A comparison of the thyroid disruption induced by decabrominated diphenyl ethers (BDE-209) and decabromodiphenyl ethane (DBDPE) in rats

2019 ◽  
Vol 174 ◽  
pp. 224-235 ◽  
Author(s):  
Yuwei Wang ◽  
Tian Chen ◽  
Yanmin Sun ◽  
Xuezhen Zhao ◽  
Dan Zheng ◽  
...  
Chemosphere ◽  
2019 ◽  
Vol 223 ◽  
pp. 675-685 ◽  
Author(s):  
Li Jing ◽  
Yanmin Sun ◽  
Yuwei Wang ◽  
Baolu Liang ◽  
Tian Chen ◽  
...  

2015 ◽  
Vol 2015 ◽  
pp. 1-10 ◽  
Author(s):  
Huimei Shan ◽  
Chongxuan Liu ◽  
Zheming Wang ◽  
Teng Ma ◽  
Jianying Shang ◽  
...  

A new method was developed for rapid and direct measurement of polybrominated diphenyl ethers (PBDEs) in aqueous samples using fluorescence spectroscopy. The fluorescence spectra of tri- to deca-BDE (BDE 28, 47, 99, 153, 190, and 209) commonly found in environment were measured at variable emission and excitation wavelengths. The results revealed that the PBDEs have distinct fluorescence spectral profiles and peak positions that can be exploited to identify these species and determine their concentrations in aqueous solutions. The detection limits as determined in deionized water spiked with PBDEs are 1.71–5.82 ng/L for BDE 28, BDE 47, BDE 190, and BDE 209 and 45.55–69.95 ng/L for BDE 99 and BDE 153. The effects of environmental variables including pH, humic substance, and groundwater chemical composition on PBDEs measurements were also investigated. These environmental variables affected fluorescence intensity, but their effect can be corrected through linear additivity and separation of spectral signal contribution. Compared with conventional GC-based analytical methods, the fluorescence spectroscopy method is more efficient as it only uses a small amount of samples (2–4 mL), avoids lengthy complicated concentration and extraction steps, and has a low detection limit of a few ng/L.


Author(s):  
Hoang Quoc Anh ◽  
Shin Takahashi ◽  
Pham Thi Ngoc Mai ◽  
Thai Thu Thuy ◽  
Nguyen Thi Thanh Huong

Concentrations of seven indicator polychlorinated biphenyls (Ʃ7PCBs) and eight predominant polybrominated diphenyl ethers (Ʃ8PBDEs) were examined in outdoor dust samples collected from some representative areas in northern Vietnam, including a core urban area of Hanoi City, an industrial park in Thai Nguyen Province, and a rural area in Bac Giang Province. Levels (median and range) of Ʃ7PCBs and Ʃ8PBDEs in our dust samples were 2.8 (0.028–22) and 11 (0.55–52) ng/g, respectively. Concentrations of PCBs and PBDEs in the urban and industrial dust samples were significantly higher than those measured in the rural ones, suggesting the role of urbanization-industrialization processes on the emission of these pollutants. PCBs exhibited specific profiles in the industrial dusts with significant proportions of low-chlorinated congeners such as CB-28 and CB-52, while the remaining samples were more contaminated by heavier compounds such as CB-118, CB-138, and CB-153. For PBDEs, BDE-209 was the most predominant congener in all the samples. Emission souces of PCBs and PBDEs in our dust samples were estimated to be household, traffic, and industrial activities. Human exposure to PCBs and PBDEs in outdoor dusts was estimated, implying relatively low health risk.


RSC Advances ◽  
2015 ◽  
Vol 5 (127) ◽  
pp. 105259-105265
Author(s):  
Donggao Yin ◽  
Hui Peng ◽  
Hua Yin ◽  
Su Zhou ◽  
Shichang Xiong ◽  
...  

The combined pollution of polybrominated diphenyl ethers (PBDEs) and heavy metals in electronic waste dismantling areas has received increasing concern in recent years.


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