From chain to layer structure: CdII coordination polymers derived from diphenic acid

2006 ◽  
Vol 784 (1-3) ◽  
pp. 1-6 ◽  
Author(s):  
Rui-Hu Wang ◽  
Ya-Qiong Gong ◽  
Lei Han ◽  
Da-Qiang Yuan ◽  
Ben-Yong Lou ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Layer Structure ◽  
Diphenic Acid

Photochromism and photoresponsive luminescence in naphthalenediimide coordination polymers with high thermostability

CrystEngComm ◽  
2021 ◽  
Vol 23 (1) ◽  
pp. 140-145
Author(s):  
Le-Tian Zhang ◽  
Bin Xia ◽  
Xia Zhang ◽  
Sha Lu ◽  
Xian-Xian Zhou ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Solvothermal Method ◽  
High Thermostability ◽  
Diphenic Acid

Two novel photochromic complexes [Zn2(bpdc)2(m-DPNDI)2]·H2O (1) and [Cd(bpdc)(m-DPNDI)]·H2O (2) (H2bpdc = 4,4′-diphenic acid, m-DPNDI = N,N′-bis(3-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide) were prepared through a solvothermal method.

Synthesis and crystal structures of two new zigzag versus helical coordination polymers based on diphenic acid

2010 ◽  
Vol 63 (7) ◽  
pp. 1130-1138 ◽  
Author(s):  
Feng Guo ◽  
Baoyong Zhu ◽  
Xiuling Zhang ◽  
Yulan Song ◽  
Ping Wu
Keyword(s):  
Crystal Structures ◽  
Coordination Polymers ◽  
Diphenic Acid

Hydrothermal synthesis, crystal structure and photoluminescence of two homochiral zinc(II) coordination polymers

2015 ◽  
Vol 71 (7) ◽  
pp. 618-622 ◽  
Author(s):  
Shao-Ming Ying ◽  
Jing-Jing Ru ◽  
Wu-Kui Luo
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers ◽  
Layer Structure ◽  
Metal Organic Frameworks ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Strong Emission ◽  
X Ray ◽  
Elemental Analyses ◽  
Metal Organic

Metal–organic frameworks (MOFs) have potentially useful applications and an intriguing variety of architectures and topologies. Two homochiral coordination polymers have been synthesized by the hydrothermal method, namely poly[(μ-N-benzyl-L-phenylalaninato-κ4O,O′:O,N)(μ-formato-κ2O:O′)zinc(II)], [Zn(C16H16NO2)(HCOO)]n, (1), and poly[(μ-N-benzyl-L-leucinato-κ4O,O′:O,N)(μ-formato-κ2O:O′)zinc(II)], [Zn(C13H18NO2)(HCOO)]n, (2), and studied by single-crystal X-ray diffraction, elemental analyses, IR spectroscopy and fluorescence spectroscopy. Compounds (1) and (2) each have a two-dimensional layer structure, with the benzyl or isobutyl groups of the ligands directed towards the interlayer interface. Photoluminescence investigations show that both (1) and (2) display a strong emission in the blue region.

scholarly journals Structures and Spectroscopy Studies of Two M(II)-Phosphonate Coordination Polymers Based on Alkaline Earth Metals (M = Ba, Mg)

2013 ◽  
Vol 2013 ◽  
pp. 1-9 ◽  
Author(s):  
Kui-Rong Ma ◽  
Chun-Li Wei ◽  
Yu Zhang ◽  
Yu-He Kan ◽  
Ming-Hui Cong ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Alkaline Earth ◽  
Layer Structure ◽  
High Energy ◽  
Triangular Prism ◽  
X Ray Diffraction ◽  
Coordination Effect ◽  
Ft Ir ◽  
Energy Emissions ◽  
Spectroscopy Studies

The two examples of alkaline-earth M(II)-phosphonate coordination polymers, [Ba2(L)(H2O)9]·3H2O (1) and [Mg1.5(H2O)9]·(L-H2)1.5·6H2O (2) (H4L = H2O3PCH2N(C4H8)NCH2PO3H2),N,N′-piperazinebis(methylenephosphonic acid), (L-H2= O3PH2CHN(C4H8)NHCH2PO3) have been hydrothermally synthesized and characterized by elemental analysis, FT-IR, PXRD, TG-DSC, and single-crystal X-ray diffraction. Compound1possesses a 2D inorganic-organic alternate arrangement layer structure built from 1D inorganic chains through the piperazine bridge, in which the ligand L−4shows two types of coordination modes reported rarely at the same time. In1, both crystallographic distinct Ba(1) and Ba(2) ions adopt 8-coordination two caps and 9-coordination three caps triangular prism geometry structures, respectively. Compound2possesses a zero-dimensional mononuclear structure with two crystallographic distinct Mg(II) ions. Free metal cations  [MgO6]n2+and uncoordinated anions(L-H2)n2-are joined together by static electric force. Results of photoluminescent measurement indicate three main emission bands centered at 300 nm, 378.5 nm, and 433 nm for1and 302 nm, 378 nm, and 434.5 nm for2(λex=235 nm), respectively. The high energy emissions could be derived from the intraligandπ∗-ntransition stations ofH4L(310 nm and 382 nm,λex=235 nm), while the low energy emission (>400 nm) of1-2may be due to the coordination effect with metal(II) ions.

Two different anionic manganese(II) coordination polymers constructed through dicyanamide coordination bridges

2015 ◽  
Vol 71 (10) ◽  
pp. 850-855 ◽  
Author(s):  
Hui-Ting Wang
Keyword(s):  
Coordination Polymers ◽  
Layer Structure ◽  
Three Dimensional ◽  
Polymeric Chain ◽  
One Dimensional ◽  
Hydrogen Bonding Interactions ◽  
The One ◽  
Hybrid Coordination ◽  
Metal Coordination Polymers ◽  
Anionic Framework

In order to explore new metal coordination polymers and to search for new types of ferroelectrics among hybrid coordination polymers, two manganese dicyanamide complexes, poly[tetramethylammonium [di-μ3-dicyanamido-κ6N1:N3:N5-tri-μ2-dicyanamido-κ6N1:N5-dimanganese(II)]], {[(CH3)4N][Mn2(NCNCN)5]}n, (I), andcatena-poly[bis(butyltriphenylphosphonium) [[(dicyanamido-κN1)manganese(II)]-di-μ2-dicyanamido-κ4N1:N5]], {[(C4H9)(C6H5)3P]2[Mn(NCNCN)4]}n, (II), were synthesized in aqueous solution. In (I), one MnIIcation is octahedrally coordinated by six nitrile N atoms from six anionic dicyanamide (dca) ligands, while the second MnIIcation is coordinated by four nitrile N atoms and two amide N atoms from six anionic dca ligands. Neighbouring MnIIcations are linked together by μ-1,5- and μ-1,3,5-bridging dca anions to form a three-dimensional polymeric structure. The anionic framework exhibits a solvent-accessible void of 289.8 Å3, amounting to 28.0% of the total unit-cell volume. Each of the cavities in the network is occupied by only one tetramethylammonium cation. In (II), each MnIIcation is octahedrally coordinated by six nitrile N atoms from six dca ligands. Neighbouring MnIIcations are linked together by double dca bridges to form a one-dimensional polymeric chain, and C—H...N hydrogen-bonding interactions are involved in the formation of the one-dimensional layer structure.

Two coordination polymers constructed by 5-[(4-carboxyphenoxy)methyl]benzene-1,3-dicarboxylic acid and 2,2′-bipyridine: syntheses, structures and luminescence properties

2019 ◽  
Vol 75 (12) ◽  
pp. 1562-1568
Author(s):  
Yuan-Chun He ◽  
Li-Yuan Xiao ◽  
Zi-Han Yuan ◽  
Jie Zhang ◽  
Yan Wang ◽  
...  
Keyword(s):  
Dicarboxylic Acid ◽  
Coordination Polymers ◽  
Supramolecular Structure ◽  
Layer Structure ◽  
Three Dimensional ◽  
Luminescence Spectra ◽  
Hydrothermal Conditions ◽  
Π Interactions ◽  
Methyl Benzene ◽  
State Luminescence

Coordination polymers (CPs) have attracted increasing interest in recent years. In this work, two new CPs, namely poly[[aquabis(2,2′-bipyridine-κ2 N,N′){μ3-5-[(4-carboxylatophenoxy)methyl]benzene-1,3-dicarboxylato-κ4 O 1,O 1′:O 3:O 5}(μ-formato-κ3 O:O,O′)dicadmium(II)] monohydrate], {[Cd2(C16H9O7)(HCO2)(C10H8N2)2(H2O)]·H2O} n (1), and poly[[(2,2′-bipyridine-κ2 N,N′){μ3-5-[(4-carboxylphenoxy)methyl]benzene-1,3-dicarboxylato-κ4 O 1,O 1′:O 3:O 5}manganese(II)] sesquihydrate], {[Mn(C16H10O7)(C10H8N2)]·1.5H2O} n (2), have been prepared using the tricarboxylic acid 5-[(4-carboxyphenoxy)methyl]benzene-1,3-dicarboxylic acid and 2,2′-bipyridine under hydrothermal conditions. CP 1 displays a two-dimensional layer structure which is further extended into a three-dimensional (3D) supramolecular structure via intermolecular π–π interactions, while CP 2 shows a different 3D supramolecular structure extended from one-dimensional ladder chains by intermolecular π–π interactions. In addition, the solid-state luminescence spectra of 1 and 2 were studied at room temperature.

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