Depression of melting point and latent heat of molten salts as inorganic phase change material: size effect and mechanism

2021 ◽  
pp. 117058
Author(s):  
Shuai Zhang ◽  
Yingai Jin ◽  
Yuying Yan
e-Polymers ◽  
2007 ◽  
Vol 7 (1) ◽  
Author(s):  
Ai Yafei ◽  
Jin Yong ◽  
Sun Jing ◽  
Wei Deqing

AbstractIn this study, suspension polymerization is described to fabricate microcapsules containing n-hexadecane as phase change material. In the suspension polymerization, casein is employed as emulsifier and stabilizer instead of synthetic surfactant. Microcapsules with polystyrene as shell and n-hexadecane as core have an average diameter of 3~15μm and the size distribution are narrow. Thermal properties are investigated by differential scanning calorimetry (DSC) showing that the microcapsules can store and release an amount of latent heat over a temperature range nearing the melting point of pure n-hexadecane. The latent heat of fusion of microencapsulated n-hexadecane decreases after microencapsulation. The melting point of microencapsulated n-hexadecane is near but higher than that of pure n-hexadecane, and the polymerization time has little effect on the melting point.


2006 ◽  
Vol 32 (5) ◽  
pp. 429-434 ◽  
Author(s):  
Hiroyuki Nakada ◽  
Mitsuhiro Kubota ◽  
Fujio Watanabe ◽  
Hitoki Matsuda ◽  
Erwin P. Ona ◽  
...  

Author(s):  
Dominic Groulx ◽  
Wilson Ogoh

One way of storing thermal energy is through the use of latent heat energy storage systems. One such system, composed of a cylindrical container filled with paraffin wax, through which a copper pipe carrying hot water is inserted, is presented in this paper. It is shown that the physical processes encountered in the flow of water, the heat transfer by conduction and convection, and the phase change behavior of the phase change material can be modeled numerically using the finite element method. Only charging (melting) is treated in this paper. The appearance and the behavior of the melting front can be simulated by modifying the specific heat of the PCM to account for the increased amount of energy, in the form of latent heat of fusion, needed to melt the PCM over its melting temperature range. The effects of adding fins to the system are also studied, as well as the effects of the water inlet velocity.


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