Imidazolium-based titanosilicate nanospheres as active catalysts in carbon dioxide conversion: Towards a cascade reaction from alkenes to cyclic carbonates

Novel bi-functional catalysts allowing to decrease the reaction temperature for the synthesis of cyclic carbonates below 150 °C were successfully synthesized.

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A Novel Methodology for the Synthesis of Cyclic Carbonates Based on the Palladium-Catalyzed Cascade Reaction of 4-Methoxycarbonyloxy-2-butyn-1-ols with Phenols, Involving a Novel Carbon Dioxide Elimination-Fixation Process

Journal of the American Chemical Society ◽

10.1021/ja0340681 ◽

2003 ◽

Vol 125 (16) ◽

pp. 4874-4881 ◽

Cited By ~ 81

Author(s):

Masahiro Yoshida ◽

Mika Fujita ◽

Tooru Ishii ◽

Masataka Ihara

Keyword(s):

Carbon Dioxide ◽

Cascade Reaction ◽

Cyclic Carbonates ◽

Carbon Dioxide Elimination ◽

Palladium Catalyzed

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In-situ cleavage and rearrangement synthesis of an easy-obtained and high stable Cu(II)-based MOF for efficient heterogeneous catalysis of carbon dioxide conversion

CrystEngComm ◽

10.1039/d1ce00888a ◽

2021 ◽

Author(s):

Lan Qin ◽

Yu Pan ◽

Lei Yu ◽

Ranran Huai ◽

Lu Yang ◽

...

Keyword(s):

Carbon Dioxide ◽

Heterogeneous Catalysis ◽

Metal Organic Frameworks ◽

Chemical Fixation ◽

Cyclic Carbonates ◽

Carbon Dioxide Conversion ◽

Metal Organic ◽

Carbon Dioxide Co2

Cycloaddition into cyclic carbonates has been attracted substantial attentions for metal-organic frameworks based catalysis of carbon dioxide (CO2) chemical fixation, not only due to the contributions that solving the environmental...

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A recyclable AgI/OAc− catalytic system for the efficient synthesis of α-alkylidene cyclic carbonates: carbon dioxide conversion at atmospheric pressure

Green Chemistry ◽

10.1039/c7gc00276a ◽

2017 ◽

Vol 19 (13) ◽

pp. 2936-2940 ◽

Cited By ~ 43

Author(s):

Ye Yuan ◽

Yu Xie ◽

Cheng Zeng ◽

Dandan Song ◽

Somboon Chaemchuen ◽

...

Keyword(s):

Carbon Dioxide ◽

Catalytic System ◽

Atmospheric Pressure ◽

Cyclic Carbonates ◽

Efficient Synthesis ◽

Carbon Dioxide Conversion ◽

Propargylic Alcohols

The cyclization of CO2 and propargylic alcohols were catalyzed by a green and recyclable (20 cycles) AgI/OAc− system under atmospheric pressure.

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Carbon Dioxide Utilisation for the Synthesis of Unsymmetrical Dialkyl and Cyclic Carbonates Promoted by Basic Ionic Liquids

Australian Journal of Chemistry ◽

10.1071/ch17530 ◽

2018 ◽

Vol 71 (3) ◽

pp. 181 ◽

Cited By ~ 2

Author(s):

Peter Goodrich ◽

H. Q. Nimal Gunaratne ◽

Lili Jin ◽

Yuntao Lei ◽

Kenneth R. Seddon

Keyword(s):

Carbon Dioxide ◽

Ionic Liquids ◽

Room Temperature ◽

Benzyl Bromide ◽

Cyclic Carbonate ◽

Cyclic Carbonates ◽

Carbon Dioxide Conversion ◽

Greener Synthesis ◽

Carbon Dioxide Utilisation ◽

Fixation Of Carbon Dioxide

An efficient and greener synthesis of unsymmetrical organic carbonates mediated by Hünig’s base-appended basic ionic liquids, via carbon dioxide conversion, is described here. These ionic liquids were found to be effective bases for the fixation of carbon dioxide by various alcohols and benzyl bromide, at room temperature. When the alcohol and the halide functionalities are present within the same substrate, the reaction cleanly produces a cyclic carbonate. These functionalised basic ionic liquids were fully recyclable with no loss product yields.

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