Anomalous elastic behaviour of xSrO-10PbO-(90-x)B2O3 glass system

Mixed alkali tungsten borate glasses xLi2O–(30–x) K2O–10WO3–60B2O3 (0 < x < 30) were prepared from the melts. These glasses were characterized using X-ray diffraction, differential scanning calorimetry and density measurements. Optical absorption studies were carried out as a function of alkali content to look for mixed alkali effect (MAE) on the spectral properties of these glasses. From the study of ultraviolet absorption edge, the optical band gap energies and Urbach energies were evaluated. The average electronic polarizability of the oxide ion, optical basicity and the interaction parameters were also evaluated for all the glasses. Many of these parameters vary non-linearly exhibiting a minima or maxima with increasing alkali concentration, indicating the mixed alkali effect. An attempt is made to interpret MAE in this glass system in terms of its glass structure.

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Thermoluminescence features of Er3+ doped BaO-ZnO-LiF-B2O3 glass system for high-dose gamma dosimetry

Ceramics International ◽

10.1016/j.ceramint.2020.04.276 ◽

2020 ◽

Vol 46 (11) ◽

pp. 19343-19353 ◽

Cited By ~ 1

Author(s):

Nimitha S. Prabhu ◽

K. Sharmila ◽

H.M. Somashekarappa ◽

G. Lakshminarayana ◽

Soumen Mandal ◽

...

Keyword(s):

Glass System ◽

High Dose ◽

B2o3 Glass

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Dielectric dispersion in the PbO–MoO3–B2O3 glass system

Solid State Communications ◽

10.1016/j.ssc.2004.07.042 ◽

2004 ◽

Vol 132 (3-4) ◽

pp. 235-240 ◽

Cited By ~ 50

Author(s):

P. Syam Prasad ◽

B.V. Raghavaiah ◽

R. Balaji Rao ◽

C. Laxmikanth ◽

N. Veeraiah

Keyword(s):

Dielectric Dispersion ◽

Glass System ◽

B2o3 Glass

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Control of spectroscopic fluorescence parameters of Nd3+ ions as a function of concentration in a SiO2–Na2O–Al2O3–B2O3 glass system

Chemical Physics Letters ◽

10.1016/j.cplett.2011.04.034 ◽

2011 ◽

Vol 508 (1-3) ◽

pp. 125-129 ◽

Cited By ~ 29

Author(s):

E.O. Serqueira ◽

N.O. Dantas ◽

M.J.V. Bell

Keyword(s):

Glass System ◽

Fluorescence Parameters ◽

B2o3 Glass

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Physical, optical properties and radiation shielding studies of xLa2O3-(100-x)B2O3 glass system

Ceramics International ◽

10.1016/j.ceramint.2019.10.293 ◽

2020 ◽

Vol 46 (4) ◽

pp. 5380-5386 ◽

Cited By ~ 11

Author(s):

Y. Al-Hadeethi ◽

M.I. Sayyed ◽

J. Kaewkhao ◽

Bahaaudin M. Raffah ◽

Rahma Almalki ◽

...

Keyword(s):

Optical Properties ◽

Radiation Shielding ◽

Glass System ◽

B2o3 Glass

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Investigation of a competent non-toxic Bi2O3−Li2O−CeO2−MoO3−B2O3 glass system for nuclear radiation security applications

Journal of Non-Crystalline Solids ◽

10.1016/j.jnoncrysol.2020.120235 ◽

2020 ◽

Vol 545 ◽

pp. 120235 ◽

Cited By ~ 5

Author(s):

Parminder Kaur ◽

K.J. Singh ◽

Sonika Thakur ◽

Murat Kurudirek

Keyword(s):

Glass System ◽

Nuclear Radiation ◽

Security Applications ◽

B2o3 Glass

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Effect of TiO2 addition on the chemical durability of Bi2O3–SiO2–ZnO–B2O3 glass system

Journal of Non-Crystalline Solids ◽

10.1016/j.jnoncrysol.2008.04.026 ◽

2008 ◽

Vol 354 (42-44) ◽

pp. 4777-4785 ◽

Cited By ~ 21

Author(s):

C. Fredericci ◽

H.N. Yoshimura ◽

A.L. Molisani ◽

H. Fellegara

Keyword(s):

Chemical Durability ◽

Glass System ◽

Tio2 Addition ◽

B2o3 Glass

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Studies on optimizing sesquioxide contents to enhance luminescence efficiency of Pr3+ ions in PbO−PbF2−B2O3 glass system

Journal of Molecular Structure ◽

10.1016/j.molstruc.2014.04.078 ◽

2014 ◽

Vol 1073 ◽

pp. 164-173 ◽

Cited By ~ 13

Author(s):

D. Rajeswara Rao ◽

G. Sahaya Baskaran ◽

P. Ramesh Babu ◽

Y. Gandhi ◽

N. Veeraiah

Keyword(s):

Glass System ◽

Luminescence Efficiency ◽

B2o3 Glass

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Effect of the addition of Fe2O3 and heat treatment duration on the magnetic susceptibility of V2O5-P2O5-B2O3 glass system

Journal of Materials Science Materials in Electronics ◽

10.1007/bf00695510 ◽

1992 ◽

Vol 3 (3) ◽

pp. 144-146 ◽

Cited By ~ 4

Author(s):

I. Kashif ◽

H. Farouk ◽

S. A. Aly ◽

A. M. Sanad ◽

M. H. El-Kottamy ◽

...

Keyword(s):

Heat Treatment ◽

Magnetic Susceptibility ◽

Treatment Duration ◽

Glass System ◽

Heat Treatment Duration ◽

B2o3 Glass

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DSC, ESR AND IR SPECTRAL STUDIES ON Li2O–WO3–B2O3 GLASS SYSTEM DOPED WITH VANADIUM IONS

Functional Materials Letters ◽

10.1142/s1793604709000661 ◽

2009 ◽

Vol 02 (03) ◽

pp. 127-130 ◽

Cited By ~ 8

Author(s):

LINGANABOINA SRINIVASA RAO ◽

TUMU VENKATAPPA RAO

Keyword(s):

Glass Transition ◽

Local Structure ◽

Glass Matrix ◽

Glass Forming Ability ◽

Glass System ◽

Spectral Studies ◽

Glass Forming ◽

System A ◽

Vanadium Ions ◽

B2o3 Glass

With in glass forming region of Li2O–WO3–B2O3 glass system, a particular composition 40Li2O–5WO3–(55 –x) B2O3 : x V2O5 (with x ranging from 0.2 to 0.8, all are in mol.%) is chosen. The DSC traces are obtained to identify the glass transition temperature ( Tg ) and the glass forming ability of all the glass samples. The ESR and IR spectra portray the local structure of the glass system and valance states of the vanadium ions in the glass matrix. As the content of V2O5 increases up to 0.6 mol.% in the glass system, a gradual conversion of vanadium ions from V5+ state to V4+ state is observed, causing the depolymerization in the glass matrix by the transformation of several glass forming units BO4 → BO3 and WO4 → WO6 .

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