Kinetics of nascent soot oxidation by molecular oxygen in a flow reactor

2015 ◽  
Vol 35 (2) ◽  
pp. 1887-1894 ◽  
Author(s):  
Joaquin Camacho ◽  
Yujie Tao ◽  
Hai Wang
Keyword(s):  
Molecular Oxygen ◽  
Flow Reactor ◽  
Soot Oxidation ◽  
Oxidation By Molecular Oxygen ◽  
Kinetics Of

Kinetics of Soot Oxidation by Molecular Oxygen in a Premixed Flame

2016 ◽  
Vol 30 (4) ◽  
pp. 3463-3472 ◽  
Author(s):  
Hossein Ghiassi ◽  
Isabel C. Jaramillo ◽  
JoAnn S. Lighty
Keyword(s):  
Molecular Oxygen ◽  
Soot Oxidation ◽  
Premixed Flame ◽  
Oxidation By Molecular Oxygen ◽  
Kinetics Of

Kinetics of FeII-polyaminocarboxylate oxidation by molecular oxygen

2018 ◽  
Vol 225 ◽  
pp. 116-127 ◽  
Author(s):  
Jessica M. Wilson ◽  
Kevin J. Farley ◽  
Richard F. Carbonaro
Keyword(s):  
Molecular Oxygen ◽  
Oxidation By Molecular Oxygen ◽  
Kinetics Of

Chemical Kinetics of Methyl Oxidation by Molecular Oxygen

1995 ◽  
Vol 99 (39) ◽  
pp. 14377-14387 ◽  
Author(s):  
C.-L. Yu ◽  
C. Wang ◽  
M. Frenklach
Keyword(s):  
Molecular Oxygen ◽  
Chemical Kinetics ◽  
Oxidation By Molecular Oxygen ◽  
Kinetics Of

Copper(II)-catalyzed oxidation of carbon monoxide by molecular oxygen

1967 ◽  
Vol 45 (24) ◽  
pp. 3025-3030 ◽  
Author(s):  
J. J. Byerley ◽  
Jolland Y. H. Lee
Keyword(s):  
Activation Energy ◽  
Carbon Monoxide ◽  
Aqueous Solutions ◽  
Molecular Oxygen ◽  
Rate Determining Step ◽  
Oxidation By Molecular Oxygen ◽  
Kinetics Of ◽  
Equilibrium Step ◽  
Catalyzed Oxidation ◽  
Oxidation Of Carbon Monoxide

The kinetics of the copper (II)-catalyzed oxidation of carbon monoxide by molecular oxygen, i.e. [Formula: see text] have been investigated in aqueous solutions at 120 °C. The rate law was found to be of the form −d[O2]/dt = kexpt[O2][CO][Cu(II)]/[H+], where kexpt = 7.88 × 10−6 M−1 s−1 in 0.25 M acetate solutions. The apparent activation energy is 29 600 cal/mole. The rate-determining step of the reaction appears to be the oxidation by molecular oxygen of a carbon monoxide insertion complex [Formula: see text] formed in the pre-equilibrium step.

Kinetics of the catalytic hydrodesulphurization reaction system; hydrogenolysis of thiophene

1980 ◽  
Vol 45 (10) ◽  
pp. 2728-2741 ◽  
Author(s):  
Pavel Fott ◽  
Petr Schneider
Keyword(s):  
Atmospheric Pressure ◽  
Active Sites ◽  
Flow Reactor ◽  
Kinetic Equations ◽  
Reaction System ◽  
Reaction Products ◽  
Molybdenum Catalyst ◽  
Cobalt Molybdenum Catalyst ◽  
Kinetics Of ◽  
Reaction Schemes

Kinetics have been studied of the reaction system taking place during the reaction of thiophene on the cobalt-molybdenum catalyst in a gradientless circulation flow reactor at 360 °C and atmospheric pressure. Butane has been found present in a small amount in the reaction products even at very low conversion. In view of this, consecutive and parallel-consecutive (triangular) reaction schemes have been proposed. In the former scheme the appearance of butane is accounted for by rate of desorption of butene being comparable with the rate of its hydrogenation. According to the latter scheme part of the butane originates from thiophene via a different route than through hydrogenation of butene. Analysis of the kinetic data has revealed that the reaction of thiophene should be considered to take place on other active sites than that of butene. Kinetic equations derived on this assumption for the consecutive and the triangular reaction schemes correlate experimental data with acceptable accuracy.

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