Peculiar Berriasian “Wealden” Shales of northwest Germany: Organic facies, depositional environment, thermal maturity and kinetics of petroleum generation

2021 ◽  
Vol 124 ◽  
pp. 104819
Author(s):  
Felix Froidl ◽  
Ralf Littke ◽  
Alireza Baniasad ◽  
Tianyu Zheng ◽  
Joschka Röth ◽  
...  
2011 ◽  
Vol 149 (1) ◽  
pp. 19-38 ◽  
Author(s):  
ALI SHEKARIFARD ◽  
FRANÇOIS BAUDIN ◽  
KAZEM SEYED-EMAMI ◽  
JOHANN SCHNYDER ◽  
FATIMA LAGGOUN-DEFARGE ◽  
...  

AbstractOrganic petrography and geochemical analyses have been carried out on shales, carbonaceous shales and coals of the Shemshak Group (Upper Triassic–Middle Jurassic) from 15 localities along the Alborz Range of Northern Iran. Thermal maturity of organic matter (OM) has been investigated using vitrinite reflectance, Rock-Eval pyrolysis and elemental analysis of kerogen. Reflectance of autochthonous vitrinite varies from 0.6 to 2.2% indicating thermally early-mature to over-mature OM in the Shemshak Group, in agreement with other maturity parameters used. The shales of the Shemshak Group are characterized by poor to high residual organic carbon contents (0.13 to 5.84%) and the presence of hydrogen-depleted OM, predominantly as a consequence of oxidation of OM at the time of deposition and the hydrogen loss during petroleum generation. According to light-reflected microscopy results, vitrinite/vitrinite-like macerals are dominant in the kerogen concentrates from the shaly facies. The coals and carbonaceous shales of the Shemshak Group show a wide range in organic carbon concentration (3.5 to 88.6%) and composition (inertinite- and vitrinite-rich types), and thereby different petroleum potentials. Thermal modelling results suggest that low to moderate palaeo-heat flow, ranging from 47 to 79 mW m−2 (57 mW m−2 on average), affected the Central-Eastern Alborz basin during Tertiary time, the time of maximum burial of the Shemshak Group. The maximum temperature that induced OM maturation of the Shemshak Group seems to be related to its deep burial rather than to a very strong heat flow related to an uppermost Triassic–Liassic rifting. The interval of petroleum generation in the most deeply buried part of the Shemshak Group (i.e. Tazareh section) corresponds to Middle Jurassic–Early Cretaceous times. Exhumation of the Alborz Range during Late Neogene time, especially along the axis of the Central-Eastern Alborz, where maximum vitrinite reflectance values are recorded, probably destroyed possible petroleum accumulations. However, on the northern flank of the Central-Eastern Alborz, preservation of petroleum accumulations may be expected. The northern part of the basin therefore seems the best target for petroleum exploration.


Energies ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 5615
Author(s):  
Marcos Escobar ◽  
Gonzalo Márquez ◽  
Blanca Guerrero ◽  
Patricia Marín ◽  
Carlos Boente ◽  
...  

The organic geochemical features of 30 sampled oils from the northern Bolivar Coastal Complex (Lake Maracaibo Basin, NW Venezuela) were examined by combining carbon isotope, classical biomarker, and extended diamondoid analyses to clarify source facies and to assess the thermal maturity and extent of biodegradation of the oils analyzed. In this work, oils are understood as a mixture of two episodes of petroleum generation from the La Luna Formation: a paleobiodegraded oil pulse during Paleogene times and a late pulse having a higher maturity in the post-Oligocene. For the oil samples analyzed, results revealed a mixing composed of different proportions of almost a terrestrially derived siliciclastic-sourced and a purely marine carbonate-sourced oil pulse. Moreover, two main groups of oils were identified by means of hierarchical cluster analysis. Finally, inter- and intrafield variations in the extent of biodegradation were also assessed using two classification schemes (Peters and Moldowan, and Manco scales).


1999 ◽  
Vol 39 (1-3) ◽  
pp. 251-278 ◽  
Author(s):  
Junghyun Kim ◽  
Thomas Wagner ◽  
Martina Bachmann ◽  
Jochen Kuss

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