General Applicability of High-Resolution Continuum-Source Graphite Furnace Molecular Absorption Spectrometry to the Quantification of Oligopeptides Using the Example of Glutathione

This communication introduces the first-time application of high-resolution continuum-source molecular absorption spectrometry (HR CS MAS) for the quantification of a peptide. The graphite furnace technique was employed and the tripeptide glutathione (GSH) served as a model compound. Based on measuring sulfur in terms of carbon monosulfide (CS), a method was elaborated to analyze aqueous solutions of GSH. The most prominent wavelength of the CS molecule occurred at 258.0560 nm and was adduced for monitoring. The methodological development covered the optimization of the pyrolysis and vaporization temperatures. These were found optimally to be 250 °C and 2250 °C, respectively. Moreover, the effect of modifiers (zirconium, calcium, magnesium, palladium) on the absorption signals was investigated. The best results were obtained after permanent coating of the graphite tube with zirconium (total amount of 400 μg) and adding a combination of palladium (10 µL, 10 g L−1) and calcium (2 µL, 1 g L−1) as a chemical modifier to the probes (10 µL). Aqueous standard samples of GSH were used for the calibration. It showed a linear range of 2.5–100 µg mL−1 sulfur contained in GSH with a correlation coefficient R2 > 0.997. The developed method exhibited a limit of detection (LOD) and quantification (LOQ) of 2.1 µg mL−1 and 4.3 µg mL−1 sulfur, respectively. The characteristic mass accounted for 5.9 ng sulfur. The method confirmed the general suitability of MAS for the analysis of an oligopeptide. Thus, this study serves as groundwork for further development in order to extend the application of classical atomic absorption spectrometry (AAS).

Simulation of the impact of the atmospheric weather state on the efficiency of functioning of solar thermal and power plants

THE PURPOSE. Determine the impact of the meteorological state of the atmosphere on the efficiency of the functioning of solar thermal and power plants. Modeling the molecular absorption of solar radiation by the atmosphere. Modeling the optical characteristics of the gaseous components of the atmosphere, atmospheric aerosol and clouds.METHODS. A method for numerical modeling of incoming solar radiation fluxes their functioning to determine the efficiency of solar thermal and power plants. The solar fluxes are calculated by stacking layers in a multi-stream approximation, taking into account the multi-tiered cloud cover and the probability of overlapping the sky with clouds. The absorption of radiation by the gaseous phase of the atmosphere is taken into account by the method of equivalent mass in an inhomogeneous atmosphere. The optical characteristics of the dispersed phase of the atmosphere are calculated using the Mie theory.RESULTS. An electronic database has been created on the optical characteristics of the gaseous components of the atmosphere, the optical characteristics of atmospheric aerosol and clouds. The effect of anthropogenic impact on the flux of solar radiation falling on the underlying surface is taken into account. The developed modeling takes into account the effect of humidity on the optical characteristics of atmospheric aerosol and its multicomponent composition, depending on the location of the power plant.CONCLUSION. The information necessary for numerical modeling of meteorological effects on the functioning of solar thermal and power plants is generalized. When calculating solar radiation fluxes, direct illumination of the light-receiving surface by solar radiation, scattered radiation by atmospheric aerosol and clouds are taken into account.

Correction to: Determination of organically bound fluorine sum parameters in river water samples—comparison of combustion ion chromatography (CIC) and high resolution-continuum source-graphite furnace molecular absorption spectrometry (HR-CS-GFMAS)

A Correction to this paper has been published: 10.1007/s00216-021-03675-z