Developing an internally consistent set of theoretically based prediction models for the critical constants and normal boiling point of large n -alkanes

2017 ◽  
Vol 449 ◽  
pp. 104-116 ◽  
Author(s):  
Richard A. Messerly ◽  
Thomas A. Knotts ◽  
Neil F. Giles ◽  
W. Vincent Wilding
Keyword(s):  
Boiling Point ◽  
Prediction Models ◽  
Normal Boiling Point ◽  
Large N ◽  
Critical Constants

The Realization of the Normal Boiling Point of Neon

Metrologia ◽  
1978 ◽  
Vol 14 (1) ◽  
pp. 9-13 ◽  
Author(s):  
R C Kemp ◽  
W R G Kemp
Keyword(s):  
Boiling Point ◽  
Normal Boiling Point

Exciplex-Based Vapor/Liquid Visualization Systems Appropriate for Automotive Gasolines

1993 ◽  
Vol 47 (6) ◽  
pp. 782-786 ◽  
Author(s):  
Lynn A. Melton
Keyword(s):  
Cross Talk ◽  
Spectral Region ◽  
Boiling Point ◽  
Automotive Gasoline ◽  
Normal Boiling Point ◽  
Tertiary Amines ◽  
Temperature Range ◽  
Exciplex Emission ◽  
Visualization Systems ◽  
Vapor Liquid

This paper reports the development of exciplex-based vapor/liquid visualization systems based on exciplexes formed from tertiary amines and fluorine-substituted benzene and/or toluene. These systems are expected to be virtually coevaporative with solvents (fuels) boiling in the temperature range 70 to 110°C and thus are expected to track the vaporization of automotive gasoline effectively. A system consisting of 10% triethylamine/0.5% fluorobenzene/89.5% hexane should be coevaporative with a normal boiling point of 69°C. A system consisting of 10% n-propyldiethylamine/0.5% 4-fluorotoluene/89.5% isooctane should be coevaporative with a normal boiling point of approximately 100°C. Although the coevaporation of these systems is excellent, the exciplexes revert to varying extents to excited monomer at temperatures near 100°C. Thus there is considerable cross talk from the liquid into the vapor spectral region. The tertiary amines generally require excitation at wavelengths below 250 nm; the fluorobenzene or 4-fluorotoluene can be excited at 266 nm. Monomer emission peaks at 290 nm; exciplex emission peaks at 350 nm.

Prediction of vapor pressures and enthalpies of vaporization of organic compounds from the normal boiling point temperature

2006 ◽  
Vol 248 (1) ◽  
pp. 70-77 ◽  
Author(s):  
Eleni Panteli ◽  
Epaminondas Voutsas ◽  
Kostis Magoulas ◽  
Dimitrios Tassios
Keyword(s):  
Organic Compounds ◽  
Boiling Point ◽  
Normal Boiling Point ◽  
Vapor Pressures ◽  
Point Temperature

Prediction of Normal Boiling Point Temperature of Medium/High Molecular Weight Compounds

1995 ◽  
Vol 34 (3) ◽  
pp. 997-1002 ◽  
Author(s):  
Ioannis N. Tsibanogiannis ◽  
Nikolaos S. Kalospiros ◽  
Dimitrios P. Tassios
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Boiling Point ◽  
Normal Boiling Point ◽  
Point Temperature
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