scholarly journals Experimental study of the kinetics of degradation of n-dodecane under thermo-oxidative stress at low temperature and mechanism inferred

Fuel ◽  
2022 ◽  
Vol 307 ◽  
pp. 121669
Author(s):  
Soraya Aminane ◽  
Mickaël Sicard ◽  
Yanis Melliti ◽  
Frédéric Ser ◽  
Lorette Sicard
Keyword(s):  
Oxidative Stress ◽  
Experimental Study ◽  
Low Temperature ◽  
Kinetics Of Degradation ◽  
Kinetics Of

Nature of Charged Metastable Defects in Network Rebonding Model

2002 ◽  
Vol 715 ◽  
Author(s):  
R. Biswas ◽  
B. C. Pan
Keyword(s):  
Low Temperature ◽  
Rate Equations ◽  
Atomistic Model ◽  
Dangling Bonds ◽  
Defect Creation ◽  
Higher Temperature ◽  
Kinetics Of Degradation ◽  
Kinetics Of ◽  
Defect Densities ◽  
Positively Charged

AbstractWe recently developed an atomistic model of metastability of a-Si:H, where defect creation is driven by the breaking of weak silicon bonds. The kinetics of degradation in this model is simulated with coupled rate equations that show t1/3 kinetics of defect creation and saturation behavior similar to experiment. Saturated defect densities of neutral dangling bonds are accompanied by a much smaller density of negatively charged floating bonds and positively charged dangling bonds (D+). We propose a two-step annealing mechanism where the positively charged D+ dangling bonds are annealed at low temperature and the D0 at higher temperature -which accounts for hysteresis in mobility lifetime products.

The low temperature aluminising kinetics of hot-work tool steels

2012 ◽  
Vol 67 (2) ◽  
pp. 133-139
Author(s):  
B. Matijević ◽  
I. Kumić ◽  
T. Belić
Keyword(s):  
Low Temperature ◽  
Tool Steels ◽  
Kinetics Of ◽  
Hot Work Tool Steels

Kinetics of catalytic conversion of methanol at higher pressures

1980 ◽  
Vol 45 (12) ◽  
pp. 3402-3407 ◽  
Author(s):  
Jaroslav Bartoň ◽  
Vladimír Pour
Keyword(s):  
Low Temperature ◽  
Reaction Kinetics ◽  
Water Vapour ◽  
Kinetic Data ◽  
Catalytic Conversion ◽  
The Given ◽  
Kinetics Of

The course of the conversion of methanol with water vapour was followed on a low-temperature Cu-Zn-Cr-Al catalyst at pressures of 0.2 and 0.6 MPa. The kinetic data were evaluated together with those obtained at 0.1 MPa and the following equation for the reaction kinetics at the given conditions was derived: r = [p(CH3OH)p(H2O)]0.5[p(H2)]-1.3.

scholarly journals Factors Affecting the Dependency of Shear Strain of LRB and SHDR: Experimental Study

Actuators ◽  
2021 ◽  
Vol 10 (5) ◽  
pp. 98
Author(s):  
Chao-Yong Shen ◽  
Xiang-Yun Huang ◽  
Yang-Yang Chen ◽  
Yu-Hong Ma
Keyword(s):  
Experimental Study ◽  
Low Temperature ◽  
Shear Strain ◽  
Loading Frequency ◽  
Loading Test ◽  
Characteristic Strength ◽  
Rubber Bearing ◽  
Dominant Feature ◽  
Loading Sequence ◽  
G Value

In this research we conducted a sensitivity experimental study where we explored the dependency of the shear strain on the seismic properties of bearings, namely lead rubber bearing (LRB) and super high damping rubber bearing (SHDR). The factors studied were vertical pressure, temperature, shear modulus of the inner rubber (G value), loading frequency, and loading sequence. Six specimens were adopted, i.e., three LRBs and three SHDR bearings. A series of test plans were designed. The seismic characteristics of the bearings were captured through a cyclic loading test, which included post-yield stiffness, characteristic strength, area of a single cycle of the hysteretic loop, equivalent stiffness, and equivalent damping ratio. A whole analysis of variances was then conducted. At the same time, to explore certain phenomena caused by the factors, an extended discussion was carried out. Test results showed that the temperature is the most dominant feature, whereas the G value is the least contributing factor, with the effect of the loading frequency and the loading sequence found between these two. The increment of the post-yielded stiffness for LRB from 100% to 25% is a significant reduction from a low temperature to high one. The slope of the characteristic strength versus the shear strain for LRB under high temperature is larger than the one under low temperature.

scholarly journals Comparative Study of Chemical Stability of Two H1Antihistaminic Drugs, Terfenadine and ItsIn VivoMetabolite Fexofenadine, Using LC-UV Methods

2019 ◽  
Vol 2019 ◽  
pp. 1-10
Author(s):  
Anna Gumieniczek ◽  
Anna Berecka-Rycerz ◽  
Rafał Pietraś ◽  
Izabela Kozak ◽  
Karolina Lejwoda ◽  
...  
Keyword(s):  
Comparative Study ◽  
Chemical Stability ◽  
First Order ◽  
First Order Kinetics ◽  
Kinetics Of Degradation ◽  
Effects Of Temperature ◽  
High Doses ◽  
Antihistaminic Drugs ◽  
Kinetics Of

A comparative study of chemical stability of terfenadine (TER) and itsin vivometabolite fexofenadine (FEX) was performed. Both TER and FEX were subjected to high temperature at different pH and UV/VIS light at different pH and then quantitatively analyzed using new validated LC-UV methods. These methods were used to monitor the degradation processes and to determine the kinetics of degradation for both the compounds. As far as the effects of temperature and pH were concerned, FEX occurred more sensitive to degradation than TER. As far as the effects of UV/VIS light and pH were concerned, the both drugs were similarly sensitive to high doses of light. Using all stress conditions, the processes of degradation of TER and FEX followed the first-order kinetics. The results obtained for these two antihistaminic drugs could be helpful in developing their new derivatives with higher activity and stability at the same time.

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