scholarly journals Dynamic modelling of an industrial copper solvent extraction process

2006 ◽  
Vol 81 (1) ◽  
pp. 52-61 ◽  
Author(s):  
Tiina Komulainen ◽  
Pertti Pekkala ◽  
Ari Rantala ◽  
Sirkka-Liisa Jämsä-Jounela
2015 ◽  
Vol 1130 ◽  
pp. 55-58
Author(s):  
Xiao Rong Liu ◽  
Chang Su ◽  
Dao Jie Chi ◽  
Xue Song Zheng ◽  
Hua Long Yu ◽  
...  

In the bioleaching - solvent extraction - electrowinning practices for copper extraction, the solvent extraction process is used to enrich the copper in the leachate to a high lever to make the sequent electrowinning process possible. O/W type of interfacial emulsion always forms at the interface between organic phase and aqueous phase in the solvent extraction practices. Diversified microorganisms were discovered by microscope growing in the interface emulsion of copper solvent extraction. The diversity of them was analyzed by using 16s rRNA gene sequencing. It was indicated that there exist seven categories of bacteria in the interface emulsion, among which common bioleaching bacteria, such as Leptospirillum sp.,Acidithiobacillus ferrooxidans, Metallibacterium sp., are included. The dominant strains are Leptospirillum sp. E4-L9 and Acidithiobacillus ferrooxidans ATCC 23270, which account up to 40.48 % and 38.1 %, respectively. It was uncovered that bioleaching bacteria can be intercepted by interfacial emulsion of solvent extraction to make their population in the raffinate lower and the efficiency of bioleaching decrease consequently.


2005 ◽  
Vol 38 (1) ◽  
pp. 223-228
Author(s):  
Tiina Komulainen ◽  
Ari Rantala ◽  
Sirkka-Liisa Jämsä-Jounela

2009 ◽  
Vol 19 (1) ◽  
pp. 2-15 ◽  
Author(s):  
Tiina Komulainen ◽  
Francis J. Doyle III ◽  
Ari Rantala ◽  
Sirkka-Liisa Jämsä-Jounela

2009 ◽  
Vol 22 (15) ◽  
pp. 1350-1358 ◽  
Author(s):  
C.M. Moreno ◽  
J.R. Pérez-Correa ◽  
A. Otero

2010 ◽  
Vol 3 (1) ◽  
pp. 49-56 ◽  
Author(s):  
Navid Mostoufi ◽  
Ali Faridkhou ◽  
Rahmat Sotudeh Gharebagh ◽  
Hamid Reza Norouzi

2014 ◽  
Vol 908 ◽  
pp. 18-21
Author(s):  
Yan Jun Liu ◽  
Xiao Rong Liu ◽  
Hui Li ◽  
Yong Sheng Li ◽  
Qing Li ◽  
...  

Effects of extraction-stripping loops of organic phase on organic chemical entrainment in the aqueous raffinate in copper solvent extraction were studied in this paper. Results demonstrated that the total amount of organic chemicals lost in the aqueous raffinate decreased with the increase of times of extraction-stripping loops but reached largest at third loop. Entrainment was the dominate way of organic chemicals losing in the aqueous raffinate at early stage of the loops. The formation of entrainment and its stabilization mechanism was also studied. The average size of entrained droplet trended to increase with extraction-stripping loops increasing. Meanwhile, the absolute value of zeta potential trended to decrease. The surface tension of the aqueous raffinate increased after reaching the minimum value 41.3 mN/m at the 3rd loop. It showed that the formation of entrained droplets and its stability were mainly affected by the surface tension of aqueous raffinate.


Minerals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 61
Author(s):  
Wenjie Zhang ◽  
Xian Xie ◽  
Xiong Tong ◽  
Yunpeng Du ◽  
Qiang Song ◽  
...  

Solvent extraction is the most widely used method for separation and purification of rare earth elements, and organic extractants such as di(2-ethylhexyl) phosphoric acid (P204) and di(1-methyl-heptyl) methyl phosphonate (P350) are most commonly used for industrial applications. However, the presence of impurity ions in the feed liquid during extraction can easily emulsify the extractant and affect the quality of rare earth products. Aluminum ion is the most common impurity ion in the feed liquid, and it is an important cause of emulsification of the extractant. In this study, the influence of aluminum ion was investigated on the extraction of light rare earth elements by the P204-P350 system in hydrochloric acid medium. The results show that Al3+ competes with light rare earths in the extraction process, reducing the overall extraction rate. In addition, the Al3+ stripping rate is low and there is continuous accumulation of Al3+ in the organic phase during the stripping process, affecting the extraction efficiency and even causing emulsification. The slope method and infrared detection were utilized to explore the formation of an extraction compound of Al3+ and the extractant P204-P350 that entered the organic phase as AlCl[(HA)2]2P350(o).


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