Hydrogenation of CO2 to formic acid catalyzed by heterogeneous Ru-PPh3/Al2O3 catalysts

2018 ◽  
Vol 178 ◽  
pp. 98-103 ◽  
Author(s):  
Wenjing Zhang ◽  
Shengping Wang ◽  
Yujun Zhao ◽  
Xinbin Ma
Keyword(s):  
Formic Acid ◽  
Hydrogenation Of Co2 ◽  
Acid Catalyzed

Continuous-flow formic acid production from the hydrogenation of CO2 without any base

2021 ◽  
Vol 23 (5) ◽  
pp. 1978-1982
Author(s):  
Zhaofu Zhang ◽  
Shuaishuai Liu ◽  
Minqiang Hou ◽  
Guangying Yang ◽  
Buxing Han
Keyword(s):  
Formic Acid ◽  
Continuous Flow ◽  
Acid Production ◽  
Hydrogenation Of Co2 ◽  
Hydrogenation Of Co

Continuous-flow formic acid production from the hydrogenation of CO2 without any base, and the concentration of formic acid by electrodialysis was tested both offline and online.

Electro-oxidation of formic acid catalyzed by FePt nanoparticles

2006 ◽  
Vol 8 (23) ◽  
pp. 2779 ◽  
Author(s):  
Wei Chen ◽  
Jaemin Kim ◽  
Shouheng Sun ◽  
Shaowei Chen
Keyword(s):  
Formic Acid ◽  
Fept Nanoparticles ◽  
Electro Oxidation ◽  
Acid Catalyzed

Acid-catalyzed Solvolysis of Isonitriles. I

1971 ◽  
Vol 49 (14) ◽  
pp. 2455-2459 ◽  
Author(s):  
Y. Y. Lim ◽  
A. R. Stein
Keyword(s):  
Formic Acid ◽  
Acid Catalysis ◽  
Hydrolysis Product ◽  
Rate Dependence ◽  
Linear Rate ◽  
First Order ◽  
Methyl Amine ◽  
Acid Catalyzed ◽  
Pseudo First Order ◽  
Hydrolysis Of

The acid-catalyzed hydrolysis of methyl isonitrile has been examined. The initial hydrolysis product is N-methylformamide which is further hydrolyzed to methyl amine and formic acid at a much slower rate. The hydrolysis to N-methylformamide is pseudo-first order in methyl isonitrile and shows a linear rate dependence on concentration of general (buffer) acid at fixed pH. The significance of general acid-catalysis in terms of the mechanism of the hydrolysis is considered and taken as evidence for carbon protonation rather than nitrogen protonation as the initiating step.

Efficient hydrogenation of CO2 to formic acid over amorphous NiRuB catalysts

2021 ◽  
Vol 54 ◽  
pp. 101751
Author(s):  
Jiehong He ◽  
Shaoshuai Chang ◽  
Haoran Du ◽  
Bo Jiang ◽  
Wenzhao Yu ◽  
...  
Keyword(s):  
Formic Acid ◽  
Hydrogenation Of Co2

Room Temperature Reduction of Graphene Oxide by Formic Acid Catalyzed by Platinum Nanoparticles

2013 ◽  
Vol 13 (4) ◽  
pp. 2967-2973 ◽  
Author(s):  
Yinjie Wang ◽  
Jincheng Liu ◽  
Lei Liu ◽  
Tong Zhang ◽  
Darren D. Sun
Keyword(s):  
Graphene Oxide ◽  
Formic Acid ◽  
Platinum Nanoparticles ◽  
Room Temperature ◽  
Temperature Reduction ◽  
Acid Catalyzed

Hydrogenation of CO2 to formic acid on the single atom catalysis Cu/C2N: A first principles study

2019 ◽  
Vol 488 ◽  
pp. 1-9 ◽  
Author(s):  
Junmei Ma ◽  
Hongwei Gong ◽  
Tong Zhang ◽  
Hong Yu ◽  
Rong Zhang ◽  
...  
Keyword(s):  
Formic Acid ◽  
First Principles ◽  
Single Atom ◽  
Hydrogenation Of Co2 ◽  
First Principles Study

Chromium-catalysed efficient N-formylation of amines with a recyclable polyoxometalate-supported green catalyst

2021 ◽  
Vol 50 (1) ◽  
pp. 90-94
Author(s):  
Demin Dan ◽  
Fubo Chen ◽  
Whenshu Zhao ◽  
Han Yu ◽  
Sheng Han ◽  
...  
Keyword(s):  
Formic Acid ◽  
Green Catalyst ◽  
Chromium Catalyst ◽  
Acid Catalyzed

A simple and efficient protocol for the formylation of amines with formic acid, catalyzed by a polyoxometalate-based chromium catalyst, is described.

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