Iron- and nitrogen-doped carbon (Fe-N-C) materials are leading candidates to replace platinum in fuel cells, but their active site structures are poorly understood. A leading postulate is that iron active sites in this class of materials exist in an Fe-N<sub>4</sub> pyridinic ligation environment. Yet, molecular Fe-based catalysts for the oxygen reduction reaction (ORR) generally feature pyrrolic coordination and pyridinic Fe-N<sub>4</sub> catalysts are, to the best of our knowledge, non-existent. We report the synthesis and characterization of a molecular pyridinic hexaazacyclophane macrocycle, (phen<sub>2</sub>N<sub>2</sub>)Fe, and compare its spectroscopic, electrochemical, and catalytic properties for oxygen reduction to a prototypical Fe-N-C material and iron octaethylporphyrin, (OEP)Fe, a prototypical pyrrolic iron macrocycle. N 1s XPS signatures for coordinated N atoms in (phen<sub>2</sub>N<sub>2</sub>)Fe are positively shifted relative to (OEP)Fe, and overlay with those of Fe-N-C. Likewise, spectroscopic XAS signatures of (phen<sub>2</sub>N<sub>2</sub>)Fe are distinct from those of (OEP)Fe, and are remarkably similar to those of Fe-N-C with compressed Fe–N bond lengths of 1.97 Å in (phen<sub>2</sub>N<sub>2</sub>)Fe that are similar to the average 1.94 Å length in Fe-N-C. Electrochemical data indicate that the iron center in (phen<sub>2</sub>N<sub>2</sub>)Fe is relatively electropositive, with an Fe(III)-OH/Fe(II)-OH<sub>2</sub> potential at 0.59 V vs the reversible hydrogen electrode (RHE), ~300 mV positive of (OEP)Fe. This correlates with a 300 mV positive shift in the onset of ORR catalysis for (phen<sub>2</sub>N<sub>2</sub>)Fe with a corresponding 1400-fold increase in TOF relative to (OEP)Fe. Consequently, the ORR onset for (phen<sub>2</sub>N<sub>2</sub>)Fe is within 150 mV of Fe-N-C. Unlike (OEP)Fe, (phen<sub>2</sub>N<sub>2</sub>)Fe displays excellent selectivity for 4-electron ORR with <4% maximum H<sub>2</sub>O<sub>2</sub> production, comparable to Fe-N-C materials. This study establishes a pyridinic iron macrocycle that effectively models Fe-N-C active sites and provides a rich platform for constructing high-performance Fe-based oxygen reduction catalysts.<br>
Elucidating the roles of the Fe-Nx active sites and pore characteristics on Fe-Pani-biomass-derived RGO as oxygen reduction catalysts in PEMFCs
