Mechanisms on the stability and instability of water-in-oil emulsion stabilized by interfacially active asphaltenes: Role of hydrogen bonding reconstructing

Fuel ◽  
2021 ◽  
Vol 297 ◽  
pp. 120763
Author(s):  
Jun Ma ◽  
Yongli Yang ◽  
Xingang Li ◽  
Hong Sui ◽  
Lin He
2011 ◽  
Vol 189-193 ◽  
pp. 3153-3157
Author(s):  
Yan Zhen Zhang ◽  
Yong Hong Liu ◽  
Ren Jie Ji ◽  
Bao Ping Cai

In this paper, the EDM performance of water-in-oil (W/O) emulsions dielectric with different surfactant concentration is investigated by correlated to its physical properties, such as viscosity and droplets size, which is predominantly determined by the surfactant concentration. Experimental results show that the stability of the W/O emulsions increases with increasing surfactant concentration, whereas the EDM performance deteriorates with increasing surfactant concentration. So, taking a comprehensively consideration of the emulsion stability and EDM performance, the concentration of surfactant must be appropriately selected.


2021 ◽  
Vol 196 ◽  
pp. 107695
Author(s):  
Guangsheng Cao ◽  
Tong Du ◽  
Yujie Bai ◽  
Tingyuan Yang ◽  
Jize Zuo

2017 ◽  
Vol 7 (1) ◽  
pp. 29-37
Author(s):  
Hulya Cakmak ◽  
Gozde Ela Gurpuz ◽  
Neslihan Bozdogan ◽  
Seher Kumcuoglu ◽  
Sebnem Tavman

2013 ◽  
Author(s):  
M. Al-Yaari ◽  
A. Al-Sarkhi ◽  
I. Hussein ◽  
M. Abbad ◽  
F. Chang ◽  
...  

REAKTOR ◽  
2017 ◽  
Vol 6 (1) ◽  
pp. 29
Author(s):  
B. Pramudono ◽  
H. B. Mat

The stability of water-in-oil emulsion of some Malaysian crude oils was studied with particular emphasis on effect of interfacial active components existed in the crude oil, i.e. asphaltene, resin and wax. The emulsion stability was studied by measuring the volume of water or oil phase separated in variation with time, water hold up, and the heights of the sedimenting/coalescing interfaces during the separation at various temperatures. The study investigated the influence of asphaltene, resin and wax on emultion stability if it`s present in the crude oil alone, together or combination one of the others. The result show that the interfacial active component that stabilize emulsion is asphaltene. The resin and wax  do not form stale emulsion either aloneor together. There is a correlation between emulsion stability and physicochemical properties of crude oil which showed that higher asphaltene content in the crude oil would form more stable emultion. Increased temperature was found to cause instability of emultion. Keywords : emultion stability, crude oil, asphaltene, resin and wax


2015 ◽  
Vol 15 (4) ◽  
pp. 997-1008
Author(s):  
Małgorzata Tabaszewska ◽  
Tadeusz Grega ◽  
Dorota Najgebauer-Lejko ◽  
Grażyna Jaworska

Abstract The effect of 0, 1.5, 5, 10 and 15 (g 100 g-1 of emulsion) WPC 80 additive (80% whey protein concentrate) on the pH, physical, oxidative and microbiological stability of the water-in-oil emulsion was studied during 16-week storage at ~20°C at 4-week intervals. All determined features were significantly affected by the supplementation. The most beneficial as regards storage stability was the emulsion with 5% of WPC 80. This treatment was the most resistant to oxidative changes showing low increase of the concentration of conjugated diene hydroperoxides (from 0.92 to 1.04 mg g-1) and of the thiobarbituric acid reactive substances (from 0.83 to 1.37 mg malondialdehyde g-1) as well as only slight increment (by 0.47 log CFU g-1) of the microorganisms number during storage. Thus, the results of the present study revealed that whey proteins can be applied in the proper amount to produce cosmetic emulsions composed of natural ingredients and with reasonable storage stability.


Author(s):  
Yemima Ben-Menahem

This chapter examines the role of stability and determinism in physical theories such as statistical mechanics. In the physical sciences, the notions of stability and instability, no longer camouflaged in the language of necessity and contingency, are often used in a variety of contexts, from chaos theory to quantum mechanics. Physicists consider questions about the stability of states, orbits, and structures to be as fundamental as questions about determinism. Before expounding on the conceptual relations between stability and determinism in physics, the chapter discusses three interconnected problems that statistical mechanics has had to tackle: the meaning of probability in statistical mechanics, the link between probability and a system's dynamics, and the origin of directionality. It shows that the notions of determinism and stability are often conflated, giving rise to teleological thinking.


Author(s):  
Norela Jusoh ◽  
Norasikin Othman

Emulsion liquid membrane (ELM) process have shown a great potential in wide application of industrial separations such as in removal of many chemicals, organic compounds, metal ions, pollutants and biomolecules. ELM promotes many advantages including simple operation, non-equilibrium mass transfer, high selectivity, low energy requirements, and simultaneous extraction and stripping process in a single step process. New development in ELM system incorporated with a green solvent (palm oil) was attempted instead of using commercial organic solvent. The important aspects must be considered for a successful ELM process is the stability of the liquid membrane. In the current work the effect of various parameter which are organic to internal ratio, emulsifying speed, surfactant concentration, and emulsifying time on green ELM stability was investigated. The results show that the most stable emulsion was observed at 3:1 organic to internal ratio, 7000 rpm speed, 3 % (w/v) surfactant concentration, and 5 minute emulsifying time. The emulsion obtained was stable up to 1/2 hour and sufficient and sufficient for extraction process. Therefore, green solvent has high potential to be applied in emulsion liquid membrane process. 


Author(s):  
N. H. Abdurahman ◽  
H. A. Magdib

The purpose of this research is to look into the formulation and evaluation of concentrated water-in-oil (W/O) emulsions stabilized by UMP NS-19-02 surfactant and their application for crude oil emulsion stabilization using gummy Malaysian crude oil. A two-petroleum oil from Malaysia oil refinery, i.e., Tapis petroleum oil and Tapis- Mesilla blend, were utilized to make water-in-oil emulsions. The various factors influencing emulsion characteristics and stability were evaluated. It was discovered that the stability of the water-in-oil emulsion improved by UMP NS-19-02 improved as the surfactant content rises, resulting in the decline of the crude oil-water interfacial tension (IFT). Nevertheless, the most optimum formulation of W/O emulsion was a 50:50 W/O ratio with 1.0% surfactant. Additionally, raising the oil content, salt concentration, duration and mixing speed, and pH of the emulsion resulted in higher emulsion stability. It also raised the temperature of the initial mixing, which significantly decreased the formulated emulsions' viscosity. The results showed that stable emulsions could be formed using the UMP NS-19-02 surfactant.


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