Effect of zinc addition on catalytic properties of PtSnK/γ-Al2O3 catalyst for isobutane dehydrogenation

2012 ◽  
Vol 96 ◽  
pp. 220-227 ◽  
Author(s):  
Yiwei Zhang ◽  
Yuming Zhou ◽  
Junjun Shi ◽  
Xiaoli Sheng ◽  
Yongzheng Duan ◽  
...  
2011 ◽  
Vol 50 (8) ◽  
pp. 4280-4285 ◽  
Author(s):  
Lihui Wan ◽  
Yuming Zhou ◽  
Yiwei Zhang ◽  
Yongzheng Duan ◽  
Xuan Liu ◽  
...  

2021 ◽  
Vol 10 (3) ◽  
pp. 01-08
Author(s):  
Khalid Ouzaouit ◽  
Abdelhay Aboulaich

The present paper describes the synthesis and first application of Nd-doped BaCeO3 nanoparticles as catalyst for the catalytic oxidation of methane (CH4) into CO2. Nd-doped barium cerate BaCeO3 nanoparticles, with the formula BaNdxCe(1-x)O3, have been prepared using a simple sol gel method starting from acetate precursors. The as-prepared nanoparticles have been fully characterized by XRD, TEM, HRTEM and specific surface area measurement. Results confirmed the formation of highly crystallized nano-sized particles with small crystallite size. In-situ FTIR spectroscopy was used to study the catalytic conversion of methane (CH4) into CO2 in the presence of the as-prepared Nd-doped BaCeO3 nanocatalyst. The catalytic properties of such nanocatalysts have been discussed and correlated to Nd-doping rate, crystallite diameter, and specific surface area of the materials. Excellent catalytic properties have been obtained with BaNd0.05Ce0.95O3, such as, superior conversion efficiency, longer catalysis lifetime and lower activation temperature compared to un-doped BaCeO3 catalyst. Interestingly, it was found that BaNd0.05Ce0.95O3 nanocatalyst successfully converts the totality of CH4 present in a mixture of CH4-Air into CO2 at much lower temperature compared to the conventional Pd/Al2O3 catalyst.


2020 ◽  
Vol 381 ◽  
pp. 122741 ◽  
Author(s):  
Anna N. Matveyeva ◽  
Johan Wärnå ◽  
Nikolai A. Pakhomov ◽  
Dmitry Yu. Murzin

2007 ◽  
Vol 25 (5) ◽  
pp. 585-589 ◽  
Author(s):  
Liu Zhimin ◽  
Chen Yaoqiang ◽  
Zhong Junbo ◽  
Wang Jianli ◽  
Yan Shenghui ◽  
...  

Energies ◽  
2020 ◽  
Vol 13 (14) ◽  
pp. 3684
Author(s):  
Sukhe Badmaev ◽  
Vladimir Sobyanin

The catalytic properties of CuO-CeO2 supported on alumina for the oxidative steam reforming (OSR) of dimethoxymethane (DMM) to hydrogen-rich gas in a tubular fixed bed reactor were studied. The CuO-CeO2/γ-Al2O3 catalyst provided complete DMM conversion and hydrogen productivity > 10 L h−1 gcat−1 at 280 °C, GHSV (gas hourly space velocity) = 15,000 h−1 and DMM:O2:H2O:N2 = 10:2.5:40:47.5 vol.%. Comparative studies showed that DMM OSR exceeded DMM steam reforming (SR) and DMM partial oxidation (PO) in terms of hydrogen productivity. Thus, the outcomes of lab-scale catalytic experiments show high promise of DMM oxidative steam reforming to produce hydrogen-rich gas for fuel cell feeding.


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