The use of artificial neural network (ANN) for modeling of COD removal from antibiotic aqueous solution by the Fenton process

2010 ◽  
Vol 179 (1-3) ◽  
pp. 127-134 ◽  
Author(s):  
Emad S. Elmolla ◽  
Malay Chaudhuri ◽  
Mohamed Meselhy Eltoukhy
2013 ◽  
Vol 69 (4) ◽  
pp. 768-774 ◽  
Author(s):  
André L. N. Mota ◽  
Osvaldo Chiavone-Filho ◽  
Syllos S. da Silva ◽  
Edson L. Foletto ◽  
José E. F. Moraes ◽  
...  

An artificial neural network (ANN) was implemented for modeling phenol mineralization in aqueous solution using the photo-Fenton process. The experiments were conducted in a photochemical multi-lamp reactor equipped with twelve fluorescent black light lamps (40 W each) irradiating UV light. A three-layer neural network was optimized in order to model the behavior of the process. The concentrations of ferrous ions and hydrogen peroxide, and the reaction time were introduced as inputs of the network and the efficiency of phenol mineralization was expressed in terms of dissolved organic carbon (DOC) as an output. Both concentrations of Fe2+ and H2O2 were shown to be significant parameters on the phenol mineralization process. The ANN model provided the best result through the application of six neurons in the hidden layer, resulting in a high determination coefficient. The ANN model was shown to be efficient in the simulation of phenol mineralization through the photo-Fenton process using a multi-lamp reactor.


2018 ◽  
Vol 65 ◽  
pp. 05004
Author(s):  
Augustine Chioma Affam ◽  
Malay Chaudhuri ◽  
Chee Chung Wong ◽  
Chee Swee Wong

The study examined artificial neural network (ANN) modeling for the prediction of chlorpyrifos, cypermethrin and chlorothalonil pesticides degradation by the FeGAC/H2O2 process. The operating condition was the optimum condition from a series of experiments. Under these conditions; FeGAC 5 g/L, H2O2 concentration 100 mg/L, pH 3 and 60 min reaction time, the COD removal obtained was 96.19%. The ANN model was developed using a three-layer multilayer perceptron (MLP) neural network to predict pesticide degradation in terms of COD removal. The configuration of the model with the smallest mean square error (MSE) of 0.000046 contained 5 inputs, 9 hidden and, 1 output neuron. The Levenberg–Marquardt backpropagation training algorithm was used for training the network, while tangent sigmoid and linear transfer functions were used at the hidden and output neurons, respectively. The predicted results were in close agreement with the experimental results with correlation coefficient (R2) of 0.9994 i.e. 99.94% showing a close agreement to the actual experimental results. The sensitivity analysis showed that FeGAC dose had the highest influence with relative importance of 25.33%. The results show how robust the ANN model could be in the prediction of the behavior of the FeGAC/H2O2 process.


Molecules ◽  
2020 ◽  
Vol 25 (14) ◽  
pp. 3263
Author(s):  
Taimur Khan ◽  
Teh Sabariah Binti Abd Manan ◽  
Mohamed Hasnain Isa ◽  
Abdulnoor A.J. Ghanim ◽  
Salmia Beddu ◽  
...  

This research optimized the adsorption performance of rice husk char (RHC4) for copper (Cu(II)) from an aqueous solution. Various physicochemical analyses such as Fourier transform infrared spectroscopy (FTIR), field-emission scanning electron microscopy (FESEM), carbon, hydrogen, nitrogen, and sulfur (CHNS) analysis, Brunauer–Emmett–Teller (BET) surface area analysis, bulk density (g/mL), ash content (%), pH, and pHZPC were performed to determine the characteristics of RHC4. The effects of operating variables such as the influences of aqueous pH, contact time, Cu(II) concentration, and doses of RHC4 on adsorption were studied. The maximum adsorption was achieved at 120 min of contact time, pH 6, and at 8 g/L of RHC4 dose. The prediction of percentage Cu(II) adsorption was investigated via an artificial neural network (ANN). The Fletcher–Reeves conjugate gradient backpropagation (BP) algorithm was the best fit among all of the tested algorithms (mean squared error (MSE) of 3.84 and R2 of 0.989). The pseudo-second-order kinetic model fitted well with the experimental data, thus indicating chemical adsorption. The intraparticle analysis showed that the adsorption process proceeded by boundary layer adsorption initially and by intraparticle diffusion at the later stage. The Langmuir and Freundlich isotherm models interpreted well the adsorption capacity and intensity. The thermodynamic parameters indicated that the adsorption of Cu(II) by RHC4 was spontaneous. The RHC4 adsorption capacity is comparable to other agricultural material-based adsorbents, making RHC4 competent for Cu(II) removal from wastewater.


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