Study of the bubble nucleation and growth mechanisms in high-pressure foam injection molding through in-situ visualization

2016 ◽  
Vol 76 ◽  
pp. 2-13 ◽  
Author(s):  
Vahid Shaayegan ◽  
Guilong Wang ◽  
Chul B. Park
Author(s):  
S. Q. Xiao ◽  
S. Baden ◽  
A. H. Heuer

The avian eggshell is one of the most rapidly mineralizing biological systems known. In situ, 5g of calcium carbonate are crystallized in less than 20 hrs to fabricate the shell. Although there have been much work about the formation of eggshells, controversy about the nucleation and growth mechanisms of the calcite crystals, and their texture in the eggshell, still remain unclear. In this report the microstructure and microchemistry of avian eggshells have been analyzed using transmission electron microscope (TEM) and energy dispersive spectroscopy (EDS).Fresh white and dry brown eggshells were broken and fixed in Karnosky's fixative (kaltitanden) for 2 hrs, then rinsed in distilled H2O. Small speckles of the eggshells were embedded in Spurr medium and thin sections were made ultramicrotome.The crystalline part of eggshells are composed of many small plate-like calcite grains, whose plate normals are approximately parallel to the shell surface. The sizes of the grains are about 0.3×0.3×1 μm3 (Fig.l). These grains are not as closely packed as man-made polycrystalline metals and ceramics, and small gaps between adjacent grains are visible indicating the absence of conventional grain boundaries.


Author(s):  
L.R. Wallenberg ◽  
J.-O. Bovin ◽  
G. Schmid

Metallic clusters are interesting from various points of view, e.g. as a mean of spreading expensive catalysts on a support, or following heterogeneous and homogeneous catalytic events. It is also possible to study nucleation and growth mechanisms for crystals with the cluster as known starting point.Gold-clusters containing 55 atoms were manufactured by reducing (C6H5)3PAuCl with B2H6 in benzene. The chemical composition was found to be Au9.2[P(C6H5)3]2Cl. Molecular-weight determination by means of an ultracentrifuge gave the formula Au55[P(C6H5)3]Cl6 A model was proposed from Mössbauer spectra by Schmid et al. with cubic close-packing of the 55 gold atoms in a cubeoctahedron as shown in Fig 1. The cluster is almost completely isolated from the surroundings by the twelve triphenylphosphane groups situated in each corner, and the chlorine atoms on the centre of the 3x3 square surfaces. This gives four groups of gold atoms, depending on the different types of surrounding.


Carbon ◽  
2020 ◽  
Vol 161 ◽  
pp. 17-24 ◽  
Author(s):  
Yuanyuan Jiang ◽  
Zhanqiu Tan ◽  
Genlian Fan ◽  
Zhibo Zhang ◽  
Ding-Bang Xiong ◽  
...  

2018 ◽  
Vol 37 (15) ◽  
pp. 1020-1034 ◽  
Author(s):  
Christoph Lohr ◽  
Björn Beck ◽  
Frank Henning ◽  
Kay André Weidenmann ◽  
Peter Elsner

The MuCell process is a special injection molding process which utilizes supercritical gas (nitrogen) to create integral foam sandwiches. The advantages are lower weight, higher specific properties and shorter cycle times. In this study, a series of glass fiber-reinforced polyphenylene sulfide foam blanks are manufactured using the MuCell injection molding process. The different variations of the process (low-pressure also known as structural foam injection molding) and high-pressure foam injection molding (also known as “core back expansion,” “breathing mold,” “precision opening,” decompression molding) are used. The sandwich structure and mechanical properties (tensile strength, bending strength, and impact behavior) of the microcellular and glass fiber-reinforced polyphenylene sulfide foams are systematically investigated and compared to compact material. The results showed that the injection parameters (injection speed, foaming mechanism) played an important role in the relative density of microcellular polyphenylene sulfide foams and the mechanical properties. It could be shown that the specific tensile strength decreased while increasing the degree of foaming which can be explained by the increased number of cells and the resulting cell size. This leads to stress peaks which lower the mechanical properties. The Charpy impact strength shows a significant dependence on the fiber orientation. The specific bending modulus of the high-pressure foaming process, however, surpasses the values of the other two processes showing the potential of this manufacturing variation especially with regard to bending loads. Furthermore, a high dependence of the mechanical properties on the fiber orientation of the tested specimens can be found.


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