Fireside Corrosion of 9Cr-1Mo Steel at High Temperatures, in the Acid Flue Gas from an Oil Refinery

2021 ◽  
pp. 109878
Author(s):  
Anibal Alviz-Meza ◽  
S Ismat Shah ◽  
Viatcheslav Kafarov ◽  
Darío Peña-Ballesteros
TAPPI Journal ◽  
2014 ◽  
Vol 13 (8) ◽  
pp. 65-78 ◽  
Author(s):  
W.B.A. (SANDY) SHARP ◽  
W.J. JIM FREDERICK ◽  
JAMES R. KEISER ◽  
DOUGLAS L. SINGBEIL

The efficiencies of biomass-fueled power plants are much lower than those of coal-fueled plants because they restrict their exit steam temperatures to inhibit fireside corrosion of superheater tubes. However, restricting the temperature of a given mass of steam produced by a biomass boiler decreases the amount of power that can be generated from this steam in the turbine generator. This paper examines the relationship between the temperature of superheated steam produced by a boiler and the quantity of power that it can generate. The thermodynamic basis for this relationship is presented, and the value of the additional power that could be generated by operating with higher superheated steam temperatures is estimated. Calculations are presented for five plants that produce both steam and power. Two are powered by black liquor recovery boilers and three by wood-fired boilers. Steam generation parameters for these plants were supplied by industrial partners. Calculations using thermodynamics-based plant simulation software show that the value of the increased power that could be generated in these units by increasing superheated steam temperatures 100°C above current operating conditions ranges between US$2,410,000 and US$11,180,000 per year. The costs and benefits of achieving higher superheated steam conditions in an individual boiler depend on local plant conditions and the price of power. However, the magnitude of the increased power that can be generated by increasing superheated steam temperatures is so great that it appears to justify the cost of corrosion-mitigation methods such as installing corrosion-resistant materials costing far more than current superheater alloys; redesigning biomassfueled boilers to remove the superheater from the flue gas path; or adding chemicals to remove corrosive constituents from the flue gas. The most economic pathways to higher steam temperatures will very likely involve combinations of these methods. Particularly attractive approaches include installing more corrosion-resistant alloys in the hottest superheater locations, and relocating the superheater from the flue gas path to an externally-fired location or to the loop seal of a circulating fluidized bed boiler.


2017 ◽  
Vol 87 (5-6) ◽  
pp. 741-756
Author(s):  
J. M. Brossard ◽  
F. Maad ◽  
J. Chartier ◽  
R. Chavrot ◽  
Y. Kawahara

2013 ◽  
Vol 378 ◽  
pp. 403-407
Author(s):  
Jian Feng Yang ◽  
Ling Ling Chen ◽  
Wen Bin Liu

Flue gas turbine is one of the highest failure rate of the power equipment in oil refinery now.It is a key role to achieve saving energy and reducing consumption, the goal ofpollution reduction and the safe, reliable and efficient operation of the flue turbine in refinery. Therefore, it is of great significance to the fault diagnosis of the blade by summarizing the fault reason of the flue gas turbine and using fault tree analysis.


2008 ◽  
Vol 595-598 ◽  
pp. 271-280 ◽  
Author(s):  
Florimonde Lebel ◽  
Christophe Rapin ◽  
Jean François Mareche ◽  
Renaud Podor ◽  
Xavier Chaucherie ◽  
...  

The efficiency of Waste-to-Energy (W-t-E) boilers is affected by fireside corrosion of the heat exchangers that involve unexpected shutdown of facilities for repairs and limit the increase of steam conditions used to produce electricity. The parameters governing fireside corrosion are various and mechanisms are very complex, nevertheless, they are relatively well documented in the literature. In this paper, a laboratory-scale corrosion pilot, which reproduces MSWI boilers conditions, is described. The specificity of our approach includes simultaneous simulation of the temperature gradient at flue-gas/tube interface, the velocity of flue-gas and ashes. Corrosion rates obtained on Tu37C carbon steel at a metal temperature equal to 400°C and a flue gas temperatures of 650°C and 850°C (1100 ppm HCl, 110 ppm SO2 and synthetic ashes free of heavy metals) are respectively around 1.6 2m/hour and 5.6 2m/hour. Preferential metal loss, attributed to erosion-corrosion phenomena, is also observed at low flue-gas temperature (T=650°C) on the face exposed at 90° to the flue-gas. The analysis of corrosion scales demonstrates the reproducibility of results and the reliability of corrosion mechanisms determined from experiments, with degradation observed similar to superheater tubes from EfW facilities. Thus, the corrosion pilot developed can be used as an accurate simulator of the environment encountered in MSWI.


2005 ◽  
Vol 44 (16) ◽  
pp. 6485-6490 ◽  
Author(s):  
Alexander Roesch ◽  
Ettireddy P. Reddy ◽  
Panagiotis G. Smirniotis

2004 ◽  
Vol 224 (1) ◽  
pp. 42-49 ◽  
Author(s):  
Guoyong Xie ◽  
Zhenyu Liu ◽  
Zhenping Zhu ◽  
Qingya Liu ◽  
Jun Ge ◽  
...  

2004 ◽  
Vol 21 (4) ◽  
pp. 525-548 ◽  
Author(s):  
D. Vamvuka ◽  
C. Arvanitidis ◽  
D. Zachariadis

2018 ◽  
Vol 37 (3) ◽  
pp. 245-251 ◽  
Author(s):  
Lu Jin-tao ◽  
Li Yan ◽  
Yang Zhen ◽  
Huang Jin-yang ◽  
Zhu Ming ◽  
...  

AbstractFireside corrosion behavior of Inconel 740H superalloy was studied at 750 °C in simulated coal ash/flue gas environments by means of XRD, SEM and EDS. The results indicated that the corrosion behavior was strongly related to the SO2 levels and was significantly affected by NaCl additions. In presence of the atmospheres with 0.1 % SO2, the alloy exhibited the highest corrosion resistance due to formation of a stable and dense Cr2O3 film. In presence of the atmosphere with 1.5 % SO2, however, a non-coherent and porous Cr2O3 film was formed. The thickness of film and internal sulfides were substantially increased. The NaCl additions significantly accelerated the corrosion process. A non-protective outer oxide film was formed, composed by multiple layers with serious inner sulfide and spallation. The depths of internal oxidizing and sulfuration zones were significantly increased. The mechanism of ash corrosion formation was also discussed.


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