A new two-dimensional CoII coordination polymer based on bis[4-(2-methyl-1H-imidazol-1-yl)phenyl] ether and biphenyl-4,4′-diyldicarboxylic acid: synthesis, crystal structure and photocatalytic degradation activity

2018 ◽  
Vol 74 (10) ◽  
pp. 1123-1127 ◽  
Author(s):  
Ning-Ning Chen ◽  
Jian-Ling Ni ◽  
Jun Wang
Keyword(s):  
Crystal Structure ◽  
Thermal Analysis ◽  
Photocatalytic Degradation ◽  
Acid Synthesis ◽  
Phenyl Ether ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
X Ray ◽  
Degradation Activity ◽  
Coordination Framework

A novel two-dimensional CoII coordination framework, namely poly[(μ2-biphenyl-4,4′-diyldicarboxylato-κ2 O 4:O 4′){μ2-bis[4-(2-methyl-1H-imidazol-1-yl)phenyl] ether-κ2 N 3:N 3′}cobalt(II)], [Co(C14H8O4)(C20H18N4O)] n , has been prepared and characterized by IR, elemental analysis, thermal analysis and single-crystal X-ray diffraction. The crystal structure reveals that the compound has an achiral two-dimensional layered structure based on opposite-handed helical chains. In addition, it exhibits significant photocatalytic degradation activity for the degradation of methylene blue.

A threefold interpenetrating two-dimensional zinc(II) coordination polymer: synthesis, crystal structure and selective luminescence sensing properties

2019 ◽  
Vol 75 (7) ◽  
pp. 979-984 ◽  
Author(s):  
Chen-Dong Pan ◽  
Jun Wang ◽  
Ju-Qin Xu ◽  
Kang-Feng Zhang ◽  
Xiao-Wan Wang
Keyword(s):  
Crystal Structure ◽  
Thermal Analysis ◽  
Aqueous Solution ◽  
Coordination Polymer ◽  
Diphenyl Ether ◽  
Biological Processes ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
X Ray ◽  
Coordination Framework

The Fe3+ ion is the most important element in environmental systems and plays a fundamental role in biological processes. Iron deficiency can result in diseases and highly selective and sensitive detection of trace Fe3+ has become a hot topic. A novel two-dimensional ZnII coordination framework, poly[[μ-4,4′-bis(2-methylimidazol-1-yl)diphenyl ether-κ2 N 3:N 3′](μ-4,4′-sulfonyldibenzoato-κ2 O:O′)zinc(II)], [Zn(C14H8O6S)(C20H18N4O)] n or [Zn(SDBA)(BMIOPE)] n , (I), where H2SDBA is 4,4′-sulfonyldibenzoic acid and BMIOPE is 4,4′-bis(2-methylimidazol-1-yl)diphenyl ether, has been prepared and characterized by IR, elemental analysis, thermal analysis and X-ray diffraction analysis, the latter showing that the coordination polymer exhibits a threefold interpenetrating two-dimensional 44-sql network. In addition, it displays a highly selective and sensitive sensing for Fe3+ ions in aqueous solution.

Two 2D Co(II)/Mn(II) coordination polymers based on the quinoline-2,3-dicarboxylate ligand: synthesis, crystal structure, and fluorescence properties

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Ya-Li Zhao ◽  
Qi-Ying Weng ◽  
Yu-Qian Xie ◽  
Jia-Ming Li
Keyword(s):  
Crystal Structure ◽  
Thermal Analysis ◽  
Coordination Polymers ◽  
Fluorescence Properties ◽  
Stacking Interactions ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
X Ray ◽  
Solid State Fluorescence ◽  
2D Network

Abstract A pair of two-dimensional (2D) isostructural coordination polymers (CPs), {[Co(2,3-qldc)(H2O)]} n (1) and {[Mn(2,3-qldc)(H2O)]} n (2), where 2,3-H2qldc = quinoline-2,3-dicarboxylic acid, were hydrothermally synthesized and characterized through IR spectroscopy, elemental and thermal analysis, power X-ray diffraction, and single-crystal X-ray diffraction. The results have revealed that the fully deprotonated 2,3-H2qldc ligand connects the Co(II)/Mn(II) atoms with a μ 3-bridge to form a square-wave 2D network, which is further extended into 3D stacks through O–H···O, C–H···O hydrogen bonds and π···π stacking interactions. Topologically, 1 or 2 can be simplified as a 4-connected sql type with a Schläfli symbol {44·62} and a Shubnikov tetragonal plane net, or as a 3-connected fes type with a Schläfli symbol {4·82} and a Shubnikov plane net. The thermal stability and the solid state fluorescence properties of 1 and 2 were investigated.

A new two-dimensional CdII coordination polymer based on 1,3-bis(2-methyl-1H-imidazol-1-yl)benzene and 1,3-phenylenediacetic acid: synthesis, crystal structure and physical properties

2018 ◽  
Vol 74 (12) ◽  
pp. 1576-1580 ◽  
Author(s):  
Ning-Ning Chen ◽  
Jian-Ning Ni ◽  
Jun Wang
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Three Dimensional ◽  
Acid Synthesis ◽  
Dimensional Structure ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
X Ray ◽  
Coordination Framework ◽  
Oriented Parallel

A novel two-dimensional CdII coordination framework, poly[[[μ-1,3-bis(2-methyl-1H-imidazol-1-yl)benzene-κ2 N:N′](μ-1,3-phenylenediacetato-κ4 O,O′:O′′,O′′′)cadmium(II)] dihydrate], {[Cd(C10H8O4)(C14H14N4)]·2H2O} n or {[Cd(PDA)(1,3-BMIB)]·2H2O} n [1,3-BMIB is 1,3-bis(2-methyl-1H-imidazol-1-yl)benzene and H2PDA is 1,3-phenylenediacetic acid], has been prepared and characterized using IR, elemental analysis, thermal analysis and single-crystal X-ray diffraction, the latter revealing that the compound is a (4,4) grid coordination polymer with layers oriented parallel to the bc crystal planes. In the crystal, adjacent layers are further connected by O—H...O and C—H...O hydrogen bonds, forming a three-dimensional structure in the solid state. In addition, the compound exhibits strong fluorescence emissions and shows photocatalytic activity for the degradation of methylene blue in the solid state at room temperature.

Synthesis, crystal structure, luminescence, and photocatalytic properties of a 2D Cu(II) metal-organic frameworks based on 3,5-di(1H-benzimidazol-1-yl)pyridine and 4,4′-oxybis(benzoate) ligands

2020 ◽  
Vol 75 (8) ◽  
pp. 727-732
Author(s):  
Chen Zhang ◽  
Jian-Qing Tao
Keyword(s):  
Crystal Structure ◽  
Thermal Analysis ◽  
Uv Light ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
X Ray Diffraction ◽  
X Ray ◽  
Uv Light Irradiation ◽  
Photocatalytic Activities ◽  
Metal Organic

AbstractA new Cu(II) metal-organic framework, [Cu(L)(OBA)·H2O]n (1) [H2OBA = 4,4′-oxybis(benzoic acid), L = 3,5-di(1H-benzimidazol-1-yl)pyridine] was hydrothermally synthesized and characterized through IR spectroscopy, elemental and thermal analysis and single-crystal X-ray diffraction. Complex 1 is a four-connected uni-nodal 2D net with a (44·62) topology which shows an emission centered at λ ∼393 nm upon excitation at λ = 245 nm. Moreover, complex 1 possesses high photocatalytic activities for the decomposition of Rhodamine B (RhB) under UV light irradiation.

On tungstates of divalent cations (III) – Pb5O2[WO6]

2020 ◽  
Vol 235 (8-9) ◽  
pp. 311-317
Author(s):  
Stephan G. Jantz ◽  
Florian Pielnhofer ◽  
Henning A. Höppe
Keyword(s):  
Crystal Structure ◽  
Thermal Analysis ◽  
Quantum Chemical ◽  
Density Functional ◽  
Divalent Cations ◽  
X Ray Diffraction ◽  
Functional Theory ◽  
X Ray ◽  
First Results ◽  
Electrostatic Calculations

Abstract${\text{Pb}}_{5}{\text{O}}_{2}\left[{\text{WO}}_{6}\right]$ was discovered as a frequently observed side phase during our investigation on lead tungstates. Its crystal structure was solved by single-crystal X-ray diffraction ($P{2}_{1}/n$, $a=7.4379\left(2\right)$ Å, $b=12.1115\left(4\right)$ Å, $c=10.6171\left(3\right)$ Å, $\beta =90.6847\left(8\right)$°, $Z=4$, ${R}_{\text{int}}=0.038$, ${R}_{1}=0.020$, $\omega {R}_{2}=0.029$, 4188 data, 128 param.) and is isotypic with ${\text{Pb}}_{5}{\text{O}}_{2}\left[{\text{Te}}_{6}\right]$. ${\text{Pb}}_{5}{\text{O}}_{2}\left[{\text{WO}}_{6}\right]$ comprises a layered structure built up by non-condensed [WO6]${}^{6-}$ octahedra and ${\left[{\text{O}}_{4}{\text{Pb}}_{10}\right]}^{12+}$ oligomers. The compound was characterised by spectroscopic measurements (Infrared (IR), Raman and Ultraviolet–visible (UV/Vis) spectra) as well as quantum chemical and electrostatic calculations (density functional theory (DFT), MAPLE) yielding a band gap of 2.9 eV fitting well with the optical one of 2.8 eV. An estimation of the refractive index based on the Gladstone-Dale relationship yielded $n\approx 2.31$. Furthermore first results of the thermal analysis are presented.

Two-dimensional lanthanide(III) coordination polymers: solvothermal synthesis, crystal structure, and stability

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Runmei Ding ◽  
Zixin He ◽  
Meilin Wang ◽  
Danian Tian ◽  
Peipei Cen
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers ◽  
Solvothermal Synthesis ◽  
Analysis Data ◽  
Water Stability ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Triclinic Space Group ◽  
X Ray ◽  
Solvothermal Conditions

AbstractBased on 2-(4-pyridyl)-terephthalate (H2pta) and oxalate ligands, two new lanthanide-containing coordination polymers (CPs), [Tb(pta)(C2O4)0.5(H2O)2)]·2H2O (1) and [Sm(pta)(C2O4)0.5(H2O)2)]·2H2O (2), have been synthesized under solvothermal conditions. The structures of both 1 and 2 have been determined by single-crystal X-ray diffraction. Infrared, elemental analysis, powder X-ray diffraction and thermogravimetric analysis data are also presented. The crystals of 1 and 2 exhibit isostructural layer-like networks, crystallizing in the triclinic space group P$‾{1}$. The layers are further stabilized and associated into 3D architectures through hydrogen bonding. Remarkably, the CPs 1 and 2 exhibit excellent water stability and remarkable thermostability with thermal decomposition temperatures of more than 420 °C.

Synthesis, IR spectrum, thermal behaviour and crystal structure of a novel one-dimensional cyano-bridged zinc(II)/nickel(II) complex

2005 ◽  
Vol 220 (1) ◽  
Author(s):  
Ahmet Karadag ◽  
Hümeyra Pasaoglu ◽  
Gökhan Kastas ◽  
Orhan Büyükgüngör
Keyword(s):  
Crystal Structure ◽  
Thermal Analysis ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Ir Spectrum ◽  
Polymeric Chain ◽  
X Ray Diffraction ◽  
Bimetallic Complex ◽  
One Dimensional ◽  
X Ray

AbstractThe cyano-bridged heteronuclear coordination polymer of zinc(II)/nickel(II) has been prepared by N-(2-hydroxyethyl)-ethylendiamine (hydet-en), alternatively named 2-(2-aminoethylamino)-ethanol and characterised by IR and thermal analysis. In the bimetallic complex, the decomposition of hydet-en ligands is seen to be endothermic whereas that of the cyano ligands is found to be exothermic. The crystal structure of the complex has been determined by single-crystal X-ray diffraction. The crystal structure of the zinc(II)-nickel(II) complex consists of a one-dimensional polymeric chain –Zn(hydet-en)

Synthesis, Structure and Properties of Two-Dimensional Coordination Polymer Based on 3,5-di(benzimidazol-1-yl)pyridine

2020 ◽  
Vol 42 (2) ◽  
pp. 249-249
Author(s):  
Guo Jun Wu Guo Jun Wu
Keyword(s):  
Infrared Spectroscopy ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Photocatalytic Degradation ◽  
Elemental Analysis ◽  
Solvothermal Reaction ◽  
Two Dimensional ◽  
Structure And Properties ◽  
X Ray Diffraction ◽  
X Ray

[Cu(L)(AIP)·1.5H2O]n (1) [L= 3,5-di(benzimidazol-1-yl)pyridine, H2AIP= 5-aminoisophthalic acid] was prepared by the solvothermal reaction, which was characterized by single-crystal X–ray diffraction, infrared spectroscopy, and elemental analysis. 1 exhibits an infinite two dimensional [Cu(AIP)]n sheet parallel to (0 1 1) crystal plane. Furthermore, complex 1 displays good photocatalytic degradation of methyl blue (MB).

A fourfold interpenetrating diamond-like three-dimensional zinc(II) coordination polymer: synthesis, crystal structure and physical properties

2019 ◽  
Vol 75 (5) ◽  
pp. 504-507 ◽  
Author(s):  
Hui-Ru Chen
Keyword(s):  
Crystal Structure ◽  
Room Temperature ◽  
Three Dimensional ◽  
Fluorescence Emission ◽  
Crystal Structure Analysis ◽  
The Novel ◽  
X Ray Diffraction ◽  
Metal Compounds ◽  
X Ray ◽  
Coordination Framework

Excellent fluorescence properties are exhibited by d 10 metal compounds. The novel three-dimensional ZnII coordination framework, poly[[{μ2-bis[4-(2-methyl-1H-imidazol-1-yl)phenyl] ether-κ2 N 3:N 3′}(μ2-furan-2,5-dicarboxylato-κ2 O 2:O 5)zinc(II)] 1.76-hydrate], {[Zn(C6H2O5)(C20H18N4O)]·1.76H2O} n , has been prepared and characterized using IR spectroscopy, elemental analysis and single-crystal X-ray diffraction. The crystal structure analysis revealed that the compound exhibits a novel fourfold interpenetrating diamond-like network. This polymer also displays a strong fluorescence emission in the solid state at room temperature.

Crystal Structure of BiFeO3 Synthesized Using the Hydrothermal Processing

2014 ◽  
Vol 602-603 ◽  
pp. 947-950
Author(s):  
Zhen Wang ◽  
Hai Yan Chen ◽  
Lin Qiang Gao ◽  
Xin Zou
Keyword(s):  
Crystal Structure ◽  
Electron Microscopy ◽  
Thermal Analysis ◽  
Scanning Electron Microscopy ◽  
Single Phase ◽  
Hydrothermal Processing ◽  
Optimal Conditions ◽  
X Ray Diffraction ◽  
X Ray ◽  
Scanning Electron

BiFeO3 nanoparticles were successfully synthesized by a hydrothermal method by a mineralizer (KNO3). Structural characterization was performed by thermal analysis, powder X-ray diffraction (XRD) and scanning electron microscopy (TEM).The results showed that the products were perovskite structure BiFeO3 powders. Optimal conditions for the synthesis of single-phase BiFeO3 ceramics were obtained.

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