Design and simulation of high efficiency lead-free heterostructure perovskite solar cell using SCAPS-1D

Optik ◽  
2021 ◽  
Vol 229 ◽  
pp. 166258
Author(s):  
S. Yasin ◽  
T. Al Zoubi ◽  
M. Moustafa
2017 ◽  
Vol 2017 ◽  
pp. 1-9 ◽  
Author(s):  
Farhana Anwar ◽  
Rafee Mahbub ◽  
Sakin Sarwar Satter ◽  
Saeed Mahmud Ullah

Simulation has been done using SCAPS-1D to examine the efficiency of CH3NH3SnI3-based solar cells including various HTM layers such as spiro-OMeTAD, Cu2O, and CuSCN. ZnO nanorod array has been considered as an ETM layer. Device parameters such as thickness of the CH3NH3SnI3 layer, defect density of interfaces, density of states, and metal work function were studied. For optimum parameters of all three structures, efficiency of 20.21%, 20.23%, and 18.34% has been achieved for spiro-OMeTAD, Cu2O, and CuSCN, respectively. From the simulations, an alternative lead-free perovskite solar cell is introduced with the CH3NH3SnI3 absorber layer, ZnO nanorod ETM layer, and Cu2O HTM layer.


2021 ◽  
Author(s):  
Zeyu Zhang ◽  
Qingde Sun ◽  
Yue Lu ◽  
Feng Lu ◽  
Xulin Mu ◽  
...  

Abstract Development of the stable, lead-free inorganic perovskite material is of greatly importance on fabricating the third-generation solar cell. Until now, double perovskite, such as Cs2AgBiBr6, has been proved to be one of the most potential candidates to solve the toxicity and stability issues of traditional lead halide perovskite solar cells (PSCs). However, due to a wide and indirect bandgap of Cs2AgBiBr6 film, its light absorption ability is largely limited and the photoelectronic conversion efficiency (PCE) is normally lower than 2.5%. In this text, by using a hydrogenation method, the bandgap (Eg) of Cs2AgBiBr6 films could be tunable from 2.14 eV to 1.61 eV. At the same time, the highest PCE of hydrogenated Cs2AgBiBr6 perovskite solar cell has been improved more than 150% up to 6.27%. To the best of our knowledge, this is a record high efficiency of Cs2AgBiBr6-based perovskite solar cell. Further investigations confirmed that the interstitial doping of atomic hydrogen (H*) in Cs2AgBiBr6 lattice could not only adjust its valence and conduction band energy levels, but also optimize the carrier mobility from 1.71 cm2V-1s-1 to 9.28 cm2V-1s-1 and enhance the carrier lifetime from 18.85 ns to 41.86 ns. All these works provide a new strategy to fabricate the high performance lead-free inorganic PSCs.


Solar Energy ◽  
2019 ◽  
Vol 186 ◽  
pp. 323-327 ◽  
Author(s):  
Weihong Chang ◽  
Hanmin Tian ◽  
Guochuan Fang ◽  
Dan Guo ◽  
Zheng Wang ◽  
...  

2020 ◽  
Vol 14 ◽  

T Perovskite solar cells are becoming a dominant alternative for the traditional solar cells reaching an efficiency of 25.2% in a short span of twelve years (2008-2020). Here, we are going to describe a simple process to 'put a voice on a laser beam' and transmit it over a distance via a perovskite solar cell. This process considered as a fascinating example of amplitude modulation of light using sound vibrations. Therefore, the design and simulation of the perovskite solar cell will be described in details in this work. This design is concerned about the lead-free based perovskite solar cell model with the total proposed structure “Metal contact /PEDOT:PSS/ CH3NH3SnI3/ ZnO/ SnO2:F/ Metal contact”. To study the efficiency and the performances of a solar cell, the use of well-known software so-called SCAPS-1D is undertaken to perform the system simulation. The obtained results show also the influence of the doping level of the HTM layer and absorber layer thickness on the performance of the device. So far, only the simulation part has been validated. Despite the costeffect of the system prototype, however, it could be implemented here in the laboratory as perspective work.


2021 ◽  
Vol 2021 ◽  
pp. 1-12
Author(s):  
Syed Sajjad Hussain ◽  
Saira Riaz ◽  
Ghazi Aman Nowsherwan ◽  
Khizer Jahangir ◽  
Akram Raza ◽  
...  

The highest power conversion efficiency (PCE) for organic-inorganic perovskite solar cells based on lead is reported as 25.2% in 2019. Lead-based hybrid perovskite materials are used in several photovoltaics applications, but these are not highly favored due to the toxicity of lead and volatility of organic cations. On the other hand, hybrid lead-free double perovskite has no such harm. In this research study, SCAPS numerical simulation is utilized to evaluate and compare the results of perovskite solar cell based on double perovskite FA 2 BiCuI 6 and standard perovskite CH 3 NH 3 PbI 3 as an active layer. The results show that the power conversion efficiency obtained in the case of FA 2 BiCuI 6 is 24.98%, while in the case of CH 3 NH 3 PbI 3 , it is reported as 26.42%. This indicates that the hybrid organic-inorganic double perovskite FA 2 BiCuI 6 has the ability to replace hybrid organic-inorganic perovskite CH 3 NH 3 PbI 3 to expand next-generation lead-free harmless materials for solar cell applications.


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