Monitoring of hydrolysis products of mustard gas, some sesqui- and oxy-mustards and other chemical warfare agents in a plant material by HPLC-MS/MS

2021 ◽  
Vol 1162 ◽  
pp. 122452
Author(s):  
Timur Baygildiev ◽  
Mikhail Vokuev ◽  
Arcady Braun ◽  
Igor Rybalchenko ◽  
Igor Rodin
Sensors ◽  
2018 ◽  
Vol 18 (12) ◽  
pp. 4291 ◽  
Author(s):  
Michael Kangas ◽  
Adreanna Ernest ◽  
Rachel Lukowicz ◽  
Andres Mora ◽  
Anais Quossi ◽  
...  

Chemical warfare agents pose significant threats in the 21st century, especially for armed forces. A colorimetric detection array was developed to identify warfare mimics, including mustard gas and nerve agents. In total, 188 sensors were screened to determine the best sensor performance, in order to identify warfare mimics 2-chloro ethyl ethylsulfide, 2-2′-thiodiethanol, trifluoroacetic acid, methylphosphonic acid, dimethylphosphite, diethylcyanophosphonate, and diethyl (methylthiomethyl)phosphonate. The highest loadings in the principle component analysis (PCA) plots were used to identify the sensors that were most effective in analyzing the RGB data to classify the warfare mimics. The dataset was reduced to only twelve sensors, and PCA results gave comparable results as the large data did, demonstrating that only twelve sensors are needed to classify the warfare mimics.


1999 ◽  
Vol 81 (2) ◽  
pp. 107-118 ◽  
Author(s):  
Vladimir I. Sklyar ◽  
Tatyana P. Mosolova ◽  
Irina A. Kucherenko ◽  
Natalya N. Degtyarova ◽  
Sergey D. Varfolomeyev ◽  
...  

2017 ◽  
Vol 24 (4) ◽  
pp. 631-638 ◽  
Author(s):  
Astrida Neimanis ◽  
Aleksija Neimanis ◽  
Cecilia Åsberg

At the end of World War II, tens of thousands of tons of chemical warfare agents – mostly mustard gas – were dumped in the Gotland Deep – a deep basin in the middle of the otherwise shallow Baltic Sea. Decades later, these weapons are being reactivated – both literally (perhaps on the faces of dead seals, and in fishermen’s nets) and also in our imaginations. In this story that recounts the beginning of our research into this situation, militarization meets with environmental concern: the past floats into the present, where humans and non-humans are equally implicated, where the sea itself conditions the kinds of questions we can ask, and answers we might get, and where terms like ‘threat’ and ‘risk’ remain undecided. After spending time on Gotland Island – the closest terrestrial site to these weapons dumps – we ask what kinds of research methods might be adequate to these tangled, underwater tales that we find so difficult to fathom.


2019 ◽  
pp. 1507-1520
Author(s):  
Jean Simonis ◽  
Diary Ali Mohammed Al-Manmi ◽  
Aram Dawood Abbas ◽  
Loffie Schoeman

16 March of every year marked the anniversary of the chemical gas attack on the City of Halabja, Kurdistan, Iraq, and its nearby villages. In the process, 5000 people reportedly died from the attack. Many more were wounded and the event left nearly 60 000 people displaced. A perceived consequence of the chemical bombing of Halabja City was the environmental pollution of the soil and water. A recent questionnaire completed by the population of Halabja City indicated that 35% believed that water pollution was still an issue, and 55% thought that soil pollution posed a high risk.In 2016, were requested by the Halabja City governor to investigate the situation. And to lay to rest the perception and concerns of soil and water still being contaminated by the events that happened on that day in March 1988. A total of 8 soil and 18 water samples were collected, Soil samples were collected from thesurface and as close as possible to bomb sites and craters, in contrast, water samples were collected from seven springs, ten water wells, and one surface streams downslope as close as possible to the bombed areas. The samples were analyzed for chemical warfare agents which are Arsenic, Cyanide, Fluoride, soluble  orthophosphate, Nitrate, Phosphorous, Sulphate, and Sulphur. The results indicated no negative contamination remaining in both water and soil. The geology and hydrogeology in the area played an important role in helping the chemical warfare agents (CWA) to degrade during the past 28 years. Most of the CWA used arewater- soluble and solubility increases when the agents are either hydrolyzed or oxidized. The hydrolysis products have equal toxicity to the parent chemicals, posing a similar threat to the environment. In contrast, the intact chemicals can be adsorbed onto sediment, where they can be stored for a longer time.


2022 ◽  
Vol 15 (1) ◽  
pp. 97
Author(s):  
Raluca-Elena Ginghina ◽  
Gabriela Toader ◽  
Munizer Purica ◽  
Adriana-Elena Bratu ◽  
Claudiu Lazaroaie ◽  
...  

The present work reveals a comprehensive decontamination study on real and simulated biological and chemical warfare agents (BCWA). The emphasis was on evaluating the antimicrobial activity against real biological warfare agents, such as Bacillus anthracis, and also the capacity of neutralizing real chemical warfare agents, such as mustard gas or soman, by employing three different types of organic solutions enriched with ZnO, TiO2, and zeolite nanoparticles, specially designed for decontamination applications. The capacity of decontaminating BCWA was evaluated through specific investigation tools, including surface monitoring with the swabs method, minimum inhibitory (MIC) and minimum bactericidal concentration (MBC) evaluations, time-kill tests for microorganisms, and GC-MS for monitoring chemical agents on different types of surfaces (glass, painted metal, rubber, and cotton butyl rubber). These tests revealed high decontamination factors for BCWA even after only 10 min, accomplishing the requirements imposed by NATO standards. At the completion of the decontamination process, the formulations reached 100% efficacy for Bacillus anthracis after 10–15 min, for soman after 20–30 min, and for mustard gas in an interval comprised between 5 and 24 h depending on the type of surface analyzed.


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