersion introduction on the properties of the cement matrix. Comparison of the dispersion level of suspensions obtained using cavitation and ultrasonic processing methods is presented. The positive effect of chrysotile fibers application on the strength characteristics of the material has been confirmed. A 34% increase in the compressive strength of the samples was achieved on the 7th day of hardening, while on the 28th day it increased by 36% and with the steam treatment - by 38% compared to the reference sample. Laser particle size analysis confirmed the predominance of the nanosized component of chrysotile fibers in the suspension, which affected the structuring of the cement matrix. The results of the differential thermography, IR spectrometry, X-ray microanalysis and scanning electron microscopy of the samples are also presented. The analysis methods confirmed that introduction of chrysotile nanofibers suspension into the composition of a cement binder makes it possible to significantly vary the structure and morphology of new formations in fine-grained concrete. It also changes the quantitative and qualitative phase composition of the material with the formation of calcium silicate hydrates of lower basicity, leading to an increase in the strength of cement concrete.

Influence of Granulometric Composition and Type of Fillers and Additives on the Strength and Biostability of Cement Composites Based on Dry Building Mixtures

The structure of filled cementitious composite materials is formed as a result of hardening with the formation of a crystalline framework. The filler is involved in the building material crystal system structure formation. Chemically active fillers promote intensive release of hydration products that bind into insoluble compounds and increase the system stability. When developing the formulations for dry building mixtures, it is effective to use several fillers with different properties that complement each other, and biocidal additives increasing the materials resistance to environment effects formed by mold fungi. To create modified dry building mixtures based on cement binder, materials such as filler made of quartz sand of various fractions, fillers chrysotile and clinoptilolite and biocidal additives of the Teflex series were used. The composition with sand grains of 0.16–0.315 mm in size showed high strength properties in bending and compression. The introduction of chrysotile in an amount of 3% by weight of cement and quartz sand with a particle size of 0.16–0.315 mm increases the compressive and flexural strength by 7 and 13%, respectively, compared with the control composition. Clinoptilolite, introduced in an amount of 20% of the cement mass instead of one of the quartz sand fractions, increases the compressive strength of the composites up to 5%. The introduction of the Teflex series additives in the amount of at least 1% by weight of the binder ensures the composites’ fungal resistance. The additive “Teflex disinfectant” in an amount of at least 3% of the cement mass gives the composites fungicidal properties, the zone of no fungal growth on the nutrient solution near the infected samples is 4 mm.