Low temperature synthesis of high-purity Ti3SiC2 via additional Si through spark plasma sintering

2019 ◽  
Vol 789 ◽  
pp. 313-322 ◽  
Author(s):  
Alireza Pourebrahim ◽  
Hamidreza Baharvandi ◽  
Hamze Foratirad ◽  
Naser Ehsani
2020 ◽  
Vol 9 (6) ◽  
pp. 759-768
Author(s):  
Yunhui Niu ◽  
Shuai Fu ◽  
Kuibao Zhang ◽  
Bo Dai ◽  
Haibin Zhang ◽  
...  

AbstractThe synthesis, microstructure, and properties of high purity dense bulk Mo2TiAlC2 ceramics were studied. High purity Mo2TiAlC2 powder was synthesized at 1873 K starting from Mo, Ti, Al, and graphite powders with a molar ratio of 2:1:1.25:2. The synthesis mechanism of Mo2TiAlC2 was explored by analyzing the compositions of samples sintered at different temperatures. It was found that the Mo2TiAlC2 phase was formed from the reaction among Mo3Al2C, Mo2C, TiC, and C. Dense Mo2TiAlC2 bulk sample was prepared by spark plasma sintering (SPS) at 1673 K under a pressure of 40 MPa. The relative density of the dense sample was 98.3%. The mean grain size was 3.5 μm in length and 1.5 μm in width. The typical layered structure could be clearly observed. The electrical conductivity of Mo2TiAlC2 ceramic measured at the temperature range of 2–300 K decreased from 0.95 × 106 to 0.77 × 106 Ω–1·m–1. Thermal conductivity measured at the temperature range of 300–1273 K decreased from 8.0 to 6.4 W·(m·K)–1. The thermal expansion coefficient (TEC) of Mo2TiAlC2 measured at the temperature of 350–1100 K was calculated as 9.0 × 10–6 K–1. Additionally, the layered structure and fine grain size benefited for excellent mechanical properties of low intrinsic Vickers hardness of 5.2 GPa, high flexural strength of 407.9 MPa, high fracture toughness of 6.5 MPa·m1/2, and high compressive strength of 1079 MPa. Even at the indentation load of 300 N, the residual flexural strength could hold 84% of the value of undamaged one, indicating remarkable damage tolerance. Furthermore, it was confirmed that Mo2TiAlC2 ceramic had a good oxidation resistance below 1200 K in the air.


2018 ◽  
Vol 5 (10) ◽  
pp. 105201 ◽  
Author(s):  
Qi Song ◽  
Zhao-Hui Zhang ◽  
Zheng-Yang Hu ◽  
Shi-Pan Yin ◽  
Hu Wang ◽  
...  

2004 ◽  
Vol 19 (12) ◽  
pp. 3715-3715

After this article appeared in the September 2004 issue of Journal of Materials Research, the authors noticed that the y2-axis labels for Fig. 1 were printed incorrectly. The correct figure is shown below:


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