Electrodialytic treatment for metal removal from sewage sludge ash from fluidized bed combustion

2010 ◽  
Vol 176 (1-3) ◽  
pp. 1073-1078 ◽  
Author(s):  
M. Pazos ◽  
G.M. Kirkelund ◽  
L.M. Ottosen
2015 ◽  
Vol 30 (S1) ◽  
pp. S31-S35 ◽  
Author(s):  
B. Peplinski ◽  
C. Adam ◽  
B. Adamczyk ◽  
R. Müller ◽  
M. Michaelis ◽  
...  

For the first time evidence is provided that a nanocrystalline and stacking-disordered, chemically stabilized β-cristobalite form of AlPO4 occurs in a sewage sludge ash (SSA). This proof is based on a combined X-ray powder diffraction and X-ray fluorescence investigation of an SSA produced at a large-scale fluidized bed incineration facility serving a catching area with a population of 2 million. The structural and chemical characterization was carried out on ‘as received’ SSA samples as well as on solid residues remaining after leaching this SSA in sodium hydroxide solution. Thus, it was ascertained that the observed nanocrystalline and stacking-disordered cristobalite-like component belongs to the aluminum phosphate component of this SSA, rather than to its silicon dioxide component. In addition, a direct proof is presented that the chemically stabilized β-cristobalite form of AlPO4 does crystallize from X-ray amorphous precursors under conditions that mimic the huge heating rate and short retention time (just seconds at T ≈ 850°C), typical for fluidized bed incinerators.


2008 ◽  
Vol 28 (12) ◽  
pp. 2709-2722 ◽  
Author(s):  
H. Mattenberger ◽  
G. Fraissler ◽  
T. Brunner ◽  
P. Herk ◽  
L. Hermann ◽  
...  

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