A novel two dimensional samarium(III) coordination framework with N-(2-Hydroxyethyl)iminodiacetic acid and oxalate ligands: Synthesis, crystal structure and magnetic property

2011 ◽  
Vol 14 (12) ◽  
pp. 1928-1931 ◽  
Author(s):  
Lang Zhao ◽  
Shuangyan Lin ◽  
Si Shen ◽  
Jinkui Tang
Keyword(s):  
Crystal Structure ◽  
Magnetic Property ◽  
Iminodiacetic Acid ◽  
Two Dimensional ◽  
Coordination Framework

A threefold interpenetrating two-dimensional zinc(II) coordination polymer: synthesis, crystal structure and selective luminescence sensing properties

2019 ◽  
Vol 75 (7) ◽  
pp. 979-984 ◽  
Author(s):  
Chen-Dong Pan ◽  
Jun Wang ◽  
Ju-Qin Xu ◽  
Kang-Feng Zhang ◽  
Xiao-Wan Wang
Keyword(s):  
Crystal Structure ◽  
Thermal Analysis ◽  
Aqueous Solution ◽  
Coordination Polymer ◽  
Diphenyl Ether ◽  
Biological Processes ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
X Ray ◽  
Coordination Framework

The Fe3+ ion is the most important element in environmental systems and plays a fundamental role in biological processes. Iron deficiency can result in diseases and highly selective and sensitive detection of trace Fe3+ has become a hot topic. A novel two-dimensional ZnII coordination framework, poly[[μ-4,4′-bis(2-methylimidazol-1-yl)diphenyl ether-κ2 N 3:N 3′](μ-4,4′-sulfonyldibenzoato-κ2 O:O′)zinc(II)], [Zn(C14H8O6S)(C20H18N4O)] n or [Zn(SDBA)(BMIOPE)] n , (I), where H2SDBA is 4,4′-sulfonyldibenzoic acid and BMIOPE is 4,4′-bis(2-methylimidazol-1-yl)diphenyl ether, has been prepared and characterized by IR, elemental analysis, thermal analysis and X-ray diffraction analysis, the latter showing that the coordination polymer exhibits a threefold interpenetrating two-dimensional 44-sql network. In addition, it displays a highly selective and sensitive sensing for Fe3+ ions in aqueous solution.

A new two-dimensional CoII coordination polymer based on bis[4-(2-methyl-1H-imidazol-1-yl)phenyl] ether and biphenyl-4,4′-diyldicarboxylic acid: synthesis, crystal structure and photocatalytic degradation activity

2018 ◽  
Vol 74 (10) ◽  
pp. 1123-1127 ◽  
Author(s):  
Ning-Ning Chen ◽  
Jian-Ling Ni ◽  
Jun Wang
Keyword(s):  
Crystal Structure ◽  
Thermal Analysis ◽  
Photocatalytic Degradation ◽  
Acid Synthesis ◽  
Phenyl Ether ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
X Ray ◽  
Degradation Activity ◽  
Coordination Framework

A novel two-dimensional CoII coordination framework, namely poly[(μ2-biphenyl-4,4′-diyldicarboxylato-κ2 O 4:O 4′){μ2-bis[4-(2-methyl-1H-imidazol-1-yl)phenyl] ether-κ2 N 3:N 3′}cobalt(II)], [Co(C14H8O4)(C20H18N4O)] n , has been prepared and characterized by IR, elemental analysis, thermal analysis and single-crystal X-ray diffraction. The crystal structure reveals that the compound has an achiral two-dimensional layered structure based on opposite-handed helical chains. In addition, it exhibits significant photocatalytic degradation activity for the degradation of methylene blue.

scholarly journals Rational Design and Simulation of Two-Dimensional Perovskite Photonic Crystal Absorption Layers Enabling Improved Light Absorption Efficiency for Solar Cells

Energies ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2460
Author(s):  
Jian Zou ◽  
Mengnan Liu ◽  
Shuyu Tan ◽  
Zhijie Bi ◽  
Yong Wan ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Solar Cells ◽  
Photonic Crystal ◽  
Incident Light ◽  
Absorption Efficiency ◽  
Utilization Efficiency ◽  
Photonic Crystal Structure ◽  
Two Dimensional ◽  
Photoelectric Conversion ◽  
Absorption Layer

A two-dimensional perovskite photonic crystal structure of Methylamine lead iodide (CH3NH3PbI3, MAPbI3) is rationally designed as the absorption layer for solar cells. The photonic crystal (PC) structure possesses the distinct “slow light” and band gap effect, leading to the increased absorption efficiency of the absorption layer, and thus the increased photoelectric conversion efficiency of the battery. Simulation results indicate that the best absorption efficiency can be achieved when the scattering element of indium arsenide (InAs) cylinder is arranged in the absorption layer in the form of tetragonal lattice with the height of 0.6 μm, the diameter of 0.24 μm, and the lattice constant of 0.4 μm. In the wide wavelength range of 400–1200 nm, the absorption efficiency can be reached up to 82.5%, which is 70.1% higher than that of the absorption layer without the photonic crystal structure. In addition, the absorption layer with photonic crystal structure has good adaptability to the incident light angle, presenting the stable absorption efficiency of 80% in the wide incident range of 0–80°. The results demonstrate that the absorption layer with photonic crystal structure can realize the wide spectrum, wide angle, and high absorption of incident light, resulting in the increased utilization efficiency of solar energy.

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