Electrochemiluminescent graphene quantum dots enhanced by MoS2 as sensing platform: a novel molecularly imprinted electrochemiluminescence sensor for 2-methyl-4-chlorophenoxyacetic acid assay

2017 ◽  
Vol 228 ◽  
pp. 107-113 ◽  
Author(s):  
Yukun Yang ◽  
Guozhen Fang ◽  
Xiaomin Wang ◽  
Fuyuan Zhang ◽  
Jingmin Liu ◽  
...  
2019 ◽  
Vol 31 (5) ◽  
pp. 838-843 ◽  
Author(s):  
Ava Gevaerd ◽  
Craig E. Banks ◽  
Márcio F. Bergamini ◽  
Luiz Humberto Marcolino‐Junior

2017 ◽  
Vol 423 ◽  
pp. 810-816 ◽  
Author(s):  
Xi Zhou ◽  
Xuexia Gao ◽  
Fengyan Song ◽  
Chunpeng Wang ◽  
Fuxiang Chu ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (76) ◽  
pp. 72670-72675 ◽  
Author(s):  
X. E. Zhao ◽  
C. H. Lei ◽  
Y. H. Wang ◽  
F. Qu ◽  
S. Y. Zhu ◽  
...  

Pristine graphene quantum dots (GQDs) without any functionalization were used as probes to develop a sensitive and selective fluorescence sensing platform for the detection of tyrosinase (TYR) activity and its inhibitor screening for the first time.


Author(s):  
Tongchang Zhou ◽  
Arnab Halder ◽  
Yi Sun

In this work, we firstly explored a mild, clean, and highly efficient approach for the synthesis of graphene quantum dots (GQDs). GQDs with carboxyl groups or amino groups, were prepared from one-pot environmentally friendly method assisted by hydrogen peroxide, respectively. It was proved that carboxyl groups played an important role in the fluorescence quenching. Based on these findings, we developed a novel fluorescent nanosensor by combining molecularly imprinted polymers (MIPs) with carboxyl functionalized GQDs for the determination of tetracycline (TC) in aqueous samples. The nanocomposite was prepared using a sol-gel process. GQDs-MIPs showed strong fluorescent emission at 410 nm when excited at 360 nm, which was subsequently quenched in the presence of TC. Under optimum conditions, the fluorescence intensity of GQDs-MIPs decreased in response to the increase of TC concentration with good linearity rage of 1.0-104 µg L-1. The limit of detection was determined to be 1 µg L-1. The fluorescence intensity of GQDs-MIPs was more strongly quenched by TC compared to the corresponding non-imprinted polymers, GQDs-NIPs. With the high sensitivity, the material was also successfully worked for the detection of TC in real spiked milk samples.


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