Pore characterization and the controls of organic matter and quartz on pore structure: Case study of the Niutitang Formation of northern Guizhou Province, South China

2019 ◽  
Vol 61 ◽  
pp. 18-31 ◽  
Author(s):  
Zhaodong Xi ◽  
Shuheng Tang ◽  
Jin Li ◽  
Zhongyao Zhang ◽  
Heqi Xiao
Keyword(s):  
Organic Matter ◽  
Pore Structure ◽  
South China ◽  
Guizhou Province ◽  
Pore Characterization ◽  
Niutitang Formation

scholarly journals Controls of Distinct Mineral Compositions on Pore Structure in Over-Mature Shales: A Case Study of Lower Cambrian Niutitang Shales in South China

Minerals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 51
Author(s):  
Xing Niu ◽  
Detian Yan ◽  
Mingyi Hu ◽  
Zixuan Liu ◽  
Xiaosong Wei ◽  
...  
Keyword(s):  
Organic Matter ◽  
Pore Structure ◽  
Clay Minerals ◽  
Mineral Composition ◽  
South China ◽  
Lower Cambrian ◽  
Great Influence ◽  
Rock Composition ◽  
Niutitang Formation ◽  
Siliceous Shale

Investigating the impacts of rock composition on pore structure is of great significance to understand shale gas occurrence and gas accumulation mechanism. Shale samples from over-mature Niutitang formation of Lower Cambrian in south China were measured by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), low pressure N2 and CO2 adsorption to elucidate the controls of distinct mineral composition on pore development. Two distinct lithofacies, namely siliceous shale and argillaceous shale, were ascertained based on their mineral composition. Due to the variability of mineral composition in different lithofacies, pore structure characteristics are not uniform. Pores in siliceous shales are dominated by interparticle pores and organic matter (OM) pores, among which the interparticle pores are mainly developed between authigenic quartz. Furthermore, most of these interparticle pores and cleavage-sheet intraparticle pores within clay minerals are usually filled by amorphous organic matter that is host to OM pores. Due to the lack of rigid minerals, argillaceous shale was cemented densely, resulting in few interparticle pores, while cleavage-sheet intraparticle pores within clay minerals are common. Comparing siliceous shales with argillaceous shales, specific surface areas and pore volumes are higher on the former than on the latter. The content of total organic carbon (TOC) and authigenic quartz have a great influence on micropore structures, but less on mesopore structure for siliceous shales. The rigid framework structure formed by authigenic quartz is believed to be able to prevent primary interparticle pores from mechanical compaction and facilitate the formation of organic matter-associated pores. In terms of argillaceous shales, due to the lack of authigenic quartz, interparticle pores were rarely developed and its pore structure is mainly controlled by illite content.

scholarly journals Elemental Geochemical Characterization of Sedimentary Conditions and Organic Matter Enrichment for Lower Cambrian Shale Formations in Northern Guizhou, South China

Minerals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 793
Author(s):  
Shuangbiao Han ◽  
Yuanlong Zhang ◽  
Jie Huang ◽  
Yurun Rui ◽  
Zhiyuan Tang
Keyword(s):  
Organic Matter ◽  
Deposition Rate ◽  
Black Shale ◽  
South China ◽  
Shale Gas ◽  
Geochemical Data ◽  
Shale Formations ◽  
Average Value ◽  
Geochemical Elements ◽  
Niutitang Formation

The black shale deposited in the Niutitang Formation and its adjacent strata is considered to be a favorable source rock in northern Guizhou of south China and has become a target horizon for shale gas exploration in recent years. Based on SQ-1 and CY-1 core samples, the organic matter properties and geochemical elements were obtained through experimental analysis. Provenance, paleoredox, paleoclimate, paleoproductivity and deposition conditions were analyzed, and the sedimentary effects on organic matter enrichment were discussed. The results show that total organic carbon (TOC) is between 0.22–10.10 wt.% in SQ-1, with an average of 2.60 wt.%, and TOC is between 0.23–7.7 wt.% in CY-1, with an average of 1.45 wt.%. The geochemical data of the samples indicate that the black shale of the Niutitang Formation and adjacent strata are deposited in the tectonic background of the passive continental margin. The provenance shows moderate weathering, with hot and humid paleoenvironmental characteristics and fast deposition rate. Using multiple ancient redox indicators, it is concluded that the formation has undergone changes in the oxidizing environment and anaerobic environment during deposition. According to the (La/Yb)N value (the average value of SQ-1 is 1.23 and the average value of CY-1 is 1.26), it shows a faster deposition rate of the two wells and shortens the residence time of organic matter in the microbial degradation zone. The Babio indicates that the bottom has a high paleoproductivity when deposited. Considering the influencing factors, the paleoproductivity mainly controls the organic matter enrichment, followed by ancient redox conditions and the deposition rate. The research results provide a reference for deepening sedimentary understanding and shale gas exploration in the study area.

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