(1,2,3,4,7-Pentamethylindenyl)rhodium complexes with arene ligands

2007 ◽  
Vol 692 (26) ◽  
pp. 5777-5787 ◽  
Author(s):  
Dmitry A. Loginov ◽  
Mikhail M. Vinogradov ◽  
Zoya A. Starikova ◽  
Elena A. Petrovskaya ◽  
Piero Zanello ◽  
...  
Keyword(s):  
Rhodium Complexes ◽  
Arene Ligands

Indenyl Rhodium Complexes with Arene Ligands: Synthesis and Application for Reductive Amination

2018 ◽  
Vol 37 (15) ◽  
pp. 2553-2562 ◽  
Author(s):  
Vladimir B. Kharitonov ◽  
Maria Makarova ◽  
Mikhail A. Arsenov ◽  
Yulia V. Nelyubina ◽  
Olga Chusova ◽  
...  
Keyword(s):  
Reductive Amination ◽  
Rhodium Complexes ◽  
Arene Ligands

Diphosphinoazine Rhodium(I) and Iridium(I) Complexes

2006 ◽  
Vol 71 (2) ◽  
pp. 197-206 ◽  
Author(s):  
Martin Pošta ◽  
Jan Čermák ◽  
Pavel Vojtíšek ◽  
Ivana Císařová
Keyword(s):  
Rhodium Complexes ◽  
Iridium Complexes ◽  
X Ray ◽  
First Time

The first rhodium complexes of diphosphinoazines [{RhCl(1,2-η:5,6-η-CH=CHCH2CH2CH=CHCH2CH2)}2 {μ-R2PCH2C(But)=NN=C(But)CH2PR2] (R = Ph, Cy, Pri) were prepared by cleavage of the bridge in chloro(cycloocta-1,5-diene)rhodium(I) dimer, the analogous iridium(I) complexes were also prepared for the first time. The X-ray structures of isostructural rhodium and iridium complexes with bis(dicyclohexylphosphino)pinacoloneazine were determined. Diphosphinoazine ligands in the complexes remained in (Z,Z) configuration bridging two RhCl(C8H12) units.

scholarly journals Platinum and rhodium complexes ligated by imidazolium-substituted phosphine as efficient and recyclable catalysts for hydrosilylation

RSC Advances ◽  
2019 ◽  
Vol 9 (50) ◽  
pp. 29396-29404 ◽  
Author(s):  
Magdalena Jankowska-Wajda ◽  
Olga Bartlewicz ◽  
Andrea Szpecht ◽  
Adrian Zajac ◽  
Marcin Smiglak ◽  
...  
Keyword(s):  
Rhodium Complexes ◽  
Recyclable Catalysts ◽  
High Yields

Platinum and rhodium complexes ligated by imidazolium substituted phosphine were obtained with high yields and applied as efficient catalysts.

Merging Molecular Recognition and Gold(I) Catalysis withTriphoscalix[6]arene Ligands

2021 ◽  
Author(s):  
Gianpiero Cera ◽  
Andrea Secchi ◽  
Arturo Arduini ◽  
Gabriele Giovanardi
Keyword(s):  
Molecular Recognition ◽  
Arene Ligands

scholarly journals 1,3-Diketone Calix[4]arene Derivatives—A New Type of Versatile Ligands for Metal Complexes and Nanoparticles

Molecules ◽  
2021 ◽  
Vol 26 (5) ◽  
pp. 1214
Author(s):  
Sergey N. Podyachev ◽  
Rustem R. Zairov ◽  
Asiya R. Mustafina
Keyword(s):  
Structural Diversity ◽  
Building Blocks ◽  
Structural Features ◽  
Structure Property ◽  
One Pot ◽  
Arene Ligands ◽  
Structure Property Relationships ◽  
New Type ◽  
Synthetic Routes ◽  
Magnetic Resonance Imaging Mri

The present review is aimed at highlighting outlooks for cyclophanic 1,3-diketones as a new type of versatile ligands and building blocks of the nanomaterial for sensing and bioimaging. Thus, the main synthetic routes for achieving the structural diversity of cyclophanic 1,3-diketones are discussed. The structural diversity is demonstrated by variation of both cyclophanic backbones (calix[4]arene, calix[4]resorcinarene and thiacalix[4]arene) and embedding of different substituents onto lower or upper macrocyclic rims. The structural features of the cyclophanic 1,3-diketones are correlated with their ability to form lanthanide complexes exhibiting both lanthanide-centered luminescence and magnetic relaxivity parameters convenient for contrast effect in magnetic resonance imaging (MRI). The revealed structure–property relationships and the applicability of facile one-pot transformation of the complexes to hydrophilic nanoparticles demonstrates the advantages of 1,3-diketone calix[4]arene ligands and their complexes in developing of nanomaterials for sensing and bioimaging.

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