Synthesis and structural characterization of three copper coordination polymers with pyridine derivatives from hydro(solvo)thermal in situ decarboxylation reactions of 2,5-dicarboxylpyridine

AbstractSynthesis and structural characterization of two heterodinuclear ZnII-LnIII complexes with the formula [ZnLn(HL)(µ-OAc)(NO3)2(H2O)x(MeOH)1-x]NO3 · n H2O · n MeOH [Ln = Pr (1), Nd (2)] and the crystal and molecular structure of [ZnNd(HL)(µ-OAc)(NO3)2(H2O)] [ZnNd(HL)(OAc)(NO3)2(H2O)](NO3)2 · n H2O · n MeOH (3) are reported. The asymmetrical compartmental ligand (E)-2-(1-(2-((2-hydroxy-3-methoxybenzylidene)amino)-ethyl)imidazolidin-2-yl)-6-methoxyphenol (H2L) is formed from N1,N3-bis(3-methoxysalicylidene)diethylenetriamine (H2valdien) through intramolecular aminal formation, resulting in a peripheral imidazoline ring. The structures of 1–3 were revealed by X-ray crystallography. The smaller ZnII ion occupies the inner N2O2 compartment of the ligand, whereas the larger and more oxophilic LnIII ions are found in the outer O2O2’ site. Graphic Abstract Synthesis and structural characterization of two heterodinuclear ZnII-LnIII complexes (Ln = Pr, Nd) bearing an asymmetrical compartmental ligand formed in situ from N1,N3-bis(3-methoxysalicylidene)diethylenetriamine (H2valdien) through intramolecular aminal formation are reported.

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Synthesis and structural characterization of new one- and two-dimensional lead(II) coordination polymers; new precursors for preparation of pure phase lead(II) oxide nanoparticles via thermal decomposition

Inorganica Chimica Acta ◽

10.1016/j.ica.2010.11.043 ◽

2011 ◽

Vol 367 (1) ◽

pp. 207-211 ◽

Cited By ~ 30

Author(s):

Lida Hashemi ◽

Ali Morsali ◽

Pascal Retailleau

Keyword(s):

Thermal Decomposition ◽

Coordination Polymers ◽

Structural Characterization ◽

Oxide Nanoparticles ◽

Two Dimensional ◽

Phase Lead ◽

Pure Phase

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Synthesis and structural characterization of an air and water stable divalent Europium squarate prepared by in situ reduction

Journal of Solid State Chemistry ◽

10.1016/j.jssc.2021.122048 ◽

2021 ◽

Vol 297 ◽

pp. 122048

Author(s):

Jason P. Stone ◽

Elizabeth A. Decoteau ◽

Matthew J. Polinski

Keyword(s):

Structural Characterization ◽

In Situ Reduction ◽

Divalent Europium

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Synthesis and structural characterization of three supramolecular coordination polymers constructed from different metal ions and 2,2′-bipyridyl-3,3′-dicarboxylic acid

Journal of Coordination Chemistry ◽

10.1080/00958972.2012.658382 ◽

2012 ◽

Vol 65 (5) ◽

pp. 754-762 ◽

Cited By ~ 7

Author(s):

Xiaoqing Cao ◽

Xu Zheng ◽

Meixi Chen ◽

Xinxin Xu ◽

Ting Sun ◽

...

Keyword(s):

Metal Ions ◽

Dicarboxylic Acid ◽

Coordination Polymers ◽

Structural Characterization ◽

Supramolecular Coordination

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Ambient Temperature Synthesis and Structural Characterization of Six Transition Metal Acetylenedicarboxylate Coordination Polymers

Zeitschrift für anorganische und allgemeine Chemie ◽

10.1002/zaac.202000265 ◽

2020 ◽

Vol 646 (19) ◽

pp. 1618-1625

Author(s):

Luke Best‐Thompson ◽

Paul J. Saines

Keyword(s):

Transition Metal ◽

Ambient Temperature ◽

Coordination Polymers ◽

Structural Characterization ◽

Temperature Synthesis

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Synthesis and structural characterization of homochiral coordination polymers with imidazole-based monocarboxylate ligands

Dalton Transactions ◽

10.1039/c9dt01237k ◽

2019 ◽

Vol 48 (24) ◽

pp. 8731-8739 ◽

Cited By ~ 1

Author(s):

Elena Borrego ◽

Antonio I. Nicasio ◽

Eleuterio Álvarez ◽

Francisco Montilla ◽

José Manuel Córdoba ◽

...

Keyword(s):

Coordination Polymers ◽

Structural Characterization ◽

Two Dimensional ◽

Bridging Ligands ◽

Silver Copper ◽

Copper And Zinc

Two-dimensional homochiral coordination polymers of sodium, silver, copper and zinc were obtained with 2alkyl,2-(1H-imidazol-1-yl)acetate anions as bridging ligands.

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