Synthesis, crystalline perfection, optical and dielectric studies on metal–organic tri-allylthiourea cadmium chloride (ATCC) nonlinear optical single crystal by solution growth technique

2012 ◽  
Vol 538 ◽  
pp. 131-135 ◽  
Author(s):  
R. Perumal ◽  
S. Moorthy Babu
2020 ◽  
Vol 49 (2) ◽  
pp. 181-186 ◽  
Author(s):  
V. Chithambaram ◽  
T. S. Franklin Rajesh ◽  
Geetha Palani ◽  
E. Ilango ◽  
B. Deepanraj ◽  
...  

2009 ◽  
Vol 18 (01) ◽  
pp. 153-159 ◽  
Author(s):  
K. KIRUBAVATHI ◽  
K. SELVARAJU ◽  
S. KUMARARAMAN

Single crystals of the metal-organic nonlinear optical material bis thiourea lead chloride were grown from solution growth technique for the first time. The grown crystals were characterized by single crystal X-ray diffraction analysis to confirm the crystal structure. The presence of various functional groups and the coordination of metal ions to thiourea were confirmed by Fourier transform infrared analysis. UV-Vis. spectrum was recorded to study the optical transparency of the grown crystals. The second order nonlinear optical property of the grown crystal was examined by Kurtz powder technique and mechanical behavior was studied by Vickers micro hardness test.


The highly meritorious single crystal ofDAST (4-N,N-dimethylamino-4’-N’-methylstilbazolium tosylate) was grown through solution growth technique. The grown single crystals crystalline perfection analysis was made by HRXRD studies. The dielectric constant (ε), dielectric loss (ε) of DAST crystal was studied at different temperatures. The thermal decomposition stages were examined by using thermogram of DAST crystal and also it was giving best description of kinetic changes. Dielectric character was studied to the DAST crystal. The dielectric character of DAST was too analyzed.


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