Thermodynamic analysis of the partial oxidation of coke oven gas for indirect reduction of iron oxides in a blast furnace

Energy ◽  
2015 ◽  
Vol 86 ◽  
pp. 758-771 ◽  
Author(s):  
Wei-Hsin Chen ◽  
Chih-Liang Hsu ◽  
Shan-Wen Du
2010 ◽  
Vol 156-157 ◽  
pp. 1024-1028
Author(s):  
Da Hai Hu ◽  
Xiong Gang Lu ◽  
Hong Wei Cheng ◽  
Wei Zhong Ding

The performance of Ni/SiO2 Catalysts modified by La2O3, ZrO2 and CeO2 were tested in a BaCo0.7Fe0.2Nb0.1O3-δ (BCFNO) membrane reactor by catalytic partial oxidation of coke oven gas (COG) under atmospheric pressure. The results show that the oxygen permeation flux increased dramatically with Ni/RxOy/SiO2 (R = La, Zr or Ce) catalysts by adding the element of rare earth especially the La during the reforming reaction. At optimized reaction conditions, the dense oxygen permeable membrane had an oxygen permeation flux around 16.4 ml/cm2•min and a CH4 conversion of 99.2% have been achieved at 900 oC.


2020 ◽  
Vol 2,2020 (2,2020 (125)) ◽  
pp. 5-9
Author(s):  
Vaniukov A ◽  
Kovalyov D ◽  
Vaniukova N ◽  
Khodyko I ◽  
Bezshkurenko O

The objective of the present work is to research a quantitate ratio of degree direct reduction inside of SRP and degree of indirect reduction outside of SRP on the top of the blast furnace.The reactions of direct and indirect reduction occurring during the heat treatment of self reducing pellets (SRP) have been studied. In this investigation Blast furnace (BF) sludge which contains particles of coke, has been included in the SRP blend as a source of solid reductant and iron bearing oxides. In the SRP as a part ot the blast furnace burden occur the reactions simultaneously: inside of SRP-direct reduction by Csolid; gasification of carbon and indirect reduction by CO; and outside of SRP-indirect reduction of iron bearing oxides by reducing gas coming from the hearth of blast furnace through the column of charged materials. The experimental setup is shown in Fig. 1. It con-sists of a electrical heating furnace, which can be moved up and down. The quartz tube passes through the furnace. The reaction zone is in the middle of the furnace. Neutral argon atmosphere is created and for indirect reduction argon changed - on hydrogen. Gases of argon, hydrogen are introduced into the furnace separately. Wire of nickel alloy chromosome joins the scales test. A thermocouple is located in the tube.The crucible of wire chrome-nickel was permeable.Metohd. The experiments was performed continuously from the start temperature (~200 ˚C) to the experimental temperature (500 ˚C; 700 ˚C; 900 ˚C; 1100 ˚C) in argon free environment. Upon reaching the desired temperature argon was replaced by hydrogen during 30 minutes. After that the reduced probe of SRP was cooled in argon. Results. The integrated degree of reduction is equal 100%, which includes 98,6 % direct reduction by solid carbon under temperatures 1100°C. The chemical analysis of the reduced SRP showed the degree of integrated reduction change from 85,79 % (900 °C) to 92,50 % (1000 °C) and 84,6% (1100°C) and metallization 83,30 % (900 °C), 89,90 % (1000 °C), 80,75 % (1100 °C).These data correspond to results of degree of reduction SRP depends on temperature


2010 ◽  
Vol 154-155 ◽  
pp. 877-881 ◽  
Author(s):  
Hong Wei Cheng ◽  
Xiong Gang Lu ◽  
Da Hai Hu ◽  
Yu Wen Zhang ◽  
Wei Zhong Ding ◽  
...  

The BaCo0.7Fe0.2Nb0.1O3-δ (BCFNO) membranes combined with Ce0.8Re0.2O2-δ (Re=La, Y) layer on the permeation side were used for hydrogen production by partial oxidation reforming of coke oven gas (COG). The Ce0.8Re0.2O2-δ improved the oxygen permeation flux of the membrane by 11–28% at 750 oC. The high oxygen permeation flux achieved using the Ce0.8Re0.2O2-δ surface-coating layer in this work are quite encouraging with a maximum value reaching 19.7 ml/cm2•min at 900 oC, which will be promising surface modification materials in the catalytic partial oxidation reforming of COG.


Author(s):  
Edoardo Bertolotto ◽  
Alberto Amato ◽  
Li Guoqiang

Abstract The present paper describes atmospheric experimental tests of a new Ansaldo Energia full scale burner which was designed to burn fuels byproduct of steel making processes (mixtures of Blast-Furnace Gas (BFG) and Coke-Oven Gas (COG)), characterized by very low heating values (LHV∼2–3.5 MJ/kg) and very low stoichiometric air/fuel ratios (∼0.5–1 kg/kg). In particular, flame stability and blow-out margins were assessed for different burner variants and fuel compositions such as pure BFG, blends of BFG with increasing content of COG, and also a synthetic mixture of natural gas, hydrogen and nitrogen (NG/H2/N2). Except for pressure, all burner inlet conditions were simulated as in the actual gas turbine engine. The best performing burner among those tested demonstrated an excellent burning stability behavior over a wide operating range and stably burned pure BFG without any supplementary fuel. Furthermore, considering that in most operating concepts gas turbine engines for Ultra-Low BTU applications require a back-up fuel (such as oil, propane or natural gas) to ignite and ramp up or to perform load-rejections, the present atmospheric tests also assessed maneuvers to switch from natural gas operation to syngas operation. Also in this type of dual-fuel operation the burner demonstrated a wide flame stability range.


2020 ◽  
Vol 34 (11) ◽  
pp. 15048-15060
Author(s):  
Ziguang Zhao ◽  
Xiaobing Yu ◽  
Yansong Shen ◽  
Yuntao Li ◽  
Hui Xu ◽  
...  

2008 ◽  
Vol 22 (3) ◽  
pp. 1444-1448 ◽  
Author(s):  
Jianzhong Guo ◽  
Zhaoyin Hou ◽  
Jing Gao ◽  
Xiaoming Zheng

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