EQCM and in situ FTIR spectroelectrochemistry study on the electrochemical oxidation of TMB and the effect of large-sized anions

2008 ◽  
Vol 622 (2) ◽  
pp. 184-192 ◽  
Author(s):  
Meiling Liu ◽  
Youyu Zhang ◽  
Yuandao Chen ◽  
Qingji Xie ◽  
Shouzhuo Yao
Keyword(s):  
Electrochemical Oxidation ◽  
In Situ Ftir

scholarly journals Electrochemical oxidation of ferricyanide

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Mun Hon Cheah ◽  
Petko Chernev
Keyword(s):  
Experimental Data ◽  
Dft Calculations ◽  
Electrochemical Oxidation ◽  
Oxidation Product ◽  
In Situ Ftir ◽  
Stable Product ◽  
Good Agreement

AbstractWe report the electrochemical oxidation of ferricyanide, [FeIII(CN)6]3− and characterised the oxidation product by in-situ FTIR and XAS spectroelectrochemistry methods. Oxidation of [FeIII(CN)6]3− is proposed to proceed via a tentative Fe(IV) intermediate that undergoes reduction elimination to give cis-[FeIII(CN)4(CH3CN)2]1− as stable product in acetonitrile. Speciation of the oxidation product by DFT calculations is underpinned by good agreement to experimental data.

In-situ FTIR studies on the electrochemical oxidation of histidine and tyrosine

1999 ◽  
Vol 463 (2) ◽  
pp. 218-223 ◽  
Author(s):  
K. Ogura ◽  
M. Kobayashi ◽  
M. Nakayama ◽  
Y. Miho
Keyword(s):  
Electrochemical Oxidation ◽  
In Situ Ftir ◽  
Ftir Studies
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