Continuous Prediction Model of Carbon Content in 120 t Converter Blowing Process

A continuous prediction model of carbon content of 120 t BOF is established in this paper. Based on the three-stage decarburization theory and combined with the production process of 120 t converter, the effects of oxygen lance height and top blowing oxygen flow rate are also considered in the model. The explicit finite difference method is used to realize continuous prediction of carbon content in the converter blowing process. The model parameters such as ultimate carbon content in molten pool are calculated according to the actual data of 120 t BOF, which improves the hit rate of the model. Process verification and end-point verification for the continuous prediction model have been carried out, and the results of process verification indicate that the continuous prediction model established in the paper basically accords with the actual behavior of decarburization. Moreover, the hit ratio of the continuous prediction model reached 85% for the prediction of end-point carbon content within a tolerance of ±0.02%.

Sintering and Smelting Property Investigations of Ludwigite

In this paper, orthogonal experiments are designed to study the sintering and smelting characteristics of the ludwigite ore. The predominant influencing factors of the optimal ratio, basicity and carbon content on different single sintering indexes, including the vertical sintering speed, yield rate, drum strength and low-temperature reduction pulverization index, are firstly explored by the range analysis method, and the main influencing factors on comprehensive indexes are obtained by a weighted scoring method based on different single index investigation. Considering the sintering characteristics, the primary and secondary influencing factors are: ordinary ore ratio, carbon content and basicity, and the optimal ore blending scheme is: basicity 1.7, ordinary ore blending ratio 60% and carbon content 5%. In terms of the smelting characteristics, the research obtains the order of the influencing factors on the softening start temperature, softening end temperature, softening zone, smelting start temperature, dripping temperature, smelting-dripping zone, maximum pressure difference and gas permeability index of the ludwigite sinters by simply considering various single smelting indexes. On this basis, considering the comprehensive softening-melting-dripping characteristics, the primary and secondary influencing factors are: carbon content, ordinary ore ratio and basicity, and the optimal ore blending scheme is: basicity 1.9, ordinary ore blending ratio 60% and a carbon content of 5.5%. Comprehensively, considering the sintering and smelting property of the ludwigite ore, the primary and secondary influencing factors are: carbon content, ordinary ore ratio and basicity, and the optimal ore blending scheme is: basicity 1.9, ordinary ore blending ratio 60% and a carbon content of 5.5%.

Influence of Different Carbon Content on Reduction of Zinc Oxide via Metal Bath

Electric arc furnace dust (EAFD) is an important secondary resource for the zinc industry. The most common process for its recycling is the pyro-metallurgical treatment in the Waelz process. However, this process focuses on the recycling of the zinc, whereas the recovery of other metals from the EAFD—such as iron and other alloying elements—is neglected. An up-to-date version of reprocessing can involve multi-metal recycling by means of a metal bath containing carbon. The use of a liquid iron alloy requires a higher processing temperature, which enables the reduction and melting of iron oxides as well as other compounds occurring in the dust. Furthermore, the Zn yield is higher and the reduction kinetics are faster than in the Waelz process. This paper is only focused on the zinc reduction in such a metal bath. In order to determine the influence of the carbon content in the molten metal on the reduction rate, experiments were carried out on the reduction behavior of zinc oxide using a synthetic slag. This slag, with a basicity B2 = 1, was applied to an iron bath with varying carbon contents. (0.85%, 2.16%, 2.89%, and 4.15%) The decrease in the zinc oxide concentration was monitored, along with the reaction rates calculated from these data. It was found that the reaction rate increases with rising carbon content in the melt.

Thermal conductivity and bending strength of SiC composites reinforced by pitch-based carbon fibers

In this work, pitch-based carbon fibers were utilized to reinforce silicon carbide (SiC) composites via reaction melting infiltration (RMI) method by controlling the reaction temperature and resin carbon content. Thermal conductivities and bending strengths of composites obtained under different preparation conditions were characterized by various analytical methods. Results showed the formation of SiC whiskers (SiCw) during RMI process according to vapor—solid (VS) mechanism. SiCw played an important role in toughening the Cpf/SiC composites due to crack bridging, crack deflection, and SiCw pull-out. Increase in reaction temperature during RMI process led to an initial increase in thermal conductivity along in-plane and thickness directions of composites, followed by a decline. At reaction temperature of 1600 °C, thermal conductivities along the in-plane and thickness directions were estimated to be 203.00 and 39.59 W/(m·K), respectively. Under these conditions, bending strength was recorded as 186.15±3.95 MPa. Increase in resin carbon content before RMI process led to the generation of more SiC matrix. Thermal conductivities along in-plane and thickness directions remained stable with desirable values of 175.79 and 38.86 W/(m·K), respectively. By comparison, optimal bending strength improved to 244.62±3.07 MPa. In sum, these findings look promising for future application of pitch-based carbon fibers for reinforcement of SiC ceramic composites.

Increasing the mechanical properties of structural cast iron for machine-building parts by combined Mn – Al alloying

The object of research in this work was cast iron for machine-building parts, alloyed with Al. The possibility of improving the mechanical properties of cast iron by choosing the optimal Mn – Al combinations, depending on the carbon content in the cast iron, was determined. The study was carried out on the basis of available retrospective data of serial industrial melts by constructing the regression equation for the ultimate strength of cast iron in the three-factor space of the input variables C – Mn – Al. The optimization problem was solved by the ridge analysis method after reducing the dimension of the factor space by fixing the carbon content at three levels: C = 3 %, C = 3.3 %, and C = 3.6 %. It was found that the maximum values of the ultimate strength are achieved at the minimum level of carbon content (C = 3%) and are in the range of values close to 300 MPa. In this case, the Al content is in the range (2.4–2.6) %, and the Mn content is about 0.82 %. With an increase in the carbon content, there is a tendency to a decrease in the content of Mn and Al in the alloy, which is necessary to ensure the ultimate strength close to 300 MPa. The results of the ridge analysis of the response surface also showed that at the upper limit of the carbon content (C = 3.6%), it is not possible to reach the ultimate strength of 300 MPa in the existing range of Mn and Al variation. All solutions are verified for the following ranges of input variables C = (2.94–3.66) %, Mn = (0.5–1.1) %, Al = (1.7–2.9) %. Graphical-analytical descriptions of the optimal Mn – Al ratios are obtained, depending on the actual content of carbon in the alloy, which make it possible to purposefully select the optimal melting modes by controlling the tensile strength of the alloy

Exergy Analysis of Alternative Configurations of Biomass-Based Light Olefin Production System with a Combined-Cycle Scheme via Methanol Intermediate

Thermodynamic performance of three conceptual systems for biomass-derived olefin production with electricity cogeneration was studied and compared via exergy analysis at the levels of system, subsystem and operation unit. The base case was composed of the subsystems of gasification, raw fuel gas adjustment, methanol/light olefin synthesis and steam & power generation, etc. The power case and fuel case were designed as the combustion of a fraction of gasification gas to increase power generation and the recycle of a fraction of synthesis tail gas to increase olefin production, respectively. It was found that the subsystems of gasification and steam & power generation contribute ca. 80% of overall exergy destruction for each case, of which gasifier and combustor are the main exergy destruction sources, due to the corresponding chemical exergy degrading of biomass and fuel gas. The low efficiency of 33.1% for the power case could be attributed to the significant irreversibility of the combustor, economizer, and condenser in the combined-cycle subsystem. The effect of the tail gas recycle ratio, moisture content of feedstock, and biomass type was also investigated to enhance system exergy performance, which could be achieved by high recycle ratio, using dry biomass and the feedstock with high carbon content. High system efficiency of 38.9% was obtained when oil palm shell was used, which was 31.7% for rice husk due to its low carbon content.

The Improvement of the Operational Characteristics of the Ventilated Front Brake Discs

Wear and crack resistance are important operational characteristics of brake discs. The paper presents the most optimal concentration of sulfur in cast iron, which ensures its least wear, and discusses the implementation of the front brake discs manufacture from Gh190 cast iron having 0.11 ... 0.13% sulfur content at contrast to the 0.01 ... 0.03% sulfur content, and proves the change leads to a significant increase in wear and frictional properties of the discs. In the course of research, it is found that the increase in the crack resistance of brake discs is possible due to the improvement of the thermophysical properties of cast iron with the increase in the carbon content (up to 3.55 ... 3.60%) and the decrease in the silicon content (up to 1.45 ... 1.50%), while the carbon equivalent is constant.