Recycling of mixed lithium-ion battery cathode materials with spent lead-acid battery electrolyte with the assistance of thermodynamic simulations

2020 ◽  
Vol 266 ◽  
pp. 121827 ◽  
Author(s):  
Shuai Gu ◽  
Liang Zhang ◽  
Bitian Fu ◽  
Ji Whan Ahn ◽  
Xinpeng Wang
Author(s):  
Doudou Nanitamo Luta ◽  
Atanda K. Raji

Most African remote telecoms base stations are powered from diesel generators, however, these generators are losing attractiveness due to their less reliability in addition to high operational and maintenance costs. Over 65% of the loss of telecom services observed in remote areas are caused by outages resulting from diverse types of failures that these generators can suffer, on top of their impacts on the environment. As alternative, off-grid renewable energy systems are often employed in place of diesel generators due to their capability to provide reliable electricity at an acceptable cost. This study proposes an off-grid system based on PV generators and backup energy storage consisting of lithium-ion batteries as an extended solution for powering remote telecom base stations in Africa. Modelling and simulation is performed using Matlab/Simulink environment. The findings showed better characteristics of lithium-ion battery bank as compared to lead-acid unit; lithium-ion battery bank displayed higher initial current and voltage over lead-acid battery bank. Moreover, when, both battery banks reached 50 % of their state of charge, lithium-ion bank current was still higher than that of lead-acid bank. In the same vein, lithium-ion battery bank presented a slower discharge time than lead-acid battery bank on top higher values at 50 % and 70% state of charges. Lastly, the state of charge of the lead-acid battery at the end of the simulation was 50 %, while that of the lithium-ion battery bank was around 60 %.


2019 ◽  
Vol 9 (11) ◽  
pp. 2262 ◽  
Author(s):  
Shuai Gu ◽  
Bitian Fu ◽  
Toyohisa Fujita ◽  
Ji Whan Ahn

By utilizing thermodynamic calculations, the possible removal path of spent lead-acid battery electrolytes was modeled. The process was divided into precipitation and carbonation processes. In the carbonation process, two scenarios were discussed, namely carbonation with and without pre-filtration of the precipitates resulted from the precipitation process. The results showed that in the precipitation process, the theoretical limit for the chemical removal of SO42− was 99.15%, while in the following carbonation process without filtration, only 69.61% of SO42− was removed due to the fact that CO2 reacts with Ca2+ ion in the solution, and thus leads to the production of CaCO3 and SO42− ions in the solution. In the carbonation process without filtration, with the increase of CO2 in the solution the removal ratio of SO42− further decreases. Thermodynamic simulation was effective in predicting the theoretical removal limits and helps in understanding and optimizing the removal process.


Author(s):  
Umair Nisar ◽  
Nitin Muralidharan ◽  
Rachid Essehli ◽  
Ruhul Amin ◽  
Ilias Belharouak

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