Ecological risk by potentially toxic elements in surface sediments of the Lake Maracaibo (Venezuela)

The evaluation of potential ecological risk of aquatic sediments associated with the presence of potentially toxic elements (PTE) determines its degree of danger on native biota. In this work, the potential ecological risk of V, Ti, Cr, Ni, Cu, Zn, As, Se, Cd, Sn, Hg and Pb in superficial sediments is explained in three different areas of Lake Maracaibo: El Tablazo Bay, Strait of Maracaibo and the lake itself, through a multi-guideline approach (elemental enrichment (enrichment factor, contamination degree, pollutant load index and geo-accumulation index), sediment quality guidelines and risk assessment code). The PTE levels ranged from < 0.025 to 176.722 mg·kg−1 DW, with an overall proportion of V > Ti > Pb > Zn > Cr > Cu > Ni > As > Cd > Se > Hg > Sn. The PTE concurrent effect on biota was El Tablazo Bay > lake > Strait of Maracaibo. The superficial sediments of Lake Maracaibo constitute a medium with a high potential ecological risk on estuarine biota. This is mainly due to the levels of As in El Tablazo Bay, Cd in the Strait of Maracaibo and Pb in the lake area. This represents a latent toxicity hazard for native biological communities and other associated organisms.

Review of Chemical EOR Projects in Venezuela: From Light to Extra-Heavy Oil Reservoirs

Venezuela is widely recognized as an oil producer country of great potential thanks to its huge hydrocarbon resources located in Eastern Venezuela and Maracaibo basins, comprising the largest oil reserves in the world, with around 302 billion barrels according to recent OPEC and EIA estimates [1]. Despite those immense hydrocarbon resources, oil production in Venezuela is a challenge in mature and waterflooded reservoirs, as well as in thin highly viscous oil reservoirs where thermal IOR/EOR methods are not technically and/or economically feasible. This is the case of many oil fields in Lake Maracaibo and in La Faja Petrolifera Del Orinoco (La FPO), where the application of Chemical Enhanced Oil Recovery (CEOR) methods is being envisaged with a view to increasing oil recovery factors. The objective of this article is to review most of the Venezuelan CEOR projects reported in the literature to identify the main insights/status of each reported project and its potentiality of application to increase oil recovery. A detailed description of each project and its main conclusions is given. According to this literature review, CEOR project evaluations for Venezuelan reservoirs have been performed mostly at laboratory and numerical simulation scales, including several pilot test designs. Only 2 executed pilot tests have been reported (ASP flooding at VLA-6/9/21 Field in Lake Maracaibo and polymer flooding at Petrocedeño Field in La FPO). Despite the encouraging results in terms of oil recovery at laboratory scale, the greatest challenges related to the application of CEOR methods in Venezuelan reservoirs are linked to technical and economic aspects (e.g. high adsorption/retention of chemicals, mobility control, complex emulsions, separation of phases, water treatments, costs of investment, oil prices, etc.).

Review and Microphysics of the maximum electricity atmospheric activity in the Word: the Catatumbo Lightning (Venezuela)

A review and phenomenology on the greatest lightning hotspots in the world, known as the Catatumbo Lightning, located southeast of Lake Maracaibo (Venezuela), is presented. A microphysical model is presented to explain the charging process through electrical displacement within the cells of the cloud, incorporating the role of the self-polarization of ice and methane molecules as pyroelectric aerosol, which accounts for the phenomenology and is consistent with the electrification in thunderstorm. It is concluded that the pyroelectric model allows to explain the phenomenology of the rapid discharges of the flashes in the Catatumbo lightning and could be applied in outer planetary lightning.

Aquatic Wildmeat Consumption of Guiana Dolphins (Sotalia guianensis) in Lake Maracaibo System, Venezuela

In many regions of the world, the use of cetaceans as bait or protein source has been reported. In most cases the individuals are from bycatch but also from intentionally killed animals. Cetaceans with coastal habits are more susceptible to negative interactions with small-scale fisheries, as in the case of the Guiana dolphin (Sotalia guianensis) in the Lake Maracaibo system. For decades, the use of Guiana dolphins by local communities has been reported in this region and is culturally supported by recipes for its preparation. Most of these data was outdated and some were anecdotal, so the objective of this work was to collect systematically data through surveys using the snowball method in seven artisanal fishing communities and to try to quantify the capture rate and to inquire about the potential impact of this practice on the population of Guiana dolphin. From 2017 to 2019, 95 semi-structured interviews were applied. An average bycatch of 180 individuals/year was obtained, the highest catch rate in the entire geographic distribution, an alarming situation considering that the surveys were not carried out in all the fishing ports, generating an underestimation. A total of 78% of interviewed recognized at least one bycatch event during their fishing effort. Surveys revealed a higher incidence of entanglement of offspring and juveniles (78%). 77% of the respondents deny the sale and commercialization of the species, while 5% mention some type of trade. The most frequent part exploited was the dorsal muscle, confirmed by fishermen (97%, n = 72) and the rest of the animal is discarded. During this investigation three episodes of directed capture were recorded, affecting a total of 23 individuals, two of them were pregnant females. The interviews also revealed that the majority of fishermen (93%) recognize the capture of this species as illegal. Considering the vulnerability of the Guiana dolphin in the country, the high incidence of capture and consumption and the lack of surveillance and sanctions by government entities, it is imperative to immediate actions to mitigate the negative impact on the population.

Origin and Biodegradation of Crude Oils from the Northernmost Fields in the Bolivar Coastal Complex (Zulia State, Venezuela)

The organic geochemical features of 30 sampled oils from the northern Bolivar Coastal Complex (Lake Maracaibo Basin, NW Venezuela) were examined by combining carbon isotope, classical biomarker, and extended diamondoid analyses to clarify source facies and to assess the thermal maturity and extent of biodegradation of the oils analyzed. In this work, oils are understood as a mixture of two episodes of petroleum generation from the La Luna Formation: a paleobiodegraded oil pulse during Paleogene times and a late pulse having a higher maturity in the post-Oligocene. For the oil samples analyzed, results revealed a mixing composed of different proportions of almost a terrestrially derived siliciclastic-sourced and a purely marine carbonate-sourced oil pulse. Moreover, two main groups of oils were identified by means of hierarchical cluster analysis. Finally, inter- and intrafield variations in the extent of biodegradation were also assessed using two classification schemes (Peters and Moldowan, and Manco scales).

Damage levels caused by Capulinia linarosae Kondo & Gullan (Hemiptera: Eriococcidae) on guava crops under two agronomic management practices in the south of lake Maracaibo, Venezuela

The objective of the present study was to test the hypothesis of no difference in the level of damage caused by the guava cottony scale Capulinia linarosae (Hemiptera: Eriococcidae) in two guava crops under different agronomic management practices: a crop whose management practices tend to be organic (PUA) was compared with another subjected to chemical methods (PUB). Forty plants in each farm were selected randomly to estimate damage on stems, branches, leaves, and fruits. Levels of damage were statistically different (P<0.0001) between the control methods for stems and branches, but not for leaves or fruits (P>0.05). It was concluded that the magnitude of damage is greater in the crop under chemical control and that agronomic management is a critical factor. Excess of insecticides and incorrect application of pruning causes damage to the plant’s bark and favor the insect proliferation. While the use of a sulfur-calcium broth in PUA regulates pH, favors the effect of other products and promotes the growth of green algae which cover bark crevices avoiding the cottony scale establishment. The excessive use of agrochemicals for weed control in UPB causes soil nudity and kills natural enemies, whereas in the UPA grass layer is clipped at 20 cm on the soil maintaining its moisture and creating habitat favorable to natural enemies.

Epidemiological and clinical characteristics of patients with malaria admitted to a hospital in Mérida, Venezuela

Background Malaria is expanding rapidly across Venezuela, spreading outwards from traditional high transmission regions in the southeast of the country, but the lack of official data make it impossible to understand the reasons for this expansion and to estimate its real magnitude. This study aims to evaluate the epidemiological characteristics driving the re-emergence of malaria in Mérida, a state in the west of Venezuela, where no cases have been reported since 2003, and also to study the clinical presentation of the disease in patients presenting with malaria. Methods Thirty-three patients who presented with anemia and fever and with a microscopic diagnosis of malaria were examined and interviewed. Data were collected in standardized forms and analyzed. One-way analysis of variance was used to study differences among patients infected with different parasites. Results Twenty-two patients were from the Zulia state and eleven were from the Mérida state, mainly from the lowlands south of Lake Maracaibo. Six of these patients traveled to the Bolívar state between 2017 and 2019. Thirteen patients presented with the WHO criteria for severe malaria. Conclusions: Domestic migration to the southeast of Venezuela may have played an important role in the expansion of malaria in previously existing endemic areas of transmission and also in the increase in the number of cases of severe malaria.