Investigation of microstructural, optical, physical properties and dielectric relaxation process of sulphur incorporated selenium–tellurium ternary glassy systems

2021 ◽  
Vol 257 ◽  
pp. 123793
Author(s):  
Rittwick Mondal ◽  
Dipankar Biswas ◽  
Sweta Paul ◽  
Anindya Sundar Das ◽  
Chiranjib Chakrabarti ◽  
...  
2021 ◽  
Vol 96 ◽  
pp. 107093
Author(s):  
Vera P. Pavlović ◽  
Dragana Tošić ◽  
Radovan Dojčilović ◽  
Duško Dudić ◽  
Miroslav D. Dramićanin ◽  
...  

2010 ◽  
Vol 65 (10) ◽  
pp. 854-858
Author(s):  
Vimal Sharma ◽  
Nagesh Thakur

The dielectric constant ε´ and dielectric loss ε´´ of the binary mixtures of tetramethylurea (TMU) and chlorobenzene (CB) have been calculated at 9.883 GHz by using standard standing microwave techniques. Gopalakrishna’s single frequency concentration variation method has been used to calculate dipole moment μ and dielectric relaxation time τ for different mole fractions of TMU in the binary mixture at different temperatures of 25 °C, 30 °C, 35 °C, and 40 °C. The variation of dielectric relaxation time with the mole fraction of TMU in the whole concentration range of the binary mixtures was found to be non-monotonic. The solute-solute and solute-solvent type of molecular associations may be proposed based upon above observations. Using Eyring rate equations the energy parameters ΔH, ΔF, and ΔS for the dielectric relaxation process and the viscous flow process have been calculated at the given temperatures. It is found from the comparison of energy parameters that, just like the viscous flow process, the dielectric relaxation process can also be treated as a rate process.


2013 ◽  
Vol 103 (11) ◽  
pp. 112908
Author(s):  
Shiguang Yan ◽  
Chaoliang Mao ◽  
Genshui Wang ◽  
Chunhua Yao ◽  
Fei Cao ◽  
...  

2016 ◽  
Vol 846 ◽  
pp. 311-317
Author(s):  
Mohd Noor Mat ◽  
M.K. Halimah ◽  
Wan Mohd Daud Wan Yusoff ◽  
H. Mansor ◽  
H. Nizam ◽  
...  

Dielectric relaxation and conductivity of Ni0.3Zn0.7Fe2O4 (NZF) were studied in the frequency range between 0.01 Hz to 3 MHz and temperature range within 313 K to 473 K. The sample was prepared by mixing Zinc Oxide, Nickel Oxide and Iron Oxide and sintered at 1573 K for 10 hours long. Dielectric properties were studied using Novo Control Dielectric Spectrometer. Dielectric relaxation and conductivity phenomena were discussed using an empirical model to key out the dielectric relaxation process. Analyze peak frequency relaxation process consist of four slopes to explain the dielectric relaxation process. The conductivity of the sample indicates an activated process and activation energy of dc conductivity is 0.44 ± 0.01 eV.


2006 ◽  
Vol 61 (3-4) ◽  
pp. 197-204
Author(s):  
Raman Kumar ◽  
V. S. Rangra ◽  
D. R. Sharma ◽  
N. Thakur ◽  
N. S. Negi

The dielectric relaxation times τ and dipole moments μ of N-methylacetamide (NMA) mixed with N,N-dimethylformamide (DMF) in benzene solutions have been obtained using standard standing wave microwave techniques and Gopala Krishna’s single frequency (9.90 GHz) concentration variational method at 25, 30, 35, and 40 ◦C. The energy parameters (ΔHε , ΔFε , ΔSε ) for the dielectric relaxation process of mixtures with equal amounts of NMA and DMF have been calculated and compared with the corresponding energy parameters (ΔHη , ΔFη , ΔSη ) for the viscous flow. On the basis of the observations it is found that the dielectric relaxation process can be treated as a rate process like the viscous flow. Solute-solute and solute-solvent types of the molecular associations have been predicted


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