Composite modification mechanism of blended bio-asphalt combining styrene-butadiene-styrene with crumb rubber: A sustainable and environmental-friendly solution for wastes

2019 ◽  
Vol 214 ◽  
pp. 593-605 ◽  
Author(s):  
Ze-jiao Dong ◽  
Tao Zhou ◽  
Hai Luan ◽  
R. Christopher Williams ◽  
Peng Wang ◽  
...  
Materials ◽  
2019 ◽  
Vol 12 (15) ◽  
pp. 2345 ◽  
Author(s):  
Yangsheng Ye ◽  
Gang Xu ◽  
Liangwei Lou ◽  
Xianhua Chen ◽  
Degou Cai ◽  
...  

In this study, a new type of composite modified bitumen was developed by blending styrene-butadiene-styrene (SBS) and crumb rubber (CR) with a chemical method to satisfy the durability requirements of waterproofing material in the waterproofing layer of high-speed railway subgrade. A pressure-aging-vessel test for 20, 40 and 80 h were conducted to obtain bitumen samples in different long-term aging conditions. Multiple stress creep recovery (MSCR) tests, linear amplitude scanning tests and bending beam rheometer tests were conducted on three kinds of asphalt binders (SBS modified asphalt, CR modified asphalt and SBS/CR composite modified asphalt) after different long-term aging processes, including high temperature permanent deformation performance, resistance to low temperature thermal and fatigue crack. Meanwhile, aging sensitivities were compared by different rheological indices. Results showed that SBS/CR composite modified asphalt possessed the best properties before and after aging. The elastic property of CR in SBS/CR composite modified asphalt improved the ability to resist low temperature thermal and fatigue cracks at a range of low and middle temperatures. Simultaneously, the copolymer network of SBS and CR significantly improved the elastic response of the asphalt SBS/CR modified asphalt at a range of high temperatures. Furthermore, all test results indicated that the SBS/CR modified asphalt possesses the outstanding ability to anti-aging. SBS/CR is an ideal kind of asphalt to satisfy the demand of 60 years of service life in the subgrade of high speed railway.


2013 ◽  
Vol 848 ◽  
pp. 26-30
Author(s):  
Fu Qiang Dong ◽  
Wen Zhe Zhao ◽  
Yu Zhen Zhang ◽  
Hua Dong Sun ◽  
Wei Yu Fan ◽  
...  

This paper presents a laboratory study of Styrene-Butadiene-Styrene (SBS)/ crumb rubber modified asphalt by the two-step method. The conventional properties of the modified asphalt were determined. The effects of crumb rubber content and shearing time on the performance of the crumb rubber modified asphalt and composite modified asphalt. The results show that the crumb rubber contents and shearing time have significant impacts on the performance of the modified asphalt. With the crumb rubber content increasing, the high temperature performance was improved and the low temperature chanethe softening point increases and penetration decrease, and the ductility change little. It is comfortable for workability at the crumb rubber content of 20%. The viscosity is an important measurement for the workability of the modified asphalt. After adding the stabilizer, the viscosity increases until the shearing time reaching 1.5h, then it will decrease gradually.


Polymers ◽  
2021 ◽  
Vol 13 (18) ◽  
pp. 3037
Author(s):  
Gang Xu ◽  
Yunhong Yu ◽  
Jingyao Yang ◽  
Tianling Wang ◽  
Peipei Kong ◽  
...  

Taking advantage of crumb rubber from waste tires to modify bitumen is widely for the environmentally friendly and sustainable development of pavement. This study investigated the modification mechanism, rheological, and aging properties of styrene–butadiene–styrene (SBS)/desulfurized crumb rubber (DCR) composite modified bitumen (SBS/DCRMB). Morphological features and chemical characteristics were assessed by fluorescence intensity measurement and gel permeation chromatography (GPC), respectively, and results demonstrated that the DCR and SBS modifier in SBS/DCRMB had been vulcanized and formed a three-dimensional network structure. Moreover, a comparison of the GPC elution curve showed the residual bitumen hardly changed due to carbon black released from DCR of SBS/DCRMB during the aging process of SBS/DCRMB, and the polymer molecules condensed to larger units. However, the remaining bitumen in SBSMB had changed evidently and the polymer degraded to smaller molecules. Meanwhile the rheological testing results, including multiple stress creep recovery, linear amplitude sweep and bending beam rheometer, declared that the SBS/DCRMB is superior to SBSMB before and after aging.


Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3780
Author(s):  
Jingyao Yang ◽  
Gang Xu ◽  
Peipei Kong ◽  
Xianhua Chen

With the growing interest in bituminous construction materials, desulfurized crumb rubber (CR)/styrene–butadiene–styrene (SBS) modified asphalts have been investigated by many researchers as low-cost environmental-friendly road construction materials. This study aimed to investigate the rheological properties of desulfurized CR/SBS composite modified asphalt within various temperature ranges. Bending beam rheometer (BBR), linear amplitude sweep (LAS), and multiple stress creep recovery (MSCR) tests were performed on conventional CR/SBS composite modified asphalt and five types of desulfurized CR/SBS modified asphalts. Meanwhile, Burgers’ model and the Kelvin–Voigt model were used to derive nonlinear viscoelastic parameters and analyze the viscoelastic mechanical behavior of the asphalts. The experimental results indicate that both the desulfurized CR/SBS composite modifier and force chemical reactor technique can enhance the crosslinking of CR and SBS copolymer, resulting in an improved high-, intermediate-, and low-temperature performance of desulfurized CR/SBS composite modified asphalt. Burgers’ model was found to be apposite in simulating the creep stages obtained from MSCR tests for CR/SBS composite modified asphalts. The superior high-temperature performance of desulfurized CR/SBS modified asphalt prepared with 4% SBS, 20% desulfurized rubber, and a force chemical reactor time of 45 min contributes to the good high-temperature elastic properties of the asphalt. Therefore, this combination is recommended as an optimal preparation process. In summary, the desulfurization of crumb rubber and using the force chemical reactor technique are beneficial to composite asphalt performance and can provide a new way of utilizing waste tire rubber.


2020 ◽  
Vol 12 (1) ◽  
pp. 12-19
Author(s):  
RAMAN PAKHOLAK ◽  
ANDRZEJ PLEWA ◽  
RAMAN HATALSKI

Good quality bitumen used in the production of bitumen-aggregate mixtures is a binder with high stiffness and elasticity at high operating temperatures occurring in summer and adequate flexibility during exposure to sub-zero temperatures. Currently, one of the best technological solutions to improve the viscoelasticity of bitumen and the resistance to ageing is their modification with various types of additives. The paper presents the results of penetration tests as a function of temperature, softening point (ring and ball method) and strain energy at various temperatures of road bitumen modified with SBS (styrene-butadiene-styrene) copolymer, crumb rubber and simultaneous bitumen modification with SBS copolymer and crumb rubber. The obtained results allowed to assess temperature sensitivity, resistance to changes in selected technical properties of the tested binders as a result of technological ageing process with RTFOT (Roler Thin Film Oven Tester) method and to evaluate changes in their technical properties in relation to the 50/70 base bitumen. Multivariate analysis of variance (MANOVA) was used to analyse the impact of the modification type on the test results of technical properties (significance of the impact of the considered factors on the level of technical properties).


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