Calcium polysulfide treatment of Cr(VI)-contaminated soil

2010 ◽  
Vol 179 (1-3) ◽  
pp. 650-657 ◽  
Author(s):  
Maria Chrysochoou ◽  
Daniel R. Ferreira ◽  
Chad P. Johnston
Chemosphere ◽  
2019 ◽  
Vol 227 ◽  
pp. 657-661 ◽  
Author(s):  
Wenyi Yuan ◽  
Weitong Xu ◽  
Ziwei Zhang ◽  
Xiaoyan Wang ◽  
Qiwu Zhang ◽  
...  

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Xilin Li ◽  
Xiaowan Yu ◽  
Ling Liu ◽  
Jianlin Yang

AbstractUsing calcium polysulfide as the reducing agent, synthetic zeolite as the adsorbent, and cement as the curing agent, the dual-index orthogonal test method was used to determine the best remediation dosage of chromium-contaminated soil. On this basis, through the dry–wet cycle test, the durability of the chromium-contaminated soil after repair is analyzed from the perspectives of unconfined compressive strength, toxic leaching concentration, quality loss, and microscopic characterization. Test results showed that the optimal ratio for the joint repair of chromium-contaminated soil was 3 times the amount of CaS5, 15% synthetic zeolite, and 20% cement. With the increase in the number of wet–dry cycles, the unconfined compressive strength of the composite preparation combined to repair chromium-contaminated soil was first increased and then reduced, and the concentration of Cr(VI) and total chromium in the leachate was first decreased and then increased. The higher the chromium content of the contaminated soil was, the lower the unconfined compressive strength, and the higher the leaching concentration of Cr(VI) and total chromium were. With the increase in cycle times, the cumulative mass-loss rate of composite preparations for repairing chromium-contaminated soil gradually increased, and the higher the chromium content was, the higher the cumulative mass-loss rate, which was less than 2%, reflecting the combination of composite preparations for repairing chromium-contaminated soil to have good durability. Microscopic and macroscopic results are consistent with each other.


2018 ◽  
Vol 8 (9) ◽  
pp. 1431 ◽  
Author(s):  
Ting-Ting Zhang ◽  
Qiang Xue ◽  
Ming-Li Wei

Ferrous sulfate (FeSO4) and calcium polysulfide (CaS5) stabilization are practical approaches to stabilizing hexavalent chromium (Cr(VI))-contaminated soil. The leachability and stability of Cr(VI) and Cr are important factors affecting the effectiveness of stabilized Cr(VI)-contaminated soil. This study compared the leachability and stability of Cr(VI) and Cr in Cr(VI)-contaminated soil stabilized by using FeSO4 and CaS5. The contaminated soil was characterized before and after stabilization, and the effectiveness of FeSO4 and CaS5 stabilization was assessed using leaching, bioaccessibility, alkaline digestion, sequential extraction, and X-ray diffraction tests. Results showed that FeSO4 and CaS5 significantly reduced the leachability and Cr(VI) content in the contaminated soil. The acid-buffering capacity and stability (leachability, bioaccessibility, speciation distribution, and mineral composition) of the Cr(VI)/Cr and Cr(VI) content of CaS5 were better than those of FeSO4. This study demonstrated that CaS5 had a better effect than FeSO4 on the stabilization of Cr(VI) in Cr(VI)-contaminated soil. The CaS5 significantly enhanced the stabilization and immobilization of Cr(VI) and reduced its leachability and toxicity.


2019 ◽  
Vol 10 (3) ◽  
pp. 148
Author(s):  
Nesreen Kurdy Al-Obaidy ◽  
Assad Al-Shueli ◽  
Hawraa Sattar ◽  
Zainab Majeed ◽  
Noor Al Huda Hamid

Author(s):  
A.I. Barbashev ◽  
◽  
S.N. Sushkova ◽  
T.M. Minkina ◽  
T.S. Dudnikova ◽  
...  

The effect of diatomite and tripoli added into the soil artificially contaminated with benzo[a]pyrene was studied. A decrease in the toxic effect of BaP on barley plants was established when diatomite and tripoli were added as ameliorants to contaminated soil. The improvement of plants grown сharacteristics on soils contaminated with BaP with the addition of diatomite and tripoli was shown up to 2-4 times compare to contaminated samples.


Author(s):  
V.V. Zinchenko ◽  
◽  
E.S Fedorenko ◽  
A.V Gorovtsov ◽  
T.M Minkina ◽  
...  

As a result of the model experiment, an increase in the enzymatic activity of meadow chernozem of the impact zone of Ataman Lake with the introduction of a strains mixture of metal-resistant microorganisms into the soil was established. The experiment has shown that the application of bacterial strains increases the dehydrogenase activity of contaminated soil by 51.8% compared to the variant without remediation


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