(Y1-xNdx)3Zr5O14.5 solid solutions as inert matrices: Phase evolution, order-disorder dynamics and thermophysical behavior

2021 ◽  
Vol 27 ◽  
pp. 102158
Author(s):  
Koushik Bhandari ◽  
V. Grover ◽  
Anushree Roy ◽  
Ranu Bhatt ◽  
Joydipta Banerjee ◽  
...  
Silicon ◽  
2021 ◽  
Author(s):  
Achile Nana ◽  
Sylvain Tomé ◽  
Sybilline Claudelle Djadock Anensong ◽  
Paul Venyite ◽  
Jean Noel Yankwa Djobo ◽  
...  

2018 ◽  
Author(s):  
Roberto Köferstein

The formation of solid solutions of the type [Ba(HOC2H4OH)4][Ti1-xGex(OC2H4O)3] as Ba(Ti1-x/Gex)O3 precursors and the phase evolution during thermaldecomposition of [Ba(HOC2H4OH)4][Ti0.9Ge0.1(OC2H4O)3] (1) are described herein. The 1,2-ethanediolato complex 1 decomposes above 589 °C to a mixture of BaTiO3 and BaGeO3. Aheating rate controlled calcination procedure up to 730 °C leads to a nm-sizedBa(Ti0.9/Ge0.1)O3 powder (1a) with a specific surface area of S = 16.9 m2/g, whereas aconstant heating rate calcination at 1000 °C for 2 h yields a powder (1b) of S = 3.0 m2/g. Theshrinkage and sintering behaviour of the resulting Ba(Ti0.9/Ge0.1)O3 powder compacts incomparison with nm-sized BaTiO3 powder compacts (2a) has been investigated. A 2-stepsintering procedure of nm-sized Ba(Ti0.9/Ge0.1)O3 compacts (1a) leads below 900 °C toceramic bodies with a relative density of ³ 90 %. Furthermore, the cubic ? tetragonal phasetransition temperature has been detected by dilatometry and the temperature dependence ofthe dielectric constant (relative permittivity) has also been measured.


Author(s):  
D. Wang ◽  
◽  
Yu.A. Mirovoy ◽  
A.G. Burlachenko ◽  
A.S. Buyakov ◽  
...  

The phase evolution during sintering under pressure in the temperature range from 1400 to 1900 oC of equimolar powder mixture NbC-HfC-TiC-ZrC was investigated. It is established that monophase solid solution of (Hf, Zr, Ti, Nb)C substitution was formed at 1700 oC. From these experiments it was determined that HfC tends to act as the host material. It is shown that formation of (Hf, Zr, Ti, Nb)C solid solution proceeded multistage with formation of intermediate two- and three-component ceramic (Hf, Zr)C, (Nb, Zr)C, (Hf, Zr, Ti)C solid solutions and their subsequent dissolution. The (Hf, Zr, Ti, Nb)C solid solutions has improved mechanical properties as compared to similar properties of the original carbides: E = (616±77) GPa, H = (36±8) GPa, K1C = (3.4±0.5) MPa∙m1/2.


2018 ◽  
Vol 1 (2) ◽  
pp. 531-542 ◽  
Author(s):  
Aryan Sankhla ◽  
Akash Patil ◽  
Hasbuna Kamila ◽  
Mohammad Yasseri ◽  
Nader Farahi ◽  
...  

2021 ◽  
Vol 127 (8) ◽  
Author(s):  
Aanchal Chawla ◽  
Swati Verma ◽  
Ishita Pushkarna ◽  
P. S. Malhi ◽  
Anupinder Singh ◽  
...  

2020 ◽  
Vol 6 (4) ◽  
pp. 677-691 ◽  
Author(s):  
Gang Liu ◽  
Jia Dong ◽  
Leiyang Zhang ◽  
Yan Yan ◽  
Ruiyi Jing ◽  
...  

2018 ◽  
Vol 44 (13) ◽  
pp. 15124-15132 ◽  
Author(s):  
Shengshou Ma ◽  
Shiyin Ji ◽  
Changzhong Liao ◽  
Chengshuai Liu ◽  
Kaimin Shih ◽  
...  

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