Ultrasound assisted-dispersive-micro-solid phase extraction based on bulky amino bimodal mesoporous silica nanoparticles for speciation of trace manganese (II)/(VII) ions in water samples

2016 ◽  
Vol 124 ◽  
pp. 637-645 ◽  
Author(s):  
Hamid Shirkhanloo ◽  
Aisan Khaligh ◽  
Hassan Zavvar Mousavi ◽  
Alimorad Rashidi
Keyword(s):  
Mesoporous Silica ◽  
Solid Phase Extraction ◽  
Silica Nanoparticles ◽  
Water Samples ◽  
Solid Phase ◽  
Mesoporous Silica Nanoparticles ◽  
Phase Extraction ◽  
Ultrasound Assisted

scholarly journals Separation and determination of lead in human urine and water samples based on thiol functionalized mesoporous silica nanoparticles packed on cartridges by micro column fast micro solid-phase extraction

2019 ◽  
pp. 39-50 ◽  
Author(s):  
Maling Gou ◽  
*Baharak Bahrami Yarahmadi
Keyword(s):  
Mesoporous Silica ◽  
Solid Phase Extraction ◽  
Silica Nanoparticles ◽  
Water Samples ◽  
Solid Phase ◽  
Mesoporous Silica Nanoparticles ◽  
Electrothermal Atomic Absorption Spectrometry ◽  
Cellulose Membrane ◽  
Phase Extraction ◽  
Functionalized Mesoporous Silica

An efficient method based on thiol functionalized mesoporous silica nanoparticles (HS-MSNPs) was used for extraction of lead ions (PbII) from urine and water samples by packed column micro solid phase extraction (PC-MSPE). By procedure, 15 mg of HS-MSNPs packed in syringe cartridges (SC, 5 mL) with cellulose membrane and pH adjusting at 5.5-6.5.  Then, the lead of urine and water sample was efficiently extracted on HS-MSNPs after pushing the plunger of a syringe. Finally, the Pb (II) was back-extracted with inorganic acid solution and the remained solution determined by electrothermal atomic absorption spectrometry (ET-AAS). By optimization conditions, the enrichment factor, LOD, linear range and RSD% was obtained 24.8, 0.04 μg L-1, 0.12-5.5 μg L-1 and less than 5%, respectively for 5 mL of urine samples. The validation was confirmed by spiking of real samples and using certified reference material (CRM, NIST) in water and urine sample.

Solid-phase extraction of phospholipids using mesoporous silica nanoparticles: application to human milk samples

2018 ◽  
Vol 410 (20) ◽  
pp. 4847-4854 ◽  
Author(s):  
Héctor Martínez Pérez-Cejuela ◽  
Isabel Ten-Doménech ◽  
Jamal El Haskouri ◽  
Pedro Amorós ◽  
Ernesto F. Simó-Alfonso ◽  
...  
Keyword(s):  
Mesoporous Silica ◽  
Solid Phase Extraction ◽  
Human Milk ◽  
Silica Nanoparticles ◽  
Solid Phase ◽  
Mesoporous Silica Nanoparticles ◽  
Phase Extraction ◽  
Milk Samples

Mesoporous silica sorbent with gold nanoparticles for solid-phase extraction of organochlorine pesticides in water samples

2021 ◽  
pp. 462729
Author(s):  
Enric Pellicer-Castell ◽  
Carolina Belenguer-Sapiña ◽  
Pedro Amorós ◽  
Jamal El Haskouri ◽  
José Manuel Herrero-Martínez ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Mesoporous Silica ◽  
Solid Phase Extraction ◽  
Organochlorine Pesticides ◽  
Water Samples ◽  
Solid Phase ◽  
Phase Extraction ◽  
Pesticides In Water

Simultaneous extraction of permethrin diastereomers and deltamethrin in environmental water samples based on aperture regulated magnetic mesoporous silica

2020 ◽  
Vol 44 (37) ◽  
pp. 16152-16162
Author(s):  
Meixing Zhang ◽  
Jie Mei ◽  
Siying Lv ◽  
Jiahao Lai ◽  
Xiaoni Zheng ◽  
...  
Keyword(s):  
Mesoporous Silica ◽  
Solid Phase Extraction ◽  
Water Samples ◽  
Solid Phase ◽  
Magnetic Solid Phase Extraction ◽  
Environmental Water ◽  
Phase Extraction ◽  
Simultaneous Extraction ◽  
Magnetic Solid ◽  
Magnetic Mesoporous Silica

The aperture of KIT-6 can influence the recoveries of magnetic solid phase extraction.

scholarly journals Zinc based metal–organic framework for nickel adsorption in water and wastewater samples by ultrasound assisted-dispersive-micro solid phase extraction coupled to electrothermal atomic absorption spectrometry

2020 ◽  
Vol 3 (04) ◽  
pp. 5-16
Author(s):  
Negar Motakef kazemi
Keyword(s):  
Solid Phase Extraction ◽  
Water Samples ◽  
Solid Phase ◽  
Metal Organic Framework ◽  
Electrothermal Atomic Absorption Spectrometry ◽  
Absorption Spectrometry ◽  
Phase Extraction ◽  
Nickel Ions ◽  
Metal Organic ◽  
Ultrasound Assisted

In this research, Zn2(BDC)2(DABCO) metal–organic framework (MOF) as a solid phase was used for separation and preconcentration toxic nickel ions (Ni) from water samples by ultrasound assisted-dispersive-micro solid phase extraction coupled to electrothermal atomic absorption spectrometry (USA-D-μ-SPE/ET-AAS). The MOF nanostructure was characterized by field emission-scanning electron microscope (FE-SEM) and transmission electron microscopey (TEM) for presentation of morphology and size of MOF synthesis. By procedure, 25 mg of Zn2(BDC)2(DABCO) as MOF adsorbent was added to 25 mL of water samples and then, Ni ions chemically adsorbed based on dative bonding of nitrogen in DABCO (1,4-diazabicyclo [2.2. 2]octane); N2(C2H4)3) at pH=8. The adsorbent was separated from liquid phase by syringe cellulose acetate filters (SCAF, 0.2 μm) and Ni ions back extracted from MOF adsorbent before determined by ET-AAS.  The maximum recovery of MOF for nickel ions as a physically and chemically adsorption was obtained 34.6% and 98.8% at pH=3 and 8, respectively.

scholarly journals Magnetic Solid Phase Extraction using Magnetic Mesoporous Silica for Preconcentration of Organophosphorus Pesticides

2019 ◽  
Vol 8 (4) ◽  
pp. 6847-6852
Keyword(s):  
Mesoporous Silica ◽  
Solid Phase Extraction ◽  
Water Samples ◽  
High Performance ◽  
Solid Phase ◽  
Organophosphorus Pesticides ◽  
Magnetic Solid Phase Extraction ◽  
Phase Extraction ◽  
Magnetic Solid ◽  
Mcm 41

The present study describes the synthesis, characterization and application of two mesoporous silica material based coated magnetic nanoparticles namely Fe3O4 -SBA-15 and Fe3O4 -MCM-41 for the simultaneous preconcentration of three selected organophosphorus pesticides (OPPs) namely chlorpyrifos, diazinon and parathion methyl from water samples. The resultant sorbent material was physicochemically and morphologically characterized by field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD) and N2 adsorption analysis. OPPs pesticides extraction efficiency of two sorbents were evaluated through magnetic solid phase extraction (MSPE) using high performance liquid chromatography with ultraviolet detector (HPLC/UV). The main parameters affecting the sorbent efficiency namely extraction time and desorption solvent were optimized. Comparatively, Fe3O4 -SBA-15 achieved excellent percent recovery (97.5%) compared to the Fe3O4 -MCM-41 (87.1%) under optimum condition respectively. The result appealed that the Fe3O4 -SBA-15 composite was efficient sorbent with good capability for the preconcentration of selected OPPs from water samples.AThe present study describes the synthesis, characterization and application of two mesoporous silica material based coated magnetic nanoparticles namely Fe3O4 -SBA-15 and Fe3O4 -MCM-41 for the simultaneous preconcentration of three selected organophosphorus pesticides (OPPs) namely chlorpyrifos, diazinon and parathion methyl from water samples. The resultant sorbent material was physicochemically and morphologically characterized by field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD) and N2 adsorption analysis. OPPs pesticides extraction efficiency of two sorbents were evaluated through magnetic solid phase extraction (MSPE) using high performance liquid chromatography with ultraviolet detector (HPLC/UV). The main parameters affecting the sorbent efficiency namely extraction time and desorption solvent were optimized. Comparatively, Fe3O4 -SBA-15 achieved excellent percent recovery (97.5%) compared to the Fe3O4 -MCM-41 (87.1%) under optimum condition respectively. The result appealed that the Fe3O4 -SBA-15 composite was efficient sorbent with good capability for the preconcentration of selected OPPs from water samples.

Solid phase extraction of Pb(II) in water samples using a new hybrid inorganic-organic mesoporous silica prior to its determination by FAAS

2009 ◽  
Vol 165 (3-4) ◽  
pp. 291-298 ◽  
Author(s):  
Damián Pérez-Quintanilla ◽  
Alfredo Sánchez ◽  
Isabel del Hierro ◽  
Mariano Fajardo ◽  
Isabel Sierra
Keyword(s):  
Mesoporous Silica ◽  
Solid Phase Extraction ◽  
Water Samples ◽  
Solid Phase ◽  
Phase Extraction
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