Ce 3+ -doped Li 4 Ti 5 O 12 with CeO 2 surface modification by a sol-gel method for high-performance lithium-ion batteries

2016 ◽  
Vol 189 ◽  
pp. 147-157 ◽  
Author(s):  
Qianyu Zhang ◽  
Yan Liu ◽  
Huansheng Lu ◽  
Daoping Tang ◽  
Chuying Ouyang ◽  
...  
2014 ◽  
Vol 115 ◽  
pp. 326-331 ◽  
Author(s):  
Yongho Lee ◽  
Junyoung Mun ◽  
Dong-Won Kim ◽  
Joong Kee Lee ◽  
Wonchang Choi

2017 ◽  
Vol 727 ◽  
pp. 718-725 ◽  
Author(s):  
Xu Yan Liu ◽  
Yan Lin Han ◽  
Qiang Li ◽  
Deng Pan

Nanostructured SnO2 is an attractive anode material for high-energy-density lithium-ion batteries because of the fourfold higher theoretical charge capacity than commercially used graphite. However, the poor capacity retention at high rates and long-term cycling have intrinsically limited applications of nanostructured SnO2 anodes due to large polarization and ~300% volume change upon lithium insertion/extraction. Here we report the design of SnO2 nanoparticles, which are synthesized by sol-gel method, with an aim at overcome the above problems for the high-performance reversible lithium storage. The results showed that the mean sizes of SnO2 particles treated with 6 wt.% ammonia were less than 30 nm, which can store charge with a capacity density as high as ~1888 mAh/g. Even when the discharge rate was increased to 0.5 C, it still retained ~1017 mAh/g.


RSC Advances ◽  
2015 ◽  
Vol 5 (98) ◽  
pp. 80170-80175 ◽  
Author(s):  
Shanshan Li ◽  
Zhi Su ◽  
Xinyu Wang

A series of (1 − x)LiMnPO4·xLi3V2(PO4)3/C (x = 0, 0.1, 0.3, 0.5, 0.7, 0.9 and 1) composite nanoparticles are synthesized as cathode materials for lithium-ion batteries by the sol–gel method, using N,N-dimethyl formamide as a dispersing agent.


2022 ◽  
Author(s):  
He Duan ◽  
Zhiyong Zhou ◽  
Yanming Zhao ◽  
Youzhong Dong

Single-phase magnesium molybdate, MgMoO4, is successfully synthesized by a facile sol-gel method. Attributed to the multielectron reaction and the synergistic effect of the elements molybdenum (Mo) and magnesium (Mg), the...


2015 ◽  
Vol 3 (9) ◽  
pp. 955-960 ◽  
Author(s):  
Lingfang Li ◽  
Changling Fan ◽  
Xiaobing Huang ◽  
Xiang Zhang ◽  
Shaochang Han

2013 ◽  
Vol 232 ◽  
pp. 258-263 ◽  
Author(s):  
Shuangke Liu ◽  
Jing Xu ◽  
Dezhan Li ◽  
Yun Hu ◽  
Xiang Liu ◽  
...  

2012 ◽  
Vol 1440 ◽  
Author(s):  
Satoru Tsumeda ◽  
Scott D. Korlann ◽  
Shunzo Suematsu ◽  
Kenji Tamamitsu

ABSTRACTOlivine lithium manganese phosphate, LiMnPO4 is a promising cathode material for high energy and safe lithium ion batteries. However, LiMnPO4 possesses excessively poor electrochemical activity, compared to conventional cathode materials. To enhance the electrochemical activity, we have synthesized LiMnPO4/multi-walled carbon nanotube (MWCNT) composites by employing an in-situ sol-gel method. The LiMnPO4/MWCNT composites were investigated by utilizing X-ray diffraction, thermogravimetric analysis, scanning electron microscope, transmission electron microscope, and galvanostatic charge-discharge cycling. The LiMnPO4 showed a particle size of ca. 50 nm and capacity of 102 mAh/g at 0.1 C without C.V. charging mode. This study demonstrated that the electrochemical activity of LiMnPO4 was significantly affected by not only pH and the amount of a chelating agent but also unreacted Mn2+. This is the first report analyzing the existence and effects of unreacted Mn2+ in LiMnPO4 synthesized by a sol-gel method.


RSC Advances ◽  
2015 ◽  
Vol 5 (91) ◽  
pp. 74774-74782 ◽  
Author(s):  
Wenjun Zhu ◽  
Hui Yang ◽  
Wenkui Zhang ◽  
Hui Huang ◽  
Xinyong Tao ◽  
...  

A Li4Ti5O12/TiO2/carbon (Li4Ti5O12/TiO2/C) nanocrystalline composite has been successfully synthesized by a facile sol–gel method and subsequent calcination treatment.


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