Compared with zinc (Zn) sorption, there is very little information on the
effect of soil properties on Zn desorption from soils. In this study,
desorption of native and added Zn from 7 Canterbury (NZ) soils was determined
using a technique involving repeated equilibration of soil in 0·01 M
Ca(NO3)2. The concentrations and
patterns of desorption of both native and added Zn varied between the
different soils. Greater concentrations of native Zn were desorbed from
surface soils than from subsoils, and greater concentrations of added Zn were
desorbed from subsoils than from their corresponding surface horizons.
Correlation analysis showed that cation exchange capacity (CEC) and organic
carbon (C) were the dominant soil variables contributing towards sorption or
desorption of Zn. However, simple linear regressions involving CEC or organic
C explained only 48–62% of the total variation in Zn sorption or
desorption from the different soils.
Multiple regression analysis indicated that cumulative native Zn desorption
(expressed as percentage of DTPA-extractable Zn) was strongly related to CEC
and the content of Mn oxides, which in combination explained 80% of the
variability between soils. Regression analysis also showed that CEC plus Mn
oxides and pH explained 91% of the variability in Zn sorption between
the soils; whereas for added Zn desorbed (%), CEC plus pH and
crystalline Al oxides explained 93% of variability in added Zn
desorption.