Properties of flame-retardant cotton fabrics: Combustion behavior, thermal stability and mechanism of Si/P/N synergistic effect

2021 ◽  
Vol 173 ◽  
pp. 114157
Author(s):  
Shihao Wang ◽  
Ling Sun ◽  
Yuyang Li ◽  
Huixin Wang ◽  
Jie Liu ◽  
...  
2016 ◽  
Vol 28 (3) ◽  
pp. 319-327 ◽  
Author(s):  
Aysun Aksit ◽  
Nurhan Onar ◽  
Bengi Kutlu ◽  
Evren Sergin ◽  
Ismail Yakin

Purpose – The purpose of this paper is to develop the flame retardancy properties of cotton fabrics with treatment of phosphorus and nitrogen containing silane-based nanosol by sol-gel process. Design/methodology/approach – Nanosols containing tetraethoxysilane or (3-aminopropyl) triethoxysilane as precursors, (3-glycidyloxypropyl) trimethoxysilane as cross-linking agent and guanidine phosphate monobasic as flame retarding agent were impregnated on cotton fabrics. Flame retardancy properties of the fabric samples were determined by limited flame spread test and limited oxygen index (LOI) test. In addition, microstructural and surface morphological properties of the fabric samples were characterized by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and scanning electron microscope. Findings – Depending on the limited flame spread test, the authors show that the coated fabric samples gain flame retardancy properties and the LOI value of the samples increased as to 45.7 per cent by the synergistic effect of phosphorus-nitrogen-silicon. Originality/value – There have some studies in flame retardancy behaviour of textiles. In this study, flame retardant cotton fabric with very low weight in grams was improved by sol-gel process. Moreover, ecological process was provided thanks to using halogen-free flame retardant.


2012 ◽  
Vol 602-604 ◽  
pp. 762-767
Author(s):  
Chong Peng ◽  
Yan Zhang ◽  
Hao Ran Wang

The flame retardancy of a thermally stable flame retardant, poly(bisphenol phenyl dichlovophosphate) (PBCL) and its synergistic effect with ammonium polyphosphate were studied in ABS. TG result indicated the good thermal stability and char-forming ability of PBCL. Thermal stability and flammability properties of ABS/APP/PBCL composites were investigated by thermogravimetric analysis (TGA), oxygen index test (LOI) and micro calorimeter calculate test (MCC). The results showed that the synergistic effect of APP and PBCL improved the thermal stability and flame retardancy of ABS, which was favorable to yield more stable layer at higher temperature and enhanced the char residue of ABS resin.


2010 ◽  
Vol 152-153 ◽  
pp. 108-115 ◽  
Author(s):  
Fei Juan Xu ◽  
Zu Min Qiu

In this paper, the flame-retardant synergistic effect between rare earth oxide and conventional flame retardants (aluminum hydroxide and iron trioxide) has been studied using vertical combustion test. The results show that good flame-retardant synergistic effect exists between them. The composites combining 100 grams of aluminum hydroxide, 40 grams of iron trioxide and 0.8 grams of rare earth oxide can reach FV-0 in vertical combustion test. The thermal stability influence of rare earth oxide to silicone rubber has also been studied by means of thermogravimetric analysis. It has been found that rare earth oxide can function as thermal stabilizer in silicone rubber.


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