Luminescence properties and energy transfer behavior of Dy3+/Tm 3+ co-doped phosphate glasses with high moisture-resistance and thermal stability for W-LEDs

2021 ◽  
Vol 236 ◽  
pp. 118087
Author(s):  
Dongyu He ◽  
Yongzheng Fang ◽  
Meisong Liao ◽  
Guoying Zhao ◽  
Yan Sun ◽  
...  
2011 ◽  
Vol 130 (1-2) ◽  
pp. 346-351 ◽  
Author(s):  
Xiaoluan Liang ◽  
Zhongwen Xing ◽  
Yinyao Liu ◽  
Weina Xu ◽  
Yunxia Yang ◽  
...  

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Ning Liu ◽  
Lefu Mei ◽  
Libing Liao ◽  
Jie Fu ◽  
Dan Yang

Abstract What ideal w-LED phosphors always aim to do is to achieve a single phase near-sunlight emission phosphor simultaneously with both high luminescence efficiency and high thermal stability at operation temperature. And It is well known that apatite compound phosphors are one of the most promising optical materials to realize those above because of their unique structure enhanced luminescence properties and thermal stability. Here, we synthesized a co-doped single phase apatite phosphors Ca2La8(SiO4)6O2:Dy3+/Sm3+ (CLSO:Dy3+/Sm3+) for white light emission, which was provided with excellent thermal stability and of which luminescence intensity at 150 °C still was 92 percentage of that at room temperature. Moreover, X-ray diffraction technique, Fourier transform infrared spectroscopy, scanning electron microscope were employed to characterization of phase structure and morphology, and consequently pure apatite structure and gravel-like morphology of phosphors were proved. Analysis of photoluminescence spectra indicated that concentration quenching effect exist in single-doped CLSO:Dy3+ phosphors owing to dipole-dipole interaction between Dy3+ ions. It is revealed that maybe exist Dy3+ ↔ Sm3+ bilateral non-radiative energy transfer processes in Dy3+/Sm3+ co-doped CLSO system by PL spectra and decay curves. And variation of Sm3+ ion concentration can control color emission, namely CIE chromaticity coordinates and correlated color temperature, finally to achieve white light emission (0.309,0.309) with CCT 6848 K, able to be a potential candidate for commercial lighting applications.


RSC Advances ◽  
2017 ◽  
Vol 7 (83) ◽  
pp. 52995-53001 ◽  
Author(s):  
Ziyao Wang ◽  
Xifeng Hou ◽  
Yangai Liu ◽  
Zhuang Hui ◽  
Zhaohui Huang ◽  
...  

Eu2+, Eu3+ and Mn4+ co-doped Sr4Al14O25 phosphors were synthesized in air by high temperature solid-state reaction.


2021 ◽  
pp. 118082
Author(s):  
Hai Ma ◽  
Xiaodan Wang ◽  
Feifei Chen ◽  
Jiafan Chen ◽  
Xionghui Zeng ◽  
...  

2017 ◽  
Vol 7 (8) ◽  
pp. 2899 ◽  
Author(s):  
Dengke Xu ◽  
Rongfei Wei ◽  
Jiangkun Cao ◽  
Hai Guo

2015 ◽  
Vol 335 ◽  
pp. 90-93 ◽  
Author(s):  
Lefu Mei ◽  
Jing Xie ◽  
Haikun Liu ◽  
Libing Liao ◽  
Yuanyuan Zhang ◽  
...  

2015 ◽  
Vol 3 (16) ◽  
pp. 4197-4204 ◽  
Author(s):  
Mingyue Chen ◽  
Zhiguo Xia ◽  
Quanlin Liu

The energy transfer process from Ce3+ to Tb3+ in Ca6Ba(PO4)4O and its mechanisms have been studied.


2015 ◽  
Vol 3 (21) ◽  
pp. 5516-5523 ◽  
Author(s):  
Jian Chen ◽  
Yan-gai Liu ◽  
Lefu Mei ◽  
Ziyao Wang ◽  
Minghao Fang ◽  
...  

A series of Eu2+- and Mn2+-coactivated KMg4(PO4)3phosphors were prepared by conventional high temperature solid-state reactions. Their luminescence properties, emission red shifts and the energy transfer between Eu2+and Mn2+were investigated and the related mechanisms were discussed in detail.


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