Kinetics of FeII-polyaminocarboxylate oxidation by molecular oxygen

2018 ◽  
Vol 225 ◽  
pp. 116-127 ◽  
Author(s):  
Jessica M. Wilson ◽  
Kevin J. Farley ◽  
Richard F. Carbonaro
Keyword(s):  
Molecular Oxygen ◽  
Oxidation By Molecular Oxygen ◽  
Kinetics Of

Kinetics of Soot Oxidation by Molecular Oxygen in a Premixed Flame

2016 ◽  
Vol 30 (4) ◽  
pp. 3463-3472 ◽  
Author(s):  
Hossein Ghiassi ◽  
Isabel C. Jaramillo ◽  
JoAnn S. Lighty
Keyword(s):  
Molecular Oxygen ◽  
Soot Oxidation ◽  
Premixed Flame ◽  
Oxidation By Molecular Oxygen ◽  
Kinetics Of

Chemical Kinetics of Methyl Oxidation by Molecular Oxygen

1995 ◽  
Vol 99 (39) ◽  
pp. 14377-14387 ◽  
Author(s):  
C.-L. Yu ◽  
C. Wang ◽  
M. Frenklach
Keyword(s):  
Molecular Oxygen ◽  
Chemical Kinetics ◽  
Oxidation By Molecular Oxygen ◽  
Kinetics Of

Copper(II)-catalyzed oxidation of carbon monoxide by molecular oxygen

1967 ◽  
Vol 45 (24) ◽  
pp. 3025-3030 ◽  
Author(s):  
J. J. Byerley ◽  
Jolland Y. H. Lee
Keyword(s):  
Activation Energy ◽  
Carbon Monoxide ◽  
Aqueous Solutions ◽  
Molecular Oxygen ◽  
Rate Determining Step ◽  
Oxidation By Molecular Oxygen ◽  
Kinetics Of ◽  
Equilibrium Step ◽  
Catalyzed Oxidation ◽  
Oxidation Of Carbon Monoxide

The kinetics of the copper (II)-catalyzed oxidation of carbon monoxide by molecular oxygen, i.e. [Formula: see text] have been investigated in aqueous solutions at 120 °C. The rate law was found to be of the form −d[O2]/dt = kexpt[O2][CO][Cu(II)]/[H+], where kexpt = 7.88 × 10−6 M−1 s−1 in 0.25 M acetate solutions. The apparent activation energy is 29 600 cal/mole. The rate-determining step of the reaction appears to be the oxidation by molecular oxygen of a carbon monoxide insertion complex [Formula: see text] formed in the pre-equilibrium step.

scholarly journals Kinetics of 1- and 2-methylallyl + O2 reaction, investigated by photoionisation using synchrotron radiation

2021 ◽  
Author(s):  
Domenik Schleier ◽  
Engelbert Reusch ◽  
Marius Gerlach ◽  
Tobias Preitschopf ◽  
Deb Pratim Mukhopadhyay ◽  
...  
Keyword(s):  
Synchrotron Radiation ◽  
Reaction Kinetics ◽  
Molecular Oxygen ◽  
Light Source ◽  
Storage Ring ◽  
Vacuum Ultraviolet ◽  
Flow Tube ◽  
Tube Reactor ◽  
Swiss Light Source ◽  
Kinetics Of

The reaction kinetics of the isomers of the methylallyl radical with molecular oxygen has been studied in a flow tube reactor at the vacuum ultraviolet (VUV) beamline of the Swiss Light Source storage ring.

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