Two structural types of dithiocarbamato-chlorido complexes of mercury(II): Preparation, supramolecular self-assembly, solid-state 13C and 15N NMR characterisation and thermal behaviour of pseudo-polymeric compounds of [Hg2(S2CNBu2)2Cl2] and [Hg4(S2CNiBu2)6][Hg2Cl6]

Mechanochemistry and accelerated aging are new routes to zirconium metal–organic frameworks, yielding UiO-66 and catalytically active UiO-66-NH2 accessible on the gram scale through mild solid-state self-assembly, without strong acids, high temperatures or excess reactants.

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Solid-state 15N NMR studies of the effects of penicillin on cell-wall metabolism of Aerococcusviridans (Gaffkyahomari)

Biochemical and Biophysical Research Communications ◽

10.1016/0006-291x(85)90285-2 ◽

1985 ◽

Vol 126 (3) ◽

pp. 1006-1012 ◽

Cited By ~ 13

Author(s):

G.Edwin Wilson ◽

Gary S. Jacob ◽

Jacob Schaefer

Keyword(s):

Cell Wall ◽

Solid State ◽

15N Nmr ◽

Cell Wall Metabolism ◽

Nmr Studies

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Supramolecular Self-Assembly of V-Shaped Water Trimers and Diethylenetriamine Molecules in a New Solid State Ferrous Molybdenum(V) Phosphate

Journal of Cluster Science ◽

10.1007/s10876-012-0545-0 ◽

2013 ◽

Vol 24 (1) ◽

pp. 243-257 ◽

Cited By ~ 1

Author(s):

Yunshan Zhou ◽

Sadaf ul Hassan ◽

Lijuan Zhang ◽

Xianqi Li ◽

Waqar Ahmad

Keyword(s):

Solid State ◽

Self Assembly

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Correlation of the solid-state reactivities of racemic 2,4(6)-di-O-benzoyl-myo-inositol 1,3,5-orthoformate and its 4,4′-bipyridine cocrystal with their crystal structures

Acta Crystallographica Section C Structural Chemistry ◽

10.1107/s2053229614021834 ◽

2014 ◽

Vol 70 (11) ◽

pp. 1040-1045 ◽

Cited By ~ 4

Author(s):

Majid I. Tamboli ◽

Vir Bahadur ◽

Rajesh G. Gonnade ◽

Mysore S. Shashidhar

Keyword(s):

Solid State ◽

Self Assembly ◽

Transfer Reaction ◽

Acyl Transfer ◽

Transfer Reactions ◽

Group Transfer ◽

Hydrogen Bonding Interactions ◽

Benzoyl Group ◽

The Stability ◽

Group Migration

Racemic 2,4(6)-di-O-benzoyl-myo-inositol 1,3,5-orthoformate, C21H18O8,(1), shows a very efficient intermolecular benzoyl-group migration reaction in its crystals. However, the presence of 4,4′-bipyridine molecules in its cocrystal, C21H18O8·C10H8N2,(1)·BP, inhibits the intermolecular benzoyl-group transfer reaction. In(1), molecules are assembled around the crystallographic twofold screw axis (baxis) to form a helical self-assembly through conventional O—H...O hydrogen-bonding interactions. This helical association places the reactive C6-O-benzoyl group (electrophile, El) and the C4-hydroxy group (nucleophile, Nu) in proximity, with a preorganized El...Nu geometry favourable for the acyl transfer reaction. In the cocrystal(1)·BP, the dibenzoate and bipyridine molecules are arranged alternately through O—H...N interactions. The presence of the bipyridine molecules perturbs the regular helical assembly of the dibenzoate molecules and thus restricts the solid-state reactivity. Hence, unlike the parent dibenzoate crystals, the cocrystals do not exhibit benzoyl-transfer reactions. This approach is useful for increasing the stability of small molecules in the crystalline state and could find application in the design of functional solids.

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